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Diacetatodi-tert-butyltin(IV)

The title compound, [Sn(C(4)H(9))(2)(CH(3)COO)(2)], was synthesized in order to study the influence of large organic groups on the mol­ecular structure of diorganotin di­acetates. The title compound exhibits the same structure type as other diorganotin(IV) di­acetates characterized by an unsymmetric...

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Detalles Bibliográficos
Autores principales: Reichelt, Martin, Reuter, Hans
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647801/
https://www.ncbi.nlm.nih.gov/pubmed/23723767
http://dx.doi.org/10.1107/S1600536813009185
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author Reichelt, Martin
Reuter, Hans
author_facet Reichelt, Martin
Reuter, Hans
author_sort Reichelt, Martin
collection PubMed
description The title compound, [Sn(C(4)H(9))(2)(CH(3)COO)(2)], was synthesized in order to study the influence of large organic groups on the mol­ecular structure of diorganotin di­acetates. The title compound exhibits the same structure type as other diorganotin(IV) di­acetates characterized by an unsymmetrical bidentate bonding mode of the two acetate groups to tin. The influence of the t-butyl groups on this mol­ecular structure is expressed in two significant differences: tin—carbon bond lengths are much more longer than in the other di­acetates, as are the additional inter­actions of the acetate groups with the tin atom. Inter­molecular inter­actions are restricted to C—H⋯O ones similar to those in the other di­acetates, giving rise to a chain-like arrangement of the molecules with the tin atoms and acetate groups in the propagation plane.
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spelling pubmed-36478012013-05-30 Diacetatodi-tert-butyltin(IV) Reichelt, Martin Reuter, Hans Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Sn(C(4)H(9))(2)(CH(3)COO)(2)], was synthesized in order to study the influence of large organic groups on the mol­ecular structure of diorganotin di­acetates. The title compound exhibits the same structure type as other diorganotin(IV) di­acetates characterized by an unsymmetrical bidentate bonding mode of the two acetate groups to tin. The influence of the t-butyl groups on this mol­ecular structure is expressed in two significant differences: tin—carbon bond lengths are much more longer than in the other di­acetates, as are the additional inter­actions of the acetate groups with the tin atom. Inter­molecular inter­actions are restricted to C—H⋯O ones similar to those in the other di­acetates, giving rise to a chain-like arrangement of the molecules with the tin atoms and acetate groups in the propagation plane. International Union of Crystallography 2013-04-13 /pmc/articles/PMC3647801/ /pubmed/23723767 http://dx.doi.org/10.1107/S1600536813009185 Text en © Reichelt and Reuter 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Reichelt, Martin
Reuter, Hans
Diacetatodi-tert-butyltin(IV)
title Diacetatodi-tert-butyltin(IV)
title_full Diacetatodi-tert-butyltin(IV)
title_fullStr Diacetatodi-tert-butyltin(IV)
title_full_unstemmed Diacetatodi-tert-butyltin(IV)
title_short Diacetatodi-tert-butyltin(IV)
title_sort diacetatodi-tert-butyltin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647801/
https://www.ncbi.nlm.nih.gov/pubmed/23723767
http://dx.doi.org/10.1107/S1600536813009185
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