Cargando…
Ba(2)Sb(4)GeS(10)
The title quaternary compound, dibarium tetraantimony germanium decasulfide, Ba(2)Sb(4)GeS(10), crystallizes in a novel three-dimensional (∞) (3)[Sb(4)GeS(10)](4−) network structure, which is composed of triangular pyramidal SbS(3) (site symmetry m..), distorted SbS(5) (m..) polyhedra and regular...
| Autor principal: | |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647782/ https://www.ncbi.nlm.nih.gov/pubmed/23723748 http://dx.doi.org/10.1107/S1600536813007988 |
| _version_ | 1782268774457540608 |
|---|---|
| author | Geng, Lei |
| author_facet | Geng, Lei |
| author_sort | Geng, Lei |
| collection | PubMed |
| description | The title quaternary compound, dibarium tetraantimony germanium decasulfide, Ba(2)Sb(4)GeS(10), crystallizes in a novel three-dimensional (∞) (3)[Sb(4)GeS(10)](4−) network structure, which is composed of triangular pyramidal SbS(3) (site symmetry m..), distorted SbS(5) (m..) polyhedra and regular GeS(4) (-4..) tetrahedra. The SbS(3) and SbS(5) units are connected with each other through corner- and edge-sharing, forming a Sb(4)S(10) layer in the ab plane. The GeS(4) tetrahedra further bridge two neighbouring Sb(4)S(10) layers, forming a three-dimensional (∞) (3)[Sb(4)GeS(10)](4−) network. The Ba(2+) cation (..2) is located between two Sb(4)S(10) layers and is coordinated by ten S atoms with Ba—S bond lengths in the range 3.2505 (9)–3.4121 (2) Å. |
| format | Online Article Text |
| id | pubmed-3647782 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2013 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-36477822013-05-30 Ba(2)Sb(4)GeS(10) Geng, Lei Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The title quaternary compound, dibarium tetraantimony germanium decasulfide, Ba(2)Sb(4)GeS(10), crystallizes in a novel three-dimensional (∞) (3)[Sb(4)GeS(10)](4−) network structure, which is composed of triangular pyramidal SbS(3) (site symmetry m..), distorted SbS(5) (m..) polyhedra and regular GeS(4) (-4..) tetrahedra. The SbS(3) and SbS(5) units are connected with each other through corner- and edge-sharing, forming a Sb(4)S(10) layer in the ab plane. The GeS(4) tetrahedra further bridge two neighbouring Sb(4)S(10) layers, forming a three-dimensional (∞) (3)[Sb(4)GeS(10)](4−) network. The Ba(2+) cation (..2) is located between two Sb(4)S(10) layers and is coordinated by ten S atoms with Ba—S bond lengths in the range 3.2505 (9)–3.4121 (2) Å. International Union of Crystallography 2013-04-05 /pmc/articles/PMC3647782/ /pubmed/23723748 http://dx.doi.org/10.1107/S1600536813007988 Text en © Lei Geng 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Inorganic Papers Geng, Lei Ba(2)Sb(4)GeS(10) |
| title | Ba(2)Sb(4)GeS(10)
|
| title_full | Ba(2)Sb(4)GeS(10)
|
| title_fullStr | Ba(2)Sb(4)GeS(10)
|
| title_full_unstemmed | Ba(2)Sb(4)GeS(10)
|
| title_short | Ba(2)Sb(4)GeS(10)
|
| title_sort | ba(2)sb(4)ges(10) |
| topic | Inorganic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647782/ https://www.ncbi.nlm.nih.gov/pubmed/23723748 http://dx.doi.org/10.1107/S1600536813007988 |
| work_keys_str_mv | AT genglei ba2sb4ges10 |