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Tetraammine-2κ(4) C-μ-cyanido-1:2κ(2) C:N-tricyanido-1κ(3) C-copper(II)palladium(II)
The title compound, [Cu(NH(3))(4)-(μ(2)-NC)—Pd(CN)(3)], is a binuclear copper(II)palladium(II) complex, in which the Cu(II) coordination is defined by four ammine ligands and one bridging cyanide ligand. The Cu—N bond lengths in the base of the resulting CuN(5) pyramid are in the range 2.016 (3)–2.0...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647788/ https://www.ncbi.nlm.nih.gov/pubmed/23723754 http://dx.doi.org/10.1107/S1600536813011033 |
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author | Suchá, Veronika Kuchár, Juraj Harms, Klaus |
author_facet | Suchá, Veronika Kuchár, Juraj Harms, Klaus |
author_sort | Suchá, Veronika |
collection | PubMed |
description | The title compound, [Cu(NH(3))(4)-(μ(2)-NC)—Pd(CN)(3)], is a binuclear copper(II)palladium(II) complex, in which the Cu(II) coordination is defined by four ammine ligands and one bridging cyanide ligand. The Cu—N bond lengths in the base of the resulting CuN(5) pyramid are in the range 2.016 (3)–2.024 (3) Å and the apical Cu—N( C) distance is 2.385 (4) Å. Based on the τ parameter, the shape of the coordination polyhedron is tetragonal–pyramidal (τ = 0). All atoms of the square-planar tetracyanidopalladate(II) moiety and the Cu(II) ion are located on a mirror plane. The electroneutral molecules interact by N—H⋯N hydrogen bonds, resulting in the formation of a three-dimensional network. |
format | Online Article Text |
id | pubmed-3647788 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36477882013-05-30 Tetraammine-2κ(4) C-μ-cyanido-1:2κ(2) C:N-tricyanido-1κ(3) C-copper(II)palladium(II) Suchá, Veronika Kuchár, Juraj Harms, Klaus Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The title compound, [Cu(NH(3))(4)-(μ(2)-NC)—Pd(CN)(3)], is a binuclear copper(II)palladium(II) complex, in which the Cu(II) coordination is defined by four ammine ligands and one bridging cyanide ligand. The Cu—N bond lengths in the base of the resulting CuN(5) pyramid are in the range 2.016 (3)–2.024 (3) Å and the apical Cu—N( C) distance is 2.385 (4) Å. Based on the τ parameter, the shape of the coordination polyhedron is tetragonal–pyramidal (τ = 0). All atoms of the square-planar tetracyanidopalladate(II) moiety and the Cu(II) ion are located on a mirror plane. The electroneutral molecules interact by N—H⋯N hydrogen bonds, resulting in the formation of a three-dimensional network. International Union of Crystallography 2013-04-30 /pmc/articles/PMC3647788/ /pubmed/23723754 http://dx.doi.org/10.1107/S1600536813011033 Text en © Suchá et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Inorganic Papers Suchá, Veronika Kuchár, Juraj Harms, Klaus Tetraammine-2κ(4) C-μ-cyanido-1:2κ(2) C:N-tricyanido-1κ(3) C-copper(II)palladium(II) |
title | Tetraammine-2κ(4)
C-μ-cyanido-1:2κ(2)
C:N-tricyanido-1κ(3)
C-copper(II)palladium(II) |
title_full | Tetraammine-2κ(4)
C-μ-cyanido-1:2κ(2)
C:N-tricyanido-1κ(3)
C-copper(II)palladium(II) |
title_fullStr | Tetraammine-2κ(4)
C-μ-cyanido-1:2κ(2)
C:N-tricyanido-1κ(3)
C-copper(II)palladium(II) |
title_full_unstemmed | Tetraammine-2κ(4)
C-μ-cyanido-1:2κ(2)
C:N-tricyanido-1κ(3)
C-copper(II)palladium(II) |
title_short | Tetraammine-2κ(4)
C-μ-cyanido-1:2κ(2)
C:N-tricyanido-1κ(3)
C-copper(II)palladium(II) |
title_sort | tetraammine-2κ(4)
c-μ-cyanido-1:2κ(2)
c:n-tricyanido-1κ(3)
c-copper(ii)palladium(ii) |
topic | Inorganic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647788/ https://www.ncbi.nlm.nih.gov/pubmed/23723754 http://dx.doi.org/10.1107/S1600536813011033 |
work_keys_str_mv | AT suchaveronika tetraammine2k4cmcyanido12k2cntricyanido1k3ccopperiipalladiumii AT kucharjuraj tetraammine2k4cmcyanido12k2cntricyanido1k3ccopperiipalladiumii AT harmsklaus tetraammine2k4cmcyanido12k2cntricyanido1k3ccopperiipalladiumii |