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(E)-3-(4-Meth­oxy­phen­yl)-3-[3-(4-meth­oxy­phen­yl)-1H-pyrazol-1-yl]prop-2-enal

In the title mol­ecule, C(20)H(18)N(2)O(3), the pyrazole ring forms a dihedral angle of 2.2 (1)° with its meth­oxy­phenyl substituent and a dihedral angle of 67.2 (1)° with the benzene substituent on the propenal unit. In the crystal, mol­ecules are connected by weak C—H⋯O hydrogen bonds, forming R...

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Autores principales: Susindran, V., Athimoolam, S., Bahadur, S. Asath, Manikannan, R., Muthusubramanian, S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629636/
https://www.ncbi.nlm.nih.gov/pubmed/23634123
http://dx.doi.org/10.1107/S1600536813007678
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author Susindran, V.
Athimoolam, S.
Bahadur, S. Asath
Manikannan, R.
Muthusubramanian, S.
author_facet Susindran, V.
Athimoolam, S.
Bahadur, S. Asath
Manikannan, R.
Muthusubramanian, S.
author_sort Susindran, V.
collection PubMed
description In the title mol­ecule, C(20)H(18)N(2)O(3), the pyrazole ring forms a dihedral angle of 2.2 (1)° with its meth­oxy­phenyl substituent and a dihedral angle of 67.2 (1)° with the benzene substituent on the propenal unit. In the crystal, mol­ecules are connected by weak C—H⋯O hydrogen bonds, forming R (2) (2)(26) and R (2) (2)(28) cyclic dimers that lie about crystallographic inversion centres. These dimers are further linked through C—H⋯O and C—H⋯N hydrogen bonds, forming C(8), C(9), C(10) and C(16) chain motifs. These primary motifs are further linked to form secondary C (2) (2)(15) chains and R (2) (2)(18) rings.
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spelling pubmed-36296362013-04-30 (E)-3-(4-Meth­oxy­phen­yl)-3-[3-(4-meth­oxy­phen­yl)-1H-pyrazol-1-yl]prop-2-enal Susindran, V. Athimoolam, S. Bahadur, S. Asath Manikannan, R. Muthusubramanian, S. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(20)H(18)N(2)O(3), the pyrazole ring forms a dihedral angle of 2.2 (1)° with its meth­oxy­phenyl substituent and a dihedral angle of 67.2 (1)° with the benzene substituent on the propenal unit. In the crystal, mol­ecules are connected by weak C—H⋯O hydrogen bonds, forming R (2) (2)(26) and R (2) (2)(28) cyclic dimers that lie about crystallographic inversion centres. These dimers are further linked through C—H⋯O and C—H⋯N hydrogen bonds, forming C(8), C(9), C(10) and C(16) chain motifs. These primary motifs are further linked to form secondary C (2) (2)(15) chains and R (2) (2)(18) rings. International Union of Crystallography 2013-03-28 /pmc/articles/PMC3629636/ /pubmed/23634123 http://dx.doi.org/10.1107/S1600536813007678 Text en © Susindran et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Susindran, V.
Athimoolam, S.
Bahadur, S. Asath
Manikannan, R.
Muthusubramanian, S.
(E)-3-(4-Meth­oxy­phen­yl)-3-[3-(4-meth­oxy­phen­yl)-1H-pyrazol-1-yl]prop-2-enal
title (E)-3-(4-Meth­oxy­phen­yl)-3-[3-(4-meth­oxy­phen­yl)-1H-pyrazol-1-yl]prop-2-enal
title_full (E)-3-(4-Meth­oxy­phen­yl)-3-[3-(4-meth­oxy­phen­yl)-1H-pyrazol-1-yl]prop-2-enal
title_fullStr (E)-3-(4-Meth­oxy­phen­yl)-3-[3-(4-meth­oxy­phen­yl)-1H-pyrazol-1-yl]prop-2-enal
title_full_unstemmed (E)-3-(4-Meth­oxy­phen­yl)-3-[3-(4-meth­oxy­phen­yl)-1H-pyrazol-1-yl]prop-2-enal
title_short (E)-3-(4-Meth­oxy­phen­yl)-3-[3-(4-meth­oxy­phen­yl)-1H-pyrazol-1-yl]prop-2-enal
title_sort (e)-3-(4-meth­oxy­phen­yl)-3-[3-(4-meth­oxy­phen­yl)-1h-pyrazol-1-yl]prop-2-enal
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629636/
https://www.ncbi.nlm.nih.gov/pubmed/23634123
http://dx.doi.org/10.1107/S1600536813007678
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