Cargando…

Dichlorido{2,6-diisopropyl-N-[(S)-pyrrolidin-2-ylmeth­yl]aniline-κ(2) N,N′}palladium(II)

In the title compound, [PdCl(2)(C(17)H(28)N(2))], the Pd(II) atom displays a square-planar coordination involving two N atoms of a 2,6-diisopropyl-N-[(S)-pyrrolidin-2-ylmeth­yl]aniline ligand and two chloride ligands, with a deviation of 0.090 (1) Å for the Pd(II) atom from the best plane. The absol...

Descripción completa

Detalles Bibliográficos
Autores principales: Nayab, Saira, Lee, Hong-In, Jeong, Jong Hwa
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647791/
https://www.ncbi.nlm.nih.gov/pubmed/23723757
http://dx.doi.org/10.1107/S1600536813008271
_version_ 1782268776522186752
author Nayab, Saira
Lee, Hong-In
Jeong, Jong Hwa
author_facet Nayab, Saira
Lee, Hong-In
Jeong, Jong Hwa
author_sort Nayab, Saira
collection PubMed
description In the title compound, [PdCl(2)(C(17)H(28)N(2))], the Pd(II) atom displays a square-planar coordination involving two N atoms of a 2,6-diisopropyl-N-[(S)-pyrrolidin-2-ylmeth­yl]aniline ligand and two chloride ligands, with a deviation of 0.090 (1) Å for the Pd(II) atom from the best plane. The absolute configuration of the chiral C atom of the pyrrolidine ring is S, which induces R configurations at the two N atoms of the aniline ligand. Optical isomerism arising from the chelate five-membered ring is configured as δ. The Pd—N bond lengths are 2.040 (3) and 2.072 (2) Å, and the Pd—Cl bond lengths are 2.3055 (8) and 2.3160 (8) Å. In the crystal, pairs of N—H⋯Cl hydrogen bonds link mol­ecules into discrete dimers.
format Online
Article
Text
id pubmed-3647791
institution National Center for Biotechnology Information
language English
publishDate 2013
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-36477912013-05-30 Dichlorido{2,6-diisopropyl-N-[(S)-pyrrolidin-2-ylmeth­yl]aniline-κ(2) N,N′}palladium(II) Nayab, Saira Lee, Hong-In Jeong, Jong Hwa Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [PdCl(2)(C(17)H(28)N(2))], the Pd(II) atom displays a square-planar coordination involving two N atoms of a 2,6-diisopropyl-N-[(S)-pyrrolidin-2-ylmeth­yl]aniline ligand and two chloride ligands, with a deviation of 0.090 (1) Å for the Pd(II) atom from the best plane. The absolute configuration of the chiral C atom of the pyrrolidine ring is S, which induces R configurations at the two N atoms of the aniline ligand. Optical isomerism arising from the chelate five-membered ring is configured as δ. The Pd—N bond lengths are 2.040 (3) and 2.072 (2) Å, and the Pd—Cl bond lengths are 2.3055 (8) and 2.3160 (8) Å. In the crystal, pairs of N—H⋯Cl hydrogen bonds link mol­ecules into discrete dimers. International Union of Crystallography 2013-04-05 /pmc/articles/PMC3647791/ /pubmed/23723757 http://dx.doi.org/10.1107/S1600536813008271 Text en © Nayab et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Nayab, Saira
Lee, Hong-In
Jeong, Jong Hwa
Dichlorido{2,6-diisopropyl-N-[(S)-pyrrolidin-2-ylmeth­yl]aniline-κ(2) N,N′}palladium(II)
title Dichlorido{2,6-diisopropyl-N-[(S)-pyrrolidin-2-ylmeth­yl]aniline-κ(2) N,N′}palladium(II)
title_full Dichlorido{2,6-diisopropyl-N-[(S)-pyrrolidin-2-ylmeth­yl]aniline-κ(2) N,N′}palladium(II)
title_fullStr Dichlorido{2,6-diisopropyl-N-[(S)-pyrrolidin-2-ylmeth­yl]aniline-κ(2) N,N′}palladium(II)
title_full_unstemmed Dichlorido{2,6-diisopropyl-N-[(S)-pyrrolidin-2-ylmeth­yl]aniline-κ(2) N,N′}palladium(II)
title_short Dichlorido{2,6-diisopropyl-N-[(S)-pyrrolidin-2-ylmeth­yl]aniline-κ(2) N,N′}palladium(II)
title_sort dichlorido{2,6-diisopropyl-n-[(s)-pyrrolidin-2-ylmeth­yl]aniline-κ(2) n,n′}palladium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647791/
https://www.ncbi.nlm.nih.gov/pubmed/23723757
http://dx.doi.org/10.1107/S1600536813008271
work_keys_str_mv AT nayabsaira dichlorido26diisopropylnspyrrolidin2ylmethylanilinek2nnpalladiumii
AT leehongin dichlorido26diisopropylnspyrrolidin2ylmethylanilinek2nnpalladiumii
AT jeongjonghwa dichlorido26diisopropylnspyrrolidin2ylmethylanilinek2nnpalladiumii