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Diacetatodi-tert-butyltin(IV)
The title compound, [Sn(C(4)H(9))(2)(CH(3)COO)(2)], was synthesized in order to study the influence of large organic groups on the molecular structure of diorganotin diacetates. The title compound exhibits the same structure type as other diorganotin(IV) diacetates characterized by an unsymmetric...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647801/ https://www.ncbi.nlm.nih.gov/pubmed/23723767 http://dx.doi.org/10.1107/S1600536813009185 |
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author | Reichelt, Martin Reuter, Hans |
author_facet | Reichelt, Martin Reuter, Hans |
author_sort | Reichelt, Martin |
collection | PubMed |
description | The title compound, [Sn(C(4)H(9))(2)(CH(3)COO)(2)], was synthesized in order to study the influence of large organic groups on the molecular structure of diorganotin diacetates. The title compound exhibits the same structure type as other diorganotin(IV) diacetates characterized by an unsymmetrical bidentate bonding mode of the two acetate groups to tin. The influence of the t-butyl groups on this molecular structure is expressed in two significant differences: tin—carbon bond lengths are much more longer than in the other diacetates, as are the additional interactions of the acetate groups with the tin atom. Intermolecular interactions are restricted to C—H⋯O ones similar to those in the other diacetates, giving rise to a chain-like arrangement of the molecules with the tin atoms and acetate groups in the propagation plane. |
format | Online Article Text |
id | pubmed-3647801 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36478012013-05-30 Diacetatodi-tert-butyltin(IV) Reichelt, Martin Reuter, Hans Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Sn(C(4)H(9))(2)(CH(3)COO)(2)], was synthesized in order to study the influence of large organic groups on the molecular structure of diorganotin diacetates. The title compound exhibits the same structure type as other diorganotin(IV) diacetates characterized by an unsymmetrical bidentate bonding mode of the two acetate groups to tin. The influence of the t-butyl groups on this molecular structure is expressed in two significant differences: tin—carbon bond lengths are much more longer than in the other diacetates, as are the additional interactions of the acetate groups with the tin atom. Intermolecular interactions are restricted to C—H⋯O ones similar to those in the other diacetates, giving rise to a chain-like arrangement of the molecules with the tin atoms and acetate groups in the propagation plane. International Union of Crystallography 2013-04-13 /pmc/articles/PMC3647801/ /pubmed/23723767 http://dx.doi.org/10.1107/S1600536813009185 Text en © Reichelt and Reuter 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Reichelt, Martin Reuter, Hans Diacetatodi-tert-butyltin(IV) |
title | Diacetatodi-tert-butyltin(IV) |
title_full | Diacetatodi-tert-butyltin(IV) |
title_fullStr | Diacetatodi-tert-butyltin(IV) |
title_full_unstemmed | Diacetatodi-tert-butyltin(IV) |
title_short | Diacetatodi-tert-butyltin(IV) |
title_sort | diacetatodi-tert-butyltin(iv) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647801/ https://www.ncbi.nlm.nih.gov/pubmed/23723767 http://dx.doi.org/10.1107/S1600536813009185 |
work_keys_str_mv | AT reicheltmartin diacetatoditertbutyltiniv AT reuterhans diacetatoditertbutyltiniv |