Cargando…
catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)copper(II)]-μ-2,2′-iminodibenzoato-κ(4) O,O′:O′′,O′′′]
The structure of the title compound, [Cu(C(14)H(9)NO(4))(C(12)H(8)N(2))](n), consists of zigzag polymeric chains along the c axis. The asymmetric unit contains one Cu(II) atom which is coordinated by one 2,2′-iminodibenzoate ligand and a one phenanthroline unit. Two intramolecular N—H⋯O hydrogen b...
Autores principales: | , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647802/ https://www.ncbi.nlm.nih.gov/pubmed/23723768 http://dx.doi.org/10.1107/S1600536813009203 |
Sumario: | The structure of the title compound, [Cu(C(14)H(9)NO(4))(C(12)H(8)N(2))](n), consists of zigzag polymeric chains along the c axis. The asymmetric unit contains one Cu(II) atom which is coordinated by one 2,2′-iminodibenzoate ligand and a one phenanthroline unit. Two intramolecular N—H⋯O hydrogen bonds occur. The supramolecular structure is characterized by weak C—H⋯O hydrogen bonds and π–π stacking interactions, forming a three-dimensional supramolecular network. The shortest centroid–centroid distances between neighbouring phenanthroline aromatic rings and 2,2′-iminodibenzoate rings are 3.684 (1) and 3.640 Å, respectively. The shortest intrachain Cu⋯Cu distance is 7.2885 (9) and the shortest Cu⋯Cu distance between Cu atoms in different chains is 7.1103 (6) Å. |
---|