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Tetra­ammine-2κ(4) C-μ-cyanido-1:2κ(2) C:N-tricyanido-1κ(3) C-copper(II)palladium(II)

The title compound, [Cu(NH(3))(4)-(μ(2)-NC)—Pd(CN)(3)], is a binuclear copper(II)palladium(II) complex, in which the Cu(II) coordination is defined by four ammine ligands and one bridging cyanide ligand. The Cu—N bond lengths in the base of the resulting CuN(5) pyramid are in the range 2.016 (3)–2.0...

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Detalles Bibliográficos
Autores principales: Suchá, Veronika, Kuchár, Juraj, Harms, Klaus
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647788/
https://www.ncbi.nlm.nih.gov/pubmed/23723754
http://dx.doi.org/10.1107/S1600536813011033
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author Suchá, Veronika
Kuchár, Juraj
Harms, Klaus
author_facet Suchá, Veronika
Kuchár, Juraj
Harms, Klaus
author_sort Suchá, Veronika
collection PubMed
description The title compound, [Cu(NH(3))(4)-(μ(2)-NC)—Pd(CN)(3)], is a binuclear copper(II)palladium(II) complex, in which the Cu(II) coordination is defined by four ammine ligands and one bridging cyanide ligand. The Cu—N bond lengths in the base of the resulting CuN(5) pyramid are in the range 2.016 (3)–2.024 (3) Å and the apical Cu—N( C) distance is 2.385 (4) Å. Based on the τ parameter, the shape of the coordination polyhedron is tetra­gonal–pyramidal (τ = 0). All atoms of the square-planar tetracyanidopalladate(II) moiety and the Cu(II) ion are located on a mirror plane. The electroneutral mol­ecules inter­act by N—H⋯N hydrogen bonds, resulting in the formation of a three-dimensional network.
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spelling pubmed-36477882013-05-30 Tetra­ammine-2κ(4) C-μ-cyanido-1:2κ(2) C:N-tricyanido-1κ(3) C-copper(II)palladium(II) Suchá, Veronika Kuchár, Juraj Harms, Klaus Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The title compound, [Cu(NH(3))(4)-(μ(2)-NC)—Pd(CN)(3)], is a binuclear copper(II)palladium(II) complex, in which the Cu(II) coordination is defined by four ammine ligands and one bridging cyanide ligand. The Cu—N bond lengths in the base of the resulting CuN(5) pyramid are in the range 2.016 (3)–2.024 (3) Å and the apical Cu—N( C) distance is 2.385 (4) Å. Based on the τ parameter, the shape of the coordination polyhedron is tetra­gonal–pyramidal (τ = 0). All atoms of the square-planar tetracyanidopalladate(II) moiety and the Cu(II) ion are located on a mirror plane. The electroneutral mol­ecules inter­act by N—H⋯N hydrogen bonds, resulting in the formation of a three-dimensional network. International Union of Crystallography 2013-04-30 /pmc/articles/PMC3647788/ /pubmed/23723754 http://dx.doi.org/10.1107/S1600536813011033 Text en © Suchá et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Suchá, Veronika
Kuchár, Juraj
Harms, Klaus
Tetra­ammine-2κ(4) C-μ-cyanido-1:2κ(2) C:N-tricyanido-1κ(3) C-copper(II)palladium(II)
title Tetra­ammine-2κ(4) C-μ-cyanido-1:2κ(2) C:N-tricyanido-1κ(3) C-copper(II)palladium(II)
title_full Tetra­ammine-2κ(4) C-μ-cyanido-1:2κ(2) C:N-tricyanido-1κ(3) C-copper(II)palladium(II)
title_fullStr Tetra­ammine-2κ(4) C-μ-cyanido-1:2κ(2) C:N-tricyanido-1κ(3) C-copper(II)palladium(II)
title_full_unstemmed Tetra­ammine-2κ(4) C-μ-cyanido-1:2κ(2) C:N-tricyanido-1κ(3) C-copper(II)palladium(II)
title_short Tetra­ammine-2κ(4) C-μ-cyanido-1:2κ(2) C:N-tricyanido-1κ(3) C-copper(II)palladium(II)
title_sort tetra­ammine-2κ(4) c-μ-cyanido-1:2κ(2) c:n-tricyanido-1κ(3) c-copper(ii)palladium(ii)
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647788/
https://www.ncbi.nlm.nih.gov/pubmed/23723754
http://dx.doi.org/10.1107/S1600536813011033
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AT harmsklaus tetraammine2k4cmcyanido12k2cntricyanido1k3ccopperiipalladiumii