Tetra­aceto­nitrile­lithium tetra­iso­thio­cyanato­borate

The crystal structure of the title salt, [Li(CH(3)CN)(4)][B(NCS)(4)], is composed of discrete cations and anions. Both the Li and B atoms show a tetra­hedral coordination by four equal ligands. The aceto­nitrile and iso­thio­cyanate ligands are linear. The bond angles at the B atom are close to the...

Descripción completa

Detalles Bibliográficos
Autores principales: Breunig, Jens Michael, Wietelmann, Ulrich, Lerner, Hans-Wolfram, Bolte, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647800/
https://www.ncbi.nlm.nih.gov/pubmed/23723766
http://dx.doi.org/10.1107/S1600536813009082
Descripción
Sumario:The crystal structure of the title salt, [Li(CH(3)CN)(4)][B(NCS)(4)], is composed of discrete cations and anions. Both the Li and B atoms show a tetra­hedral coordination by four equal ligands. The aceto­nitrile and iso­thio­cyanate ligands are linear. The bond angles at the B atom are close to the ideal tetra­hedral value [108.92 (18)–109.94 (16)°], but the bond angles at the Li atom show larger deviations [106.15 (17)–113.70 (17)°].

Ejemplares similares