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Dichloridobis{2-[(1H-1,2,4-triazol-1-yl)meth­yl]-1H-benzimidazole-κN (3)}­zinc(II)

In the title complex, [ZnCl(2)(C(10)H(9)N(5))(2)], the Zn(II) ion is coordinated by two N atoms from two 2-[(1H-1,2,4-triazol-1-yl)meth­yl]-1H-benzimidazole (tmb) ligands and by two chloride ligands in a slightly distorted tetra­hedral geometry. In the tmb ligands, the benzimidazole rings systems ar...

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Autores principales: Zhang, Wei-Peng, Zhang, Jiao-Lin, Hao, Bao-Lian, Yang, Huai-Xia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647793/
https://www.ncbi.nlm.nih.gov/pubmed/23723759
http://dx.doi.org/10.1107/S1600536813008283
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author Zhang, Wei-Peng
Zhang, Jiao-Lin
Hao, Bao-Lian
Yang, Huai-Xia
author_facet Zhang, Wei-Peng
Zhang, Jiao-Lin
Hao, Bao-Lian
Yang, Huai-Xia
author_sort Zhang, Wei-Peng
collection PubMed
description In the title complex, [ZnCl(2)(C(10)H(9)N(5))(2)], the Zn(II) ion is coordinated by two N atoms from two 2-[(1H-1,2,4-triazol-1-yl)meth­yl]-1H-benzimidazole (tmb) ligands and by two chloride ligands in a slightly distorted tetra­hedral geometry. In the tmb ligands, the benzimidazole rings systems are essentially planar, with maximum deviations from the mean plane of 0.021 (3) and 0.030 (3) Å, and form dihedral angles of 73.2 (2) and 83.5 (2)° with the triazole rings. In the crystal, N—H⋯N hydrogen bonds link complex mol­ecules into chains along [010]. In addition, weak C—H⋯Cl and C—H⋯N hydrogen bonds complete a three-dimensional network. Two weak intra­molecular C—H⋯Cl hydrogen bonds are also observed.
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spelling pubmed-36477932013-05-30 Dichloridobis{2-[(1H-1,2,4-triazol-1-yl)meth­yl]-1H-benzimidazole-κN (3)}­zinc(II) Zhang, Wei-Peng Zhang, Jiao-Lin Hao, Bao-Lian Yang, Huai-Xia Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [ZnCl(2)(C(10)H(9)N(5))(2)], the Zn(II) ion is coordinated by two N atoms from two 2-[(1H-1,2,4-triazol-1-yl)meth­yl]-1H-benzimidazole (tmb) ligands and by two chloride ligands in a slightly distorted tetra­hedral geometry. In the tmb ligands, the benzimidazole rings systems are essentially planar, with maximum deviations from the mean plane of 0.021 (3) and 0.030 (3) Å, and form dihedral angles of 73.2 (2) and 83.5 (2)° with the triazole rings. In the crystal, N—H⋯N hydrogen bonds link complex mol­ecules into chains along [010]. In addition, weak C—H⋯Cl and C—H⋯N hydrogen bonds complete a three-dimensional network. Two weak intra­molecular C—H⋯Cl hydrogen bonds are also observed. International Union of Crystallography 2013-04-05 /pmc/articles/PMC3647793/ /pubmed/23723759 http://dx.doi.org/10.1107/S1600536813008283 Text en © Zhang et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Wei-Peng
Zhang, Jiao-Lin
Hao, Bao-Lian
Yang, Huai-Xia
Dichloridobis{2-[(1H-1,2,4-triazol-1-yl)meth­yl]-1H-benzimidazole-κN (3)}­zinc(II)
title Dichloridobis{2-[(1H-1,2,4-triazol-1-yl)meth­yl]-1H-benzimidazole-κN (3)}­zinc(II)
title_full Dichloridobis{2-[(1H-1,2,4-triazol-1-yl)meth­yl]-1H-benzimidazole-κN (3)}­zinc(II)
title_fullStr Dichloridobis{2-[(1H-1,2,4-triazol-1-yl)meth­yl]-1H-benzimidazole-κN (3)}­zinc(II)
title_full_unstemmed Dichloridobis{2-[(1H-1,2,4-triazol-1-yl)meth­yl]-1H-benzimidazole-κN (3)}­zinc(II)
title_short Dichloridobis{2-[(1H-1,2,4-triazol-1-yl)meth­yl]-1H-benzimidazole-κN (3)}­zinc(II)
title_sort dichloridobis{2-[(1h-1,2,4-triazol-1-yl)meth­yl]-1h-benzimidazole-κn (3)}­zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647793/
https://www.ncbi.nlm.nih.gov/pubmed/23723759
http://dx.doi.org/10.1107/S1600536813008283
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