Kinetic Studies that Evaluate the Solvolytic Mechanisms of Allyl and Vinyl Chloroformate Esters

At 25.0 °C the specific rates of solvolysis for allyl and vinyl chloroformates have been determined in a wide mix of pure and aqueous organic mixtures. In all the solvents studied, vinyl chloroformate was found to react significantly faster than allyl chloroformate. Multiple correlation analyses of...

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Detalles Bibliográficos
Autores principales: D’Souza, Malcolm J., Givens, Aaron F., Lorchak, Peter A., Greenwood, Abigail E., Gottschall, Stacey L., Carter, Shannon E., Kevill, Dennis N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International (MDPI) 2013
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3645686/
https://www.ncbi.nlm.nih.gov/pubmed/23549265
http://dx.doi.org/10.3390/ijms14047286

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3645686/
https://www.ncbi.nlm.nih.gov/pubmed/23549265
http://dx.doi.org/10.3390/ijms14047286

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