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Dichlorido{2,6-diisopropyl-N-[(S)-pyrrolidin-2-ylmethyl]aniline-κ(2) N,N′}palladium(II)
In the title compound, [PdCl(2)(C(17)H(28)N(2))], the Pd(II) atom displays a square-planar coordination involving two N atoms of a 2,6-diisopropyl-N-[(S)-pyrrolidin-2-ylmethyl]aniline ligand and two chloride ligands, with a deviation of 0.090 (1) Å for the Pd(II) atom from the best plane. The absol...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647791/ https://www.ncbi.nlm.nih.gov/pubmed/23723757 http://dx.doi.org/10.1107/S1600536813008271 |
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author | Nayab, Saira Lee, Hong-In Jeong, Jong Hwa |
author_facet | Nayab, Saira Lee, Hong-In Jeong, Jong Hwa |
author_sort | Nayab, Saira |
collection | PubMed |
description | In the title compound, [PdCl(2)(C(17)H(28)N(2))], the Pd(II) atom displays a square-planar coordination involving two N atoms of a 2,6-diisopropyl-N-[(S)-pyrrolidin-2-ylmethyl]aniline ligand and two chloride ligands, with a deviation of 0.090 (1) Å for the Pd(II) atom from the best plane. The absolute configuration of the chiral C atom of the pyrrolidine ring is S, which induces R configurations at the two N atoms of the aniline ligand. Optical isomerism arising from the chelate five-membered ring is configured as δ. The Pd—N bond lengths are 2.040 (3) and 2.072 (2) Å, and the Pd—Cl bond lengths are 2.3055 (8) and 2.3160 (8) Å. In the crystal, pairs of N—H⋯Cl hydrogen bonds link molecules into discrete dimers. |
format | Online Article Text |
id | pubmed-3647791 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36477912013-05-30 Dichlorido{2,6-diisopropyl-N-[(S)-pyrrolidin-2-ylmethyl]aniline-κ(2) N,N′}palladium(II) Nayab, Saira Lee, Hong-In Jeong, Jong Hwa Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [PdCl(2)(C(17)H(28)N(2))], the Pd(II) atom displays a square-planar coordination involving two N atoms of a 2,6-diisopropyl-N-[(S)-pyrrolidin-2-ylmethyl]aniline ligand and two chloride ligands, with a deviation of 0.090 (1) Å for the Pd(II) atom from the best plane. The absolute configuration of the chiral C atom of the pyrrolidine ring is S, which induces R configurations at the two N atoms of the aniline ligand. Optical isomerism arising from the chelate five-membered ring is configured as δ. The Pd—N bond lengths are 2.040 (3) and 2.072 (2) Å, and the Pd—Cl bond lengths are 2.3055 (8) and 2.3160 (8) Å. In the crystal, pairs of N—H⋯Cl hydrogen bonds link molecules into discrete dimers. International Union of Crystallography 2013-04-05 /pmc/articles/PMC3647791/ /pubmed/23723757 http://dx.doi.org/10.1107/S1600536813008271 Text en © Nayab et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Nayab, Saira Lee, Hong-In Jeong, Jong Hwa Dichlorido{2,6-diisopropyl-N-[(S)-pyrrolidin-2-ylmethyl]aniline-κ(2) N,N′}palladium(II) |
title | Dichlorido{2,6-diisopropyl-N-[(S)-pyrrolidin-2-ylmethyl]aniline-κ(2)
N,N′}palladium(II) |
title_full | Dichlorido{2,6-diisopropyl-N-[(S)-pyrrolidin-2-ylmethyl]aniline-κ(2)
N,N′}palladium(II) |
title_fullStr | Dichlorido{2,6-diisopropyl-N-[(S)-pyrrolidin-2-ylmethyl]aniline-κ(2)
N,N′}palladium(II) |
title_full_unstemmed | Dichlorido{2,6-diisopropyl-N-[(S)-pyrrolidin-2-ylmethyl]aniline-κ(2)
N,N′}palladium(II) |
title_short | Dichlorido{2,6-diisopropyl-N-[(S)-pyrrolidin-2-ylmethyl]aniline-κ(2)
N,N′}palladium(II) |
title_sort | dichlorido{2,6-diisopropyl-n-[(s)-pyrrolidin-2-ylmethyl]aniline-κ(2)
n,n′}palladium(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647791/ https://www.ncbi.nlm.nih.gov/pubmed/23723757 http://dx.doi.org/10.1107/S1600536813008271 |
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