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catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)copper(II)]-μ-2,2′-iminodibenzoato-κ(4) O,O′:O′′,O′′′]
The structure of the title compound, [Cu(C(14)H(9)NO(4))(C(12)H(8)N(2))](n), consists of zigzag polymeric chains along the c axis. The asymmetric unit contains one Cu(II) atom which is coordinated by one 2,2′-iminodibenzoate ligand and a one phenanthroline unit. Two intramolecular N—H⋯O hydrogen b...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647802/ https://www.ncbi.nlm.nih.gov/pubmed/23723768 http://dx.doi.org/10.1107/S1600536813009203 |
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author | Yuste-Vivas, Consuelo Coutinho, Joana T. Pereira, Laura C. J. Silva, Manuela Ramos |
author_facet | Yuste-Vivas, Consuelo Coutinho, Joana T. Pereira, Laura C. J. Silva, Manuela Ramos |
author_sort | Yuste-Vivas, Consuelo |
collection | PubMed |
description | The structure of the title compound, [Cu(C(14)H(9)NO(4))(C(12)H(8)N(2))](n), consists of zigzag polymeric chains along the c axis. The asymmetric unit contains one Cu(II) atom which is coordinated by one 2,2′-iminodibenzoate ligand and a one phenanthroline unit. Two intramolecular N—H⋯O hydrogen bonds occur. The supramolecular structure is characterized by weak C—H⋯O hydrogen bonds and π–π stacking interactions, forming a three-dimensional supramolecular network. The shortest centroid–centroid distances between neighbouring phenanthroline aromatic rings and 2,2′-iminodibenzoate rings are 3.684 (1) and 3.640 Å, respectively. The shortest intrachain Cu⋯Cu distance is 7.2885 (9) and the shortest Cu⋯Cu distance between Cu atoms in different chains is 7.1103 (6) Å. |
format | Online Article Text |
id | pubmed-3647802 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36478022013-05-30 catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)copper(II)]-μ-2,2′-iminodibenzoato-κ(4) O,O′:O′′,O′′′] Yuste-Vivas, Consuelo Coutinho, Joana T. Pereira, Laura C. J. Silva, Manuela Ramos Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, [Cu(C(14)H(9)NO(4))(C(12)H(8)N(2))](n), consists of zigzag polymeric chains along the c axis. The asymmetric unit contains one Cu(II) atom which is coordinated by one 2,2′-iminodibenzoate ligand and a one phenanthroline unit. Two intramolecular N—H⋯O hydrogen bonds occur. The supramolecular structure is characterized by weak C—H⋯O hydrogen bonds and π–π stacking interactions, forming a three-dimensional supramolecular network. The shortest centroid–centroid distances between neighbouring phenanthroline aromatic rings and 2,2′-iminodibenzoate rings are 3.684 (1) and 3.640 Å, respectively. The shortest intrachain Cu⋯Cu distance is 7.2885 (9) and the shortest Cu⋯Cu distance between Cu atoms in different chains is 7.1103 (6) Å. International Union of Crystallography 2013-04-13 /pmc/articles/PMC3647802/ /pubmed/23723768 http://dx.doi.org/10.1107/S1600536813009203 Text en © Yuste-Vivas et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Yuste-Vivas, Consuelo Coutinho, Joana T. Pereira, Laura C. J. Silva, Manuela Ramos catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)copper(II)]-μ-2,2′-iminodibenzoato-κ(4) O,O′:O′′,O′′′] |
title |
catena-Poly[[(1,10-phenanthroline-κ(2)
N,N′)copper(II)]-μ-2,2′-iminodibenzoato-κ(4)
O,O′:O′′,O′′′] |
title_full |
catena-Poly[[(1,10-phenanthroline-κ(2)
N,N′)copper(II)]-μ-2,2′-iminodibenzoato-κ(4)
O,O′:O′′,O′′′] |
title_fullStr |
catena-Poly[[(1,10-phenanthroline-κ(2)
N,N′)copper(II)]-μ-2,2′-iminodibenzoato-κ(4)
O,O′:O′′,O′′′] |
title_full_unstemmed |
catena-Poly[[(1,10-phenanthroline-κ(2)
N,N′)copper(II)]-μ-2,2′-iminodibenzoato-κ(4)
O,O′:O′′,O′′′] |
title_short |
catena-Poly[[(1,10-phenanthroline-κ(2)
N,N′)copper(II)]-μ-2,2′-iminodibenzoato-κ(4)
O,O′:O′′,O′′′] |
title_sort | catena-poly[[(1,10-phenanthroline-κ(2)
n,n′)copper(ii)]-μ-2,2′-iminodibenzoato-κ(4)
o,o′:o′′,o′′′] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647802/ https://www.ncbi.nlm.nih.gov/pubmed/23723768 http://dx.doi.org/10.1107/S1600536813009203 |
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