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(Butane-1,4-di­yl)(trimethyl­phosphane-κP)[tris­(3,5-dimethyl­pyrazol-1-yl-κN (2))hydro­borato]iridium(III)

In the mononuclear title iridium(III) complex, [Ir(C(4)H(8))(C(15)H(22)BN(6))(C(3)H(9)P)], which is based on the [tris­(3,5-dimethyl­pyrazol-1-yl)hydro­borato]iridium moiety, Ir[Tp(Me2)], the Ir(III) atom is coordinated by a chelating butane-1,4-diyl fragment and a trimethyl­phosphane ligand in a mo...

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Autores principales: Gómez, Margarita, Santos, Laura L., Paneque, Margarita, Mereiter, Kurt
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647789/
https://www.ncbi.nlm.nih.gov/pubmed/23723755
http://dx.doi.org/10.1107/S1600536813008040
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author Gómez, Margarita
Santos, Laura L.
Paneque, Margarita
Mereiter, Kurt
author_facet Gómez, Margarita
Santos, Laura L.
Paneque, Margarita
Mereiter, Kurt
author_sort Gómez, Margarita
collection PubMed
description In the mononuclear title iridium(III) complex, [Ir(C(4)H(8))(C(15)H(22)BN(6))(C(3)H(9)P)], which is based on the [tris­(3,5-dimethyl­pyrazol-1-yl)hydro­borato]iridium moiety, Ir[Tp(Me2)], the Ir(III) atom is coordinated by a chelating butane-1,4-diyl fragment and a trimethyl­phosphane ligand in a modestly distorted octa­hedral coordination environment formed by three facial N, two C and one P atom. The iridium–butane-1,4-diyl ring has an envelope conformation. This ring is disordered because alternately the second or the third C atom of the butane-1,4-diyl fragment function as an envelope flap atom (the occupancy ratio is 1:1). In the crystal, mol­ecules are organized into densely packed columns extending along [101]. Coherence between the mol­ecules is essentially based on van der Waals inter­actions.
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spelling pubmed-36477892013-05-30 (Butane-1,4-di­yl)(trimethyl­phosphane-κP)[tris­(3,5-dimethyl­pyrazol-1-yl-κN (2))hydro­borato]iridium(III) Gómez, Margarita Santos, Laura L. Paneque, Margarita Mereiter, Kurt Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title iridium(III) complex, [Ir(C(4)H(8))(C(15)H(22)BN(6))(C(3)H(9)P)], which is based on the [tris­(3,5-dimethyl­pyrazol-1-yl)hydro­borato]iridium moiety, Ir[Tp(Me2)], the Ir(III) atom is coordinated by a chelating butane-1,4-diyl fragment and a trimethyl­phosphane ligand in a modestly distorted octa­hedral coordination environment formed by three facial N, two C and one P atom. The iridium–butane-1,4-diyl ring has an envelope conformation. This ring is disordered because alternately the second or the third C atom of the butane-1,4-diyl fragment function as an envelope flap atom (the occupancy ratio is 1:1). In the crystal, mol­ecules are organized into densely packed columns extending along [101]. Coherence between the mol­ecules is essentially based on van der Waals inter­actions. International Union of Crystallography 2013-04-05 /pmc/articles/PMC3647789/ /pubmed/23723755 http://dx.doi.org/10.1107/S1600536813008040 Text en © Gómez et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gómez, Margarita
Santos, Laura L.
Paneque, Margarita
Mereiter, Kurt
(Butane-1,4-di­yl)(trimethyl­phosphane-κP)[tris­(3,5-dimethyl­pyrazol-1-yl-κN (2))hydro­borato]iridium(III)
title (Butane-1,4-di­yl)(trimethyl­phosphane-κP)[tris­(3,5-dimethyl­pyrazol-1-yl-κN (2))hydro­borato]iridium(III)
title_full (Butane-1,4-di­yl)(trimethyl­phosphane-κP)[tris­(3,5-dimethyl­pyrazol-1-yl-κN (2))hydro­borato]iridium(III)
title_fullStr (Butane-1,4-di­yl)(trimethyl­phosphane-κP)[tris­(3,5-dimethyl­pyrazol-1-yl-κN (2))hydro­borato]iridium(III)
title_full_unstemmed (Butane-1,4-di­yl)(trimethyl­phosphane-κP)[tris­(3,5-dimethyl­pyrazol-1-yl-κN (2))hydro­borato]iridium(III)
title_short (Butane-1,4-di­yl)(trimethyl­phosphane-κP)[tris­(3,5-dimethyl­pyrazol-1-yl-κN (2))hydro­borato]iridium(III)
title_sort (butane-1,4-di­yl)(trimethyl­phosphane-κp)[tris­(3,5-dimethyl­pyrazol-1-yl-κn (2))hydro­borato]iridium(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647789/
https://www.ncbi.nlm.nih.gov/pubmed/23723755
http://dx.doi.org/10.1107/S1600536813008040
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