Cargando…
(3,3′-{(1E,1′E)-1,1′-[Ethane-1,2-diylbis(azan-1-yl-1-ylidene-κN)]bis(ethan-1-yl-1-ylidene)}dipyrazine 1-oxide-κN (4))bis(nitrato-κO)nickel(II) monohydrate
In the title complex, [Ni(NO(3))(2)(C(14)H(16)N(6)O(2))]·H(2)O, the Ni(II) atom, lying on a twofold rotation axis, is coordinated by a tetradentate 3,3′-{(1E,1′E)-1,1′-[ethane-1,2-diylbis(azan-1-yl-1-ylidene)]bis(ethan-1-yl-1-ylidene)}dipyrazine 1-oxide ligand and two mutually trans monodentate...
Autores principales: | , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647806/ https://www.ncbi.nlm.nih.gov/pubmed/23723772 http://dx.doi.org/10.1107/S1600536813009355 |
_version_ | 1782268780042256384 |
---|---|
author | Omer, Mohammed A. S. Liu, Jia-Cheng |
author_facet | Omer, Mohammed A. S. Liu, Jia-Cheng |
author_sort | Omer, Mohammed A. S. |
collection | PubMed |
description | In the title complex, [Ni(NO(3))(2)(C(14)H(16)N(6)O(2))]·H(2)O, the Ni(II) atom, lying on a twofold rotation axis, is coordinated by a tetradentate 3,3′-{(1E,1′E)-1,1′-[ethane-1,2-diylbis(azan-1-yl-1-ylidene)]bis(ethan-1-yl-1-ylidene)}dipyrazine 1-oxide ligand and two mutually trans monodentate nitrate anions in a distorted octahedral geometry. The lattice water molecule is located on a twofold rotation axis. The complex molecules are linked by the water molecules through O—H⋯O hydrogen bonds into a chain along [001]. Further C—H⋯O hydrogen bonds lead to the formation of a three-dimensional network. |
format | Online Article Text |
id | pubmed-3647806 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36478062013-05-30 (3,3′-{(1E,1′E)-1,1′-[Ethane-1,2-diylbis(azan-1-yl-1-ylidene-κN)]bis(ethan-1-yl-1-ylidene)}dipyrazine 1-oxide-κN (4))bis(nitrato-κO)nickel(II) monohydrate Omer, Mohammed A. S. Liu, Jia-Cheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(NO(3))(2)(C(14)H(16)N(6)O(2))]·H(2)O, the Ni(II) atom, lying on a twofold rotation axis, is coordinated by a tetradentate 3,3′-{(1E,1′E)-1,1′-[ethane-1,2-diylbis(azan-1-yl-1-ylidene)]bis(ethan-1-yl-1-ylidene)}dipyrazine 1-oxide ligand and two mutually trans monodentate nitrate anions in a distorted octahedral geometry. The lattice water molecule is located on a twofold rotation axis. The complex molecules are linked by the water molecules through O—H⋯O hydrogen bonds into a chain along [001]. Further C—H⋯O hydrogen bonds lead to the formation of a three-dimensional network. International Union of Crystallography 2013-04-13 /pmc/articles/PMC3647806/ /pubmed/23723772 http://dx.doi.org/10.1107/S1600536813009355 Text en © Omer and Liu 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Omer, Mohammed A. S. Liu, Jia-Cheng (3,3′-{(1E,1′E)-1,1′-[Ethane-1,2-diylbis(azan-1-yl-1-ylidene-κN)]bis(ethan-1-yl-1-ylidene)}dipyrazine 1-oxide-κN (4))bis(nitrato-κO)nickel(II) monohydrate |
title | (3,3′-{(1E,1′E)-1,1′-[Ethane-1,2-diylbis(azan-1-yl-1-ylidene-κN)]bis(ethan-1-yl-1-ylidene)}dipyrazine 1-oxide-κN
(4))bis(nitrato-κO)nickel(II) monohydrate |
title_full | (3,3′-{(1E,1′E)-1,1′-[Ethane-1,2-diylbis(azan-1-yl-1-ylidene-κN)]bis(ethan-1-yl-1-ylidene)}dipyrazine 1-oxide-κN
(4))bis(nitrato-κO)nickel(II) monohydrate |
title_fullStr | (3,3′-{(1E,1′E)-1,1′-[Ethane-1,2-diylbis(azan-1-yl-1-ylidene-κN)]bis(ethan-1-yl-1-ylidene)}dipyrazine 1-oxide-κN
(4))bis(nitrato-κO)nickel(II) monohydrate |
title_full_unstemmed | (3,3′-{(1E,1′E)-1,1′-[Ethane-1,2-diylbis(azan-1-yl-1-ylidene-κN)]bis(ethan-1-yl-1-ylidene)}dipyrazine 1-oxide-κN
(4))bis(nitrato-κO)nickel(II) monohydrate |
title_short | (3,3′-{(1E,1′E)-1,1′-[Ethane-1,2-diylbis(azan-1-yl-1-ylidene-κN)]bis(ethan-1-yl-1-ylidene)}dipyrazine 1-oxide-κN
(4))bis(nitrato-κO)nickel(II) monohydrate |
title_sort | (3,3′-{(1e,1′e)-1,1′-[ethane-1,2-diylbis(azan-1-yl-1-ylidene-κn)]bis(ethan-1-yl-1-ylidene)}dipyrazine 1-oxide-κn
(4))bis(nitrato-κo)nickel(ii) monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647806/ https://www.ncbi.nlm.nih.gov/pubmed/23723772 http://dx.doi.org/10.1107/S1600536813009355 |
work_keys_str_mv | AT omermohammedas 331e1e11ethane12diylbisazan1yl1ylideneknbisethan1yl1ylidenedipyrazine1oxidekn4bisnitratokonickeliimonohydrate AT liujiacheng 331e1e11ethane12diylbisazan1yl1ylideneknbisethan1yl1ylidenedipyrazine1oxidekn4bisnitratokonickeliimonohydrate |