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catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)copper(II)]-μ-2,2′-iminodibenzoato-κ(4) O,O′:O′′,O′′′]

The structure of the title compound, [Cu(C(14)H(9)NO(4))(C(12)H(8)N(2))](n), consists of zigzag polymeric chains along the c axis. The asymmetric unit contains one Cu(II) atom which is coordinated by one 2,2′-imino­dibenzoate ligand and a one phenanthroline unit. Two intra­molecular N—H⋯O hydrogen b...

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Autores principales: Yuste-Vivas, Consuelo, Coutinho, Joana T., Pereira, Laura C. J., Silva, Manuela Ramos
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647802/
https://www.ncbi.nlm.nih.gov/pubmed/23723768
http://dx.doi.org/10.1107/S1600536813009203
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author Yuste-Vivas, Consuelo
Coutinho, Joana T.
Pereira, Laura C. J.
Silva, Manuela Ramos
author_facet Yuste-Vivas, Consuelo
Coutinho, Joana T.
Pereira, Laura C. J.
Silva, Manuela Ramos
author_sort Yuste-Vivas, Consuelo
collection PubMed
description The structure of the title compound, [Cu(C(14)H(9)NO(4))(C(12)H(8)N(2))](n), consists of zigzag polymeric chains along the c axis. The asymmetric unit contains one Cu(II) atom which is coordinated by one 2,2′-imino­dibenzoate ligand and a one phenanthroline unit. Two intra­molecular N—H⋯O hydrogen bonds occur. The supra­molecular structure is characterized by weak C—H⋯O hydrogen bonds and π–π stacking inter­actions, forming a three-dimensional supramolecular network. The shortest centroid–centroid distances between neighbouring phenanthroline aromatic rings and 2,2′-imino­dibenzoate rings are 3.684 (1) and 3.640 Å, respectively. The shortest intra­chain Cu⋯Cu distance is 7.2885 (9) and the shortest Cu⋯Cu distance between Cu atoms in different chains is 7.1103 (6) Å.
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spelling pubmed-36478022013-05-30 catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)copper(II)]-μ-2,2′-iminodibenzoato-κ(4) O,O′:O′′,O′′′] Yuste-Vivas, Consuelo Coutinho, Joana T. Pereira, Laura C. J. Silva, Manuela Ramos Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, [Cu(C(14)H(9)NO(4))(C(12)H(8)N(2))](n), consists of zigzag polymeric chains along the c axis. The asymmetric unit contains one Cu(II) atom which is coordinated by one 2,2′-imino­dibenzoate ligand and a one phenanthroline unit. Two intra­molecular N—H⋯O hydrogen bonds occur. The supra­molecular structure is characterized by weak C—H⋯O hydrogen bonds and π–π stacking inter­actions, forming a three-dimensional supramolecular network. The shortest centroid–centroid distances between neighbouring phenanthroline aromatic rings and 2,2′-imino­dibenzoate rings are 3.684 (1) and 3.640 Å, respectively. The shortest intra­chain Cu⋯Cu distance is 7.2885 (9) and the shortest Cu⋯Cu distance between Cu atoms in different chains is 7.1103 (6) Å. International Union of Crystallography 2013-04-13 /pmc/articles/PMC3647802/ /pubmed/23723768 http://dx.doi.org/10.1107/S1600536813009203 Text en © Yuste-Vivas et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yuste-Vivas, Consuelo
Coutinho, Joana T.
Pereira, Laura C. J.
Silva, Manuela Ramos
catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)copper(II)]-μ-2,2′-iminodibenzoato-κ(4) O,O′:O′′,O′′′]
title catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)copper(II)]-μ-2,2′-iminodibenzoato-κ(4) O,O′:O′′,O′′′]
title_full catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)copper(II)]-μ-2,2′-iminodibenzoato-κ(4) O,O′:O′′,O′′′]
title_fullStr catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)copper(II)]-μ-2,2′-iminodibenzoato-κ(4) O,O′:O′′,O′′′]
title_full_unstemmed catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)copper(II)]-μ-2,2′-iminodibenzoato-κ(4) O,O′:O′′,O′′′]
title_short catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)copper(II)]-μ-2,2′-iminodibenzoato-κ(4) O,O′:O′′,O′′′]
title_sort catena-poly[[(1,10-phenanthroline-κ(2) n,n′)copper(ii)]-μ-2,2′-iminodibenzoato-κ(4) o,o′:o′′,o′′′]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647802/
https://www.ncbi.nlm.nih.gov/pubmed/23723768
http://dx.doi.org/10.1107/S1600536813009203
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