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(Butane-1,4-diyl)(trimethylphosphane-κP)[tris(3,5-dimethylpyrazol-1-yl-κN (2))hydroborato]iridium(III)
In the mononuclear title iridium(III) complex, [Ir(C(4)H(8))(C(15)H(22)BN(6))(C(3)H(9)P)], which is based on the [tris(3,5-dimethylpyrazol-1-yl)hydroborato]iridium moiety, Ir[Tp(Me2)], the Ir(III) atom is coordinated by a chelating butane-1,4-diyl fragment and a trimethylphosphane ligand in a mo...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647789/ https://www.ncbi.nlm.nih.gov/pubmed/23723755 http://dx.doi.org/10.1107/S1600536813008040 |
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author | Gómez, Margarita Santos, Laura L. Paneque, Margarita Mereiter, Kurt |
author_facet | Gómez, Margarita Santos, Laura L. Paneque, Margarita Mereiter, Kurt |
author_sort | Gómez, Margarita |
collection | PubMed |
description | In the mononuclear title iridium(III) complex, [Ir(C(4)H(8))(C(15)H(22)BN(6))(C(3)H(9)P)], which is based on the [tris(3,5-dimethylpyrazol-1-yl)hydroborato]iridium moiety, Ir[Tp(Me2)], the Ir(III) atom is coordinated by a chelating butane-1,4-diyl fragment and a trimethylphosphane ligand in a modestly distorted octahedral coordination environment formed by three facial N, two C and one P atom. The iridium–butane-1,4-diyl ring has an envelope conformation. This ring is disordered because alternately the second or the third C atom of the butane-1,4-diyl fragment function as an envelope flap atom (the occupancy ratio is 1:1). In the crystal, molecules are organized into densely packed columns extending along [101]. Coherence between the molecules is essentially based on van der Waals interactions. |
format | Online Article Text |
id | pubmed-3647789 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36477892013-05-30 (Butane-1,4-diyl)(trimethylphosphane-κP)[tris(3,5-dimethylpyrazol-1-yl-κN (2))hydroborato]iridium(III) Gómez, Margarita Santos, Laura L. Paneque, Margarita Mereiter, Kurt Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title iridium(III) complex, [Ir(C(4)H(8))(C(15)H(22)BN(6))(C(3)H(9)P)], which is based on the [tris(3,5-dimethylpyrazol-1-yl)hydroborato]iridium moiety, Ir[Tp(Me2)], the Ir(III) atom is coordinated by a chelating butane-1,4-diyl fragment and a trimethylphosphane ligand in a modestly distorted octahedral coordination environment formed by three facial N, two C and one P atom. The iridium–butane-1,4-diyl ring has an envelope conformation. This ring is disordered because alternately the second or the third C atom of the butane-1,4-diyl fragment function as an envelope flap atom (the occupancy ratio is 1:1). In the crystal, molecules are organized into densely packed columns extending along [101]. Coherence between the molecules is essentially based on van der Waals interactions. International Union of Crystallography 2013-04-05 /pmc/articles/PMC3647789/ /pubmed/23723755 http://dx.doi.org/10.1107/S1600536813008040 Text en © Gómez et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Gómez, Margarita Santos, Laura L. Paneque, Margarita Mereiter, Kurt (Butane-1,4-diyl)(trimethylphosphane-κP)[tris(3,5-dimethylpyrazol-1-yl-κN (2))hydroborato]iridium(III) |
title | (Butane-1,4-diyl)(trimethylphosphane-κP)[tris(3,5-dimethylpyrazol-1-yl-κN
(2))hydroborato]iridium(III) |
title_full | (Butane-1,4-diyl)(trimethylphosphane-κP)[tris(3,5-dimethylpyrazol-1-yl-κN
(2))hydroborato]iridium(III) |
title_fullStr | (Butane-1,4-diyl)(trimethylphosphane-κP)[tris(3,5-dimethylpyrazol-1-yl-κN
(2))hydroborato]iridium(III) |
title_full_unstemmed | (Butane-1,4-diyl)(trimethylphosphane-κP)[tris(3,5-dimethylpyrazol-1-yl-κN
(2))hydroborato]iridium(III) |
title_short | (Butane-1,4-diyl)(trimethylphosphane-κP)[tris(3,5-dimethylpyrazol-1-yl-κN
(2))hydroborato]iridium(III) |
title_sort | (butane-1,4-diyl)(trimethylphosphane-κp)[tris(3,5-dimethylpyrazol-1-yl-κn
(2))hydroborato]iridium(iii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647789/ https://www.ncbi.nlm.nih.gov/pubmed/23723755 http://dx.doi.org/10.1107/S1600536813008040 |
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