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Diacetatodi-tert-butyltin(IV)

The title compound, [Sn(C(4)H(9))(2)(CH(3)COO)(2)], was synthesized in order to study the influence of large organic groups on the mol­ecular structure of diorganotin di­acetates. The title compound exhibits the same structure type as other diorganotin(IV) di­acetates characterized by an unsymmetric...

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Detalles Bibliográficos
Autores principales: Reichelt, Martin, Reuter, Hans
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647801/
https://www.ncbi.nlm.nih.gov/pubmed/23723767
http://dx.doi.org/10.1107/S1600536813009185
Descripción
Sumario:The title compound, [Sn(C(4)H(9))(2)(CH(3)COO)(2)], was synthesized in order to study the influence of large organic groups on the mol­ecular structure of diorganotin di­acetates. The title compound exhibits the same structure type as other diorganotin(IV) di­acetates characterized by an unsymmetrical bidentate bonding mode of the two acetate groups to tin. The influence of the t-butyl groups on this mol­ecular structure is expressed in two significant differences: tin—carbon bond lengths are much more longer than in the other di­acetates, as are the additional inter­actions of the acetate groups with the tin atom. Inter­molecular inter­actions are restricted to C—H⋯O ones similar to those in the other di­acetates, giving rise to a chain-like arrangement of the molecules with the tin atoms and acetate groups in the propagation plane.