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(3,3′-{(1E,1′E)-1,1′-[Ethane-1,2-diylbis(azan-1-yl-1-ylidene-κN)]bis(ethan-1-yl-1-ylidene)}dipyrazine 1-oxide-κN (4))bis(nitrato-κO)nickel(II) monohydrate
In the title complex, [Ni(NO(3))(2)(C(14)H(16)N(6)O(2))]·H(2)O, the Ni(II) atom, lying on a twofold rotation axis, is coordinated by a tetradentate 3,3′-{(1E,1′E)-1,1′-[ethane-1,2-diylbis(azan-1-yl-1-ylidene)]bis(ethan-1-yl-1-ylidene)}dipyrazine 1-oxide ligand and two mutually trans monodentate...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647806/ https://www.ncbi.nlm.nih.gov/pubmed/23723772 http://dx.doi.org/10.1107/S1600536813009355 |
Sumario: | In the title complex, [Ni(NO(3))(2)(C(14)H(16)N(6)O(2))]·H(2)O, the Ni(II) atom, lying on a twofold rotation axis, is coordinated by a tetradentate 3,3′-{(1E,1′E)-1,1′-[ethane-1,2-diylbis(azan-1-yl-1-ylidene)]bis(ethan-1-yl-1-ylidene)}dipyrazine 1-oxide ligand and two mutually trans monodentate nitrate anions in a distorted octahedral geometry. The lattice water molecule is located on a twofold rotation axis. The complex molecules are linked by the water molecules through O—H⋯O hydrogen bonds into a chain along [001]. Further C—H⋯O hydrogen bonds lead to the formation of a three-dimensional network. |
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