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Dichloridobis{2-[(1H-1,2,4-triazol-1-yl)methyl]-1H-benzimidazole-κN (3)}zinc(II)
In the title complex, [ZnCl(2)(C(10)H(9)N(5))(2)], the Zn(II) ion is coordinated by two N atoms from two 2-[(1H-1,2,4-triazol-1-yl)methyl]-1H-benzimidazole (tmb) ligands and by two chloride ligands in a slightly distorted tetrahedral geometry. In the tmb ligands, the benzimidazole rings systems ar...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647793/ https://www.ncbi.nlm.nih.gov/pubmed/23723759 http://dx.doi.org/10.1107/S1600536813008283 |
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author | Zhang, Wei-Peng Zhang, Jiao-Lin Hao, Bao-Lian Yang, Huai-Xia |
author_facet | Zhang, Wei-Peng Zhang, Jiao-Lin Hao, Bao-Lian Yang, Huai-Xia |
author_sort | Zhang, Wei-Peng |
collection | PubMed |
description | In the title complex, [ZnCl(2)(C(10)H(9)N(5))(2)], the Zn(II) ion is coordinated by two N atoms from two 2-[(1H-1,2,4-triazol-1-yl)methyl]-1H-benzimidazole (tmb) ligands and by two chloride ligands in a slightly distorted tetrahedral geometry. In the tmb ligands, the benzimidazole rings systems are essentially planar, with maximum deviations from the mean plane of 0.021 (3) and 0.030 (3) Å, and form dihedral angles of 73.2 (2) and 83.5 (2)° with the triazole rings. In the crystal, N—H⋯N hydrogen bonds link complex molecules into chains along [010]. In addition, weak C—H⋯Cl and C—H⋯N hydrogen bonds complete a three-dimensional network. Two weak intramolecular C—H⋯Cl hydrogen bonds are also observed. |
format | Online Article Text |
id | pubmed-3647793 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36477932013-05-30 Dichloridobis{2-[(1H-1,2,4-triazol-1-yl)methyl]-1H-benzimidazole-κN (3)}zinc(II) Zhang, Wei-Peng Zhang, Jiao-Lin Hao, Bao-Lian Yang, Huai-Xia Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [ZnCl(2)(C(10)H(9)N(5))(2)], the Zn(II) ion is coordinated by two N atoms from two 2-[(1H-1,2,4-triazol-1-yl)methyl]-1H-benzimidazole (tmb) ligands and by two chloride ligands in a slightly distorted tetrahedral geometry. In the tmb ligands, the benzimidazole rings systems are essentially planar, with maximum deviations from the mean plane of 0.021 (3) and 0.030 (3) Å, and form dihedral angles of 73.2 (2) and 83.5 (2)° with the triazole rings. In the crystal, N—H⋯N hydrogen bonds link complex molecules into chains along [010]. In addition, weak C—H⋯Cl and C—H⋯N hydrogen bonds complete a three-dimensional network. Two weak intramolecular C—H⋯Cl hydrogen bonds are also observed. International Union of Crystallography 2013-04-05 /pmc/articles/PMC3647793/ /pubmed/23723759 http://dx.doi.org/10.1107/S1600536813008283 Text en © Zhang et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhang, Wei-Peng Zhang, Jiao-Lin Hao, Bao-Lian Yang, Huai-Xia Dichloridobis{2-[(1H-1,2,4-triazol-1-yl)methyl]-1H-benzimidazole-κN (3)}zinc(II) |
title | Dichloridobis{2-[(1H-1,2,4-triazol-1-yl)methyl]-1H-benzimidazole-κN
(3)}zinc(II) |
title_full | Dichloridobis{2-[(1H-1,2,4-triazol-1-yl)methyl]-1H-benzimidazole-κN
(3)}zinc(II) |
title_fullStr | Dichloridobis{2-[(1H-1,2,4-triazol-1-yl)methyl]-1H-benzimidazole-κN
(3)}zinc(II) |
title_full_unstemmed | Dichloridobis{2-[(1H-1,2,4-triazol-1-yl)methyl]-1H-benzimidazole-κN
(3)}zinc(II) |
title_short | Dichloridobis{2-[(1H-1,2,4-triazol-1-yl)methyl]-1H-benzimidazole-κN
(3)}zinc(II) |
title_sort | dichloridobis{2-[(1h-1,2,4-triazol-1-yl)methyl]-1h-benzimidazole-κn
(3)}zinc(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647793/ https://www.ncbi.nlm.nih.gov/pubmed/23723759 http://dx.doi.org/10.1107/S1600536813008283 |
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