Bis[2-(hy­droxy­imino)­cyclo­hexan-1-one oximato-κ(2) N,N′]copper(II)

In the title compound, [Cu(C(6)H(9)N(2)O(2))(2)], the Cu(II) atom is located on an inversion center and has a square-planar environment. Two 2-(hy­droxy­imino)­cyclo­hexan-1-one oxim­ate monoanions chelate to the Cu(II) atom and the Cu—N distances are 1.920 (3) and 1.930 (3) Å. There are two short i...

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Detalles Bibliográficos
Autores principales: Melnic, Elena, Coropceanu, Eduard B., Croitor, Lilia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647792/
https://www.ncbi.nlm.nih.gov/pubmed/23723758
http://dx.doi.org/10.1107/S160053681300785X
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author Melnic, Elena
Coropceanu, Eduard B.
Croitor, Lilia
author_facet Melnic, Elena
Coropceanu, Eduard B.
Croitor, Lilia
author_sort Melnic, Elena
collection PubMed
description In the title compound, [Cu(C(6)H(9)N(2)O(2))(2)], the Cu(II) atom is located on an inversion center and has a square-planar environment. Two 2-(hy­droxy­imino)­cyclo­hexan-1-one oxim­ate monoanions chelate to the Cu(II) atom and the Cu—N distances are 1.920 (3) and 1.930 (3) Å. There are two short intra­molecular O—H⋯O hydrogen bonds between the ligands. The complex mol­ecules stack into columns extended along the c axis, with a Cu⋯Cu distance between adjacent mol­ecules of 3.3060 (3) Å.
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spelling pubmed-36477922013-05-30 Bis[2-(hy­droxy­imino)­cyclo­hexan-1-one oximato-κ(2) N,N′]copper(II) Melnic, Elena Coropceanu, Eduard B. Croitor, Lilia Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(6)H(9)N(2)O(2))(2)], the Cu(II) atom is located on an inversion center and has a square-planar environment. Two 2-(hy­droxy­imino)­cyclo­hexan-1-one oxim­ate monoanions chelate to the Cu(II) atom and the Cu—N distances are 1.920 (3) and 1.930 (3) Å. There are two short intra­molecular O—H⋯O hydrogen bonds between the ligands. The complex mol­ecules stack into columns extended along the c axis, with a Cu⋯Cu distance between adjacent mol­ecules of 3.3060 (3) Å. International Union of Crystallography 2013-04-05 /pmc/articles/PMC3647792/ /pubmed/23723758 http://dx.doi.org/10.1107/S160053681300785X Text en © Melnic et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Melnic, Elena
Coropceanu, Eduard B.
Croitor, Lilia
Bis[2-(hy­droxy­imino)­cyclo­hexan-1-one oximato-κ(2) N,N′]copper(II)
title Bis[2-(hy­droxy­imino)­cyclo­hexan-1-one oximato-κ(2) N,N′]copper(II)
title_full Bis[2-(hy­droxy­imino)­cyclo­hexan-1-one oximato-κ(2) N,N′]copper(II)
title_fullStr Bis[2-(hy­droxy­imino)­cyclo­hexan-1-one oximato-κ(2) N,N′]copper(II)
title_full_unstemmed Bis[2-(hy­droxy­imino)­cyclo­hexan-1-one oximato-κ(2) N,N′]copper(II)
title_short Bis[2-(hy­droxy­imino)­cyclo­hexan-1-one oximato-κ(2) N,N′]copper(II)
title_sort bis[2-(hy­droxy­imino)­cyclo­hexan-1-one oximato-κ(2) n,n′]copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647792/
https://www.ncbi.nlm.nih.gov/pubmed/23723758
http://dx.doi.org/10.1107/S160053681300785X
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