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9-(2-Hy­droxy-6-oxocyclo­hex-1-en-1-yl)-2,3,4,9-tetra­hydro-1H-xanthen-1-one

In the xanthene ring system in the title compound, C(19)H(18)O(4), the 4H-pyran ring has a maximum deviation of 0.110 (2) Å from planarity and the cyclo­hexene ring exhibits a puckered conformation [puckering parameters Q (T) = 0.452 (3) Å, θ = 57.0 (4) and ϕ = 131.7 (4)°]. The cyclo­hexene ring att...

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Detalles Bibliográficos
Autores principales: Mohamed, Shaaban K., Akkurt, Mehmet, Abdelhamid, Antar A., Saeed, Aamer, Flörke, Ulrich
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629652/
https://www.ncbi.nlm.nih.gov/pubmed/23634139
http://dx.doi.org/10.1107/S1600536813007952
Descripción
Sumario:In the xanthene ring system in the title compound, C(19)H(18)O(4), the 4H-pyran ring has a maximum deviation of 0.110 (2) Å from planarity and the cyclo­hexene ring exhibits a puckered conformation [puckering parameters Q (T) = 0.452 (3) Å, θ = 57.0 (4) and ϕ = 131.7 (4)°]. The cyclo­hexene ring attached to the xanthene system adopts an envelope conformation, with the middle of the three methylene C atoms as the flap atom. In the crystal, O—H⋯O and C—H⋯O hydrogen bonds form infinite chains of R (1) (2)(6) ring motifs along [100] with the xanthene groups arranged in an alternating zigzag manner.