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(E)-3-(4-Methoxyphenyl)-3-[3-(4-methoxyphenyl)-1H-pyrazol-1-yl]prop-2-enal
In the title molecule, C(20)H(18)N(2)O(3), the pyrazole ring forms a dihedral angle of 2.2 (1)° with its methoxyphenyl substituent and a dihedral angle of 67.2 (1)° with the benzene substituent on the propenal unit. In the crystal, molecules are connected by weak C—H⋯O hydrogen bonds, forming R...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629636/ https://www.ncbi.nlm.nih.gov/pubmed/23634123 http://dx.doi.org/10.1107/S1600536813007678 |
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author | Susindran, V. Athimoolam, S. Bahadur, S. Asath Manikannan, R. Muthusubramanian, S. |
author_facet | Susindran, V. Athimoolam, S. Bahadur, S. Asath Manikannan, R. Muthusubramanian, S. |
author_sort | Susindran, V. |
collection | PubMed |
description | In the title molecule, C(20)H(18)N(2)O(3), the pyrazole ring forms a dihedral angle of 2.2 (1)° with its methoxyphenyl substituent and a dihedral angle of 67.2 (1)° with the benzene substituent on the propenal unit. In the crystal, molecules are connected by weak C—H⋯O hydrogen bonds, forming R (2) (2)(26) and R (2) (2)(28) cyclic dimers that lie about crystallographic inversion centres. These dimers are further linked through C—H⋯O and C—H⋯N hydrogen bonds, forming C(8), C(9), C(10) and C(16) chain motifs. These primary motifs are further linked to form secondary C (2) (2)(15) chains and R (2) (2)(18) rings. |
format | Online Article Text |
id | pubmed-3629636 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36296362013-04-30 (E)-3-(4-Methoxyphenyl)-3-[3-(4-methoxyphenyl)-1H-pyrazol-1-yl]prop-2-enal Susindran, V. Athimoolam, S. Bahadur, S. Asath Manikannan, R. Muthusubramanian, S. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title molecule, C(20)H(18)N(2)O(3), the pyrazole ring forms a dihedral angle of 2.2 (1)° with its methoxyphenyl substituent and a dihedral angle of 67.2 (1)° with the benzene substituent on the propenal unit. In the crystal, molecules are connected by weak C—H⋯O hydrogen bonds, forming R (2) (2)(26) and R (2) (2)(28) cyclic dimers that lie about crystallographic inversion centres. These dimers are further linked through C—H⋯O and C—H⋯N hydrogen bonds, forming C(8), C(9), C(10) and C(16) chain motifs. These primary motifs are further linked to form secondary C (2) (2)(15) chains and R (2) (2)(18) rings. International Union of Crystallography 2013-03-28 /pmc/articles/PMC3629636/ /pubmed/23634123 http://dx.doi.org/10.1107/S1600536813007678 Text en © Susindran et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Susindran, V. Athimoolam, S. Bahadur, S. Asath Manikannan, R. Muthusubramanian, S. (E)-3-(4-Methoxyphenyl)-3-[3-(4-methoxyphenyl)-1H-pyrazol-1-yl]prop-2-enal |
title | (E)-3-(4-Methoxyphenyl)-3-[3-(4-methoxyphenyl)-1H-pyrazol-1-yl]prop-2-enal |
title_full | (E)-3-(4-Methoxyphenyl)-3-[3-(4-methoxyphenyl)-1H-pyrazol-1-yl]prop-2-enal |
title_fullStr | (E)-3-(4-Methoxyphenyl)-3-[3-(4-methoxyphenyl)-1H-pyrazol-1-yl]prop-2-enal |
title_full_unstemmed | (E)-3-(4-Methoxyphenyl)-3-[3-(4-methoxyphenyl)-1H-pyrazol-1-yl]prop-2-enal |
title_short | (E)-3-(4-Methoxyphenyl)-3-[3-(4-methoxyphenyl)-1H-pyrazol-1-yl]prop-2-enal |
title_sort | (e)-3-(4-methoxyphenyl)-3-[3-(4-methoxyphenyl)-1h-pyrazol-1-yl]prop-2-enal |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629636/ https://www.ncbi.nlm.nih.gov/pubmed/23634123 http://dx.doi.org/10.1107/S1600536813007678 |
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