Aqua­bis­(4-methyl­benzene­sulfonato-κO)(η(5)-penta­methyl­cyclo­penta­dien­yl)rhodium(III) monohydrate

The title half-sandwich rhodium(III) complex, [Rh(C(10)H(15))(C(7)H(7)O(3)S)(2)(H(2)O)]·H(2)O, consists of a π-bonded penta­methyl­cyclo­penta­dienyl group, two σ-bonded tosyl­ate groups and an aqua ligand. The structure displays both inter- and intra­molecular O—H⋯O hydrogen bonding. The inter­mole...

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Detalles Bibliográficos
Autores principales: Roy, Christopher P., Boyer, Pauline M., Merola, Joseph S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647804/
https://www.ncbi.nlm.nih.gov/pubmed/23723770
http://dx.doi.org/10.1107/S160053681300860X
Descripción
Sumario:The title half-sandwich rhodium(III) complex, [Rh(C(10)H(15))(C(7)H(7)O(3)S)(2)(H(2)O)]·H(2)O, consists of a π-bonded penta­methyl­cyclo­penta­dienyl group, two σ-bonded tosyl­ate groups and an aqua ligand. The structure displays both inter- and intra­molecular O—H⋯O hydrogen bonding. The inter­molecular hydrogen bonding results in an extended helical chain along a 2(1) screw axis parallel to c, due to hydrogen bonding from the coordinating water ligand to the lattice water mol­ecule and then to a sulfonate O atom of a different asymmetric unit.

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