Penta­cobalt(II) divanadium(III) tetrakis(diphosphate), Co(5)V(2)(P(2)O(7))(4)

Co(5)V(2)(P(2)O(7))(4) was crystallized by chemical vapour transport using HCl as transport agent. Its crystal structure is isotypic to that of Fe(II) (5)Fe(III) (2)(P(2)O(7))(4) and can be regarded as a member of the thortveitite structure family with corrugated layers of metal–oxygen polyhedra ext...

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Detalles Bibliográficos
Autores principales: Bronova, Anna, Glaum, Robert, Litterscheid, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647784/
https://www.ncbi.nlm.nih.gov/pubmed/23723750
http://dx.doi.org/10.1107/S1600536813008507
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author Bronova, Anna
Glaum, Robert
Litterscheid, Christian
author_facet Bronova, Anna
Glaum, Robert
Litterscheid, Christian
author_sort Bronova, Anna
collection PubMed
description Co(5)V(2)(P(2)O(7))(4) was crystallized by chemical vapour transport using HCl as transport agent. Its crystal structure is isotypic to that of Fe(II) (5)Fe(III) (2)(P(2)O(7))(4) and can be regarded as a member of the thortveitite structure family with corrugated layers of metal–oxygen polyhedra extending parallel to (010). Significant occupational disorder between cobalt(II) and vanadium(III) is observed. Four of the five cation sites are occupied by both cobalt and vanadium. The fifth cation site (Co1) is occupied by cobalt only. Sites Co1, M3 and M4 are located on twofold axes. Sites Co1, M2, M3 and M4 show o­cta­hedral coordination by oxygen; M5 has a square-pyramidal environment.
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spelling pubmed-36477842013-05-30 Penta­cobalt(II) divanadium(III) tetrakis(diphosphate), Co(5)V(2)(P(2)O(7))(4) Bronova, Anna Glaum, Robert Litterscheid, Christian Acta Crystallogr Sect E Struct Rep Online Inorganic Papers Co(5)V(2)(P(2)O(7))(4) was crystallized by chemical vapour transport using HCl as transport agent. Its crystal structure is isotypic to that of Fe(II) (5)Fe(III) (2)(P(2)O(7))(4) and can be regarded as a member of the thortveitite structure family with corrugated layers of metal–oxygen polyhedra extending parallel to (010). Significant occupational disorder between cobalt(II) and vanadium(III) is observed. Four of the five cation sites are occupied by both cobalt and vanadium. The fifth cation site (Co1) is occupied by cobalt only. Sites Co1, M3 and M4 are located on twofold axes. Sites Co1, M2, M3 and M4 show o­cta­hedral coordination by oxygen; M5 has a square-pyramidal environment. International Union of Crystallography 2013-04-10 /pmc/articles/PMC3647784/ /pubmed/23723750 http://dx.doi.org/10.1107/S1600536813008507 Text en © Bronova et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Bronova, Anna
Glaum, Robert
Litterscheid, Christian
Penta­cobalt(II) divanadium(III) tetrakis(diphosphate), Co(5)V(2)(P(2)O(7))(4)
title Penta­cobalt(II) divanadium(III) tetrakis(diphosphate), Co(5)V(2)(P(2)O(7))(4)
title_full Penta­cobalt(II) divanadium(III) tetrakis(diphosphate), Co(5)V(2)(P(2)O(7))(4)
title_fullStr Penta­cobalt(II) divanadium(III) tetrakis(diphosphate), Co(5)V(2)(P(2)O(7))(4)
title_full_unstemmed Penta­cobalt(II) divanadium(III) tetrakis(diphosphate), Co(5)V(2)(P(2)O(7))(4)
title_short Penta­cobalt(II) divanadium(III) tetrakis(diphosphate), Co(5)V(2)(P(2)O(7))(4)
title_sort penta­cobalt(ii) divanadium(iii) tetrakis(diphosphate), co(5)v(2)(p(2)o(7))(4)
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647784/
https://www.ncbi.nlm.nih.gov/pubmed/23723750
http://dx.doi.org/10.1107/S1600536813008507
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AT litterscheidchristian pentacobaltiidivanadiumiiitetrakisdiphosphateco5v2p2o74

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