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catena-Poly[silver(I)-bis[μ-4-methyl-1H-1,2,4-triazole-3(4H)-thione-κ(2) S:S]-silver(I)-di-μ-thiocyanato-κ(2) S:N;κ(2) N:S]
In the title one-dimensional coordination polymer, [Ag(2)(NCS)(2)(C(3)H(5)N(3)S)(2)](n), the Ag(I) atom adopts a distorted tetrahedral AgNS(3) geometry. Adjacent Ag(I) atoms in the [001] chain are alternately linked by pairs of bridging 4-methyl-1H-1,2,4-triazole-3(4H)-thione (Hmptrz) ligands (via...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647807/ https://www.ncbi.nlm.nih.gov/pubmed/23723773 http://dx.doi.org/10.1107/S160053681300946X |
Sumario: | In the title one-dimensional coordination polymer, [Ag(2)(NCS)(2)(C(3)H(5)N(3)S)(2)](n), the Ag(I) atom adopts a distorted tetrahedral AgNS(3) geometry. Adjacent Ag(I) atoms in the [001] chain are alternately linked by pairs of bridging 4-methyl-1H-1,2,4-triazole-3(4H)-thione (Hmptrz) ligands (via their S atoms) and double thiocyanate bridges linking through both S and N atoms (μ-1,3-SCN). An intrachain N—H⋯N hydrogen bond occurs between the NH group of the triazole ring and the N atom of the thiocyanate bridging ligand. A (101) sheet structure arises from interchain S⋯N short contacts [3.239 (3) Å] involving the thiocyanate S atom and the triazole-ring N atom and possible very weak π–π stacking [centroid–centroid separation = 4.0762 (18) Å] between the triazole rings. |
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