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9-(2-Hydroxy-6-oxocyclohex-1-en-1-yl)-2,3,4,9-tetrahydro-1H-xanthen-1-one
In the xanthene ring system in the title compound, C(19)H(18)O(4), the 4H-pyran ring has a maximum deviation of 0.110 (2) Å from planarity and the cyclohexene ring exhibits a puckered conformation [puckering parameters Q (T) = 0.452 (3) Å, θ = 57.0 (4) and ϕ = 131.7 (4)°]. The cyclohexene ring att...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629652/ https://www.ncbi.nlm.nih.gov/pubmed/23634139 http://dx.doi.org/10.1107/S1600536813007952 |
Sumario: | In the xanthene ring system in the title compound, C(19)H(18)O(4), the 4H-pyran ring has a maximum deviation of 0.110 (2) Å from planarity and the cyclohexene ring exhibits a puckered conformation [puckering parameters Q (T) = 0.452 (3) Å, θ = 57.0 (4) and ϕ = 131.7 (4)°]. The cyclohexene ring attached to the xanthene system adopts an envelope conformation, with the middle of the three methylene C atoms as the flap atom. In the crystal, O—H⋯O and C—H⋯O hydrogen bonds form infinite chains of R (1) (2)(6) ring motifs along [100] with the xanthene groups arranged in an alternating zigzag manner. |
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