Tetra­aceto­nitrile­lithium tetra­iso­thio­cyanato­borate

The crystal structure of the title salt, [Li(CH(3)CN)(4)][B(NCS)(4)], is composed of discrete cations and anions. Both the Li and B atoms show a tetra­hedral coordination by four equal ligands. The aceto­nitrile and iso­thio­cyanate ligands are linear. The bond angles at the B atom are close to the...

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Autores principales: Breunig, Jens Michael, Wietelmann, Ulrich, Lerner, Hans-Wolfram, Bolte, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647800/
https://www.ncbi.nlm.nih.gov/pubmed/23723766
http://dx.doi.org/10.1107/S1600536813009082
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author Breunig, Jens Michael
Wietelmann, Ulrich
Lerner, Hans-Wolfram
Bolte, Michael
author_facet Breunig, Jens Michael
Wietelmann, Ulrich
Lerner, Hans-Wolfram
Bolte, Michael
author_sort Breunig, Jens Michael
collection PubMed
description The crystal structure of the title salt, [Li(CH(3)CN)(4)][B(NCS)(4)], is composed of discrete cations and anions. Both the Li and B atoms show a tetra­hedral coordination by four equal ligands. The aceto­nitrile and iso­thio­cyanate ligands are linear. The bond angles at the B atom are close to the ideal tetra­hedral value [108.92 (18)–109.94 (16)°], but the bond angles at the Li atom show larger deviations [106.15 (17)–113.70 (17)°].
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spelling pubmed-36478002013-05-30 Tetra­aceto­nitrile­lithium tetra­iso­thio­cyanato­borate Breunig, Jens Michael Wietelmann, Ulrich Lerner, Hans-Wolfram Bolte, Michael Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title salt, [Li(CH(3)CN)(4)][B(NCS)(4)], is composed of discrete cations and anions. Both the Li and B atoms show a tetra­hedral coordination by four equal ligands. The aceto­nitrile and iso­thio­cyanate ligands are linear. The bond angles at the B atom are close to the ideal tetra­hedral value [108.92 (18)–109.94 (16)°], but the bond angles at the Li atom show larger deviations [106.15 (17)–113.70 (17)°]. International Union of Crystallography 2013-04-10 /pmc/articles/PMC3647800/ /pubmed/23723766 http://dx.doi.org/10.1107/S1600536813009082 Text en © Breunig et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Breunig, Jens Michael
Wietelmann, Ulrich
Lerner, Hans-Wolfram
Bolte, Michael
Tetra­aceto­nitrile­lithium tetra­iso­thio­cyanato­borate
title Tetra­aceto­nitrile­lithium tetra­iso­thio­cyanato­borate
title_full Tetra­aceto­nitrile­lithium tetra­iso­thio­cyanato­borate
title_fullStr Tetra­aceto­nitrile­lithium tetra­iso­thio­cyanato­borate
title_full_unstemmed Tetra­aceto­nitrile­lithium tetra­iso­thio­cyanato­borate
title_short Tetra­aceto­nitrile­lithium tetra­iso­thio­cyanato­borate
title_sort tetra­aceto­nitrile­lithium tetra­iso­thio­cyanato­borate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647800/
https://www.ncbi.nlm.nih.gov/pubmed/23723766
http://dx.doi.org/10.1107/S1600536813009082
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AT wietelmannulrich tetraacetonitrilelithiumtetraisothiocyanatoborate
AT lernerhanswolfram tetraacetonitrilelithiumtetraisothiocyanatoborate
AT boltemichael tetraacetonitrilelithiumtetraisothiocyanatoborate

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