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(3,3′-{(1E,1′E)-1,1′-[Ethane-1,2-diylbis(azan-1-yl-1-yl­idene-κN)]bis­(ethan-1-yl-1-yl­idene)}di­pyrazine 1-oxide-κN (4))bis­(nitrato-κO)nickel(II) monohydrate

In the title complex, [Ni(NO(3))(2)(C(14)H(16)N(6)O(2))]·H(2)O, the Ni(II) atom, lying on a twofold rotation axis, is coordinated by a tetra­dentate 3,3′-{(1E,1′E)-1,1′-[ethane-1,2-diylbis(azan-1-yl-1-yl­idene)]bis­(ethan-1-yl-1-yl­idene)}di­pyrazine 1-oxide ligand and two mutually trans monodentate...

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Detalles Bibliográficos
Autores principales: Omer, Mohammed A. S., Liu, Jia-Cheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647806/
https://www.ncbi.nlm.nih.gov/pubmed/23723772
http://dx.doi.org/10.1107/S1600536813009355
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author Omer, Mohammed A. S.
Liu, Jia-Cheng
author_facet Omer, Mohammed A. S.
Liu, Jia-Cheng
author_sort Omer, Mohammed A. S.
collection PubMed
description In the title complex, [Ni(NO(3))(2)(C(14)H(16)N(6)O(2))]·H(2)O, the Ni(II) atom, lying on a twofold rotation axis, is coordinated by a tetra­dentate 3,3′-{(1E,1′E)-1,1′-[ethane-1,2-diylbis(azan-1-yl-1-yl­idene)]bis­(ethan-1-yl-1-yl­idene)}di­pyrazine 1-oxide ligand and two mutually trans monodentate nitrate anions in a distorted o­cta­hedral geometry. The lattice water mol­ecule is located on a twofold rotation axis. The complex mol­ecules are linked by the water mol­ecules through O—H⋯O hydrogen bonds into a chain along [001]. Further C—H⋯O hydrogen bonds lead to the formation of a three-dimensional network.
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spelling pubmed-36478062013-05-30 (3,3′-{(1E,1′E)-1,1′-[Ethane-1,2-diylbis(azan-1-yl-1-yl­idene-κN)]bis­(ethan-1-yl-1-yl­idene)}di­pyrazine 1-oxide-κN (4))bis­(nitrato-κO)nickel(II) monohydrate Omer, Mohammed A. S. Liu, Jia-Cheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(NO(3))(2)(C(14)H(16)N(6)O(2))]·H(2)O, the Ni(II) atom, lying on a twofold rotation axis, is coordinated by a tetra­dentate 3,3′-{(1E,1′E)-1,1′-[ethane-1,2-diylbis(azan-1-yl-1-yl­idene)]bis­(ethan-1-yl-1-yl­idene)}di­pyrazine 1-oxide ligand and two mutually trans monodentate nitrate anions in a distorted o­cta­hedral geometry. The lattice water mol­ecule is located on a twofold rotation axis. The complex mol­ecules are linked by the water mol­ecules through O—H⋯O hydrogen bonds into a chain along [001]. Further C—H⋯O hydrogen bonds lead to the formation of a three-dimensional network. International Union of Crystallography 2013-04-13 /pmc/articles/PMC3647806/ /pubmed/23723772 http://dx.doi.org/10.1107/S1600536813009355 Text en © Omer and Liu 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Omer, Mohammed A. S.
Liu, Jia-Cheng
(3,3′-{(1E,1′E)-1,1′-[Ethane-1,2-diylbis(azan-1-yl-1-yl­idene-κN)]bis­(ethan-1-yl-1-yl­idene)}di­pyrazine 1-oxide-κN (4))bis­(nitrato-κO)nickel(II) monohydrate
title (3,3′-{(1E,1′E)-1,1′-[Ethane-1,2-diylbis(azan-1-yl-1-yl­idene-κN)]bis­(ethan-1-yl-1-yl­idene)}di­pyrazine 1-oxide-κN (4))bis­(nitrato-κO)nickel(II) monohydrate
title_full (3,3′-{(1E,1′E)-1,1′-[Ethane-1,2-diylbis(azan-1-yl-1-yl­idene-κN)]bis­(ethan-1-yl-1-yl­idene)}di­pyrazine 1-oxide-κN (4))bis­(nitrato-κO)nickel(II) monohydrate
title_fullStr (3,3′-{(1E,1′E)-1,1′-[Ethane-1,2-diylbis(azan-1-yl-1-yl­idene-κN)]bis­(ethan-1-yl-1-yl­idene)}di­pyrazine 1-oxide-κN (4))bis­(nitrato-κO)nickel(II) monohydrate
title_full_unstemmed (3,3′-{(1E,1′E)-1,1′-[Ethane-1,2-diylbis(azan-1-yl-1-yl­idene-κN)]bis­(ethan-1-yl-1-yl­idene)}di­pyrazine 1-oxide-κN (4))bis­(nitrato-κO)nickel(II) monohydrate
title_short (3,3′-{(1E,1′E)-1,1′-[Ethane-1,2-diylbis(azan-1-yl-1-yl­idene-κN)]bis­(ethan-1-yl-1-yl­idene)}di­pyrazine 1-oxide-κN (4))bis­(nitrato-κO)nickel(II) monohydrate
title_sort (3,3′-{(1e,1′e)-1,1′-[ethane-1,2-diylbis(azan-1-yl-1-yl­idene-κn)]bis­(ethan-1-yl-1-yl­idene)}di­pyrazine 1-oxide-κn (4))bis­(nitrato-κo)nickel(ii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647806/
https://www.ncbi.nlm.nih.gov/pubmed/23723772
http://dx.doi.org/10.1107/S1600536813009355
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