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catena-Poly[silver(I)-bis­[μ-4-methyl-1H-1,2,4-triazole-3(4H)-thione-κ(2) S:S]-silver(I)-di-μ-thio­cyanato-κ(2) S:N;κ(2) N:S]

In the title one-dimensional coordination polymer, [Ag(2)(NCS)(2)(C(3)H(5)N(3)S)(2)](n), the Ag(I) atom adopts a distorted tetra­hedral AgNS(3) geometry. Adjacent Ag(I) atoms in the [001] chain are alternately linked by pairs of bridging 4-methyl-1H-1,2,4-triazole-3(4H)-thione (Hmptrz) ligands (via...

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Detalles Bibliográficos
Autores principales: Kodcharat, Kultida, Pakawatchai, Chaveng, Saithong, Saowanit
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647807/
https://www.ncbi.nlm.nih.gov/pubmed/23723773
http://dx.doi.org/10.1107/S160053681300946X
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author Kodcharat, Kultida
Pakawatchai, Chaveng
Saithong, Saowanit
author_facet Kodcharat, Kultida
Pakawatchai, Chaveng
Saithong, Saowanit
author_sort Kodcharat, Kultida
collection PubMed
description In the title one-dimensional coordination polymer, [Ag(2)(NCS)(2)(C(3)H(5)N(3)S)(2)](n), the Ag(I) atom adopts a distorted tetra­hedral AgNS(3) geometry. Adjacent Ag(I) atoms in the [001] chain are alternately linked by pairs of bridging 4-methyl-1H-1,2,4-triazole-3(4H)-thione (Hmptrz) ligands (via their S atoms) and double thio­cyanate bridges linking through both S and N atoms (μ-1,3-SCN). An intra­chain N—H⋯N hydrogen bond occurs between the NH group of the triazole ring and the N atom of the thio­cyanate bridging ligand. A (101) sheet structure arises from inter­chain S⋯N short contacts [3.239 (3) Å] involving the thio­cyanate S atom and the triazole-ring N atom and possible very weak π–π stacking [centroid–centroid separation = 4.0762 (18) Å] between the triazole rings.
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spelling pubmed-36478072013-05-30 catena-Poly[silver(I)-bis­[μ-4-methyl-1H-1,2,4-triazole-3(4H)-thione-κ(2) S:S]-silver(I)-di-μ-thio­cyanato-κ(2) S:N;κ(2) N:S] Kodcharat, Kultida Pakawatchai, Chaveng Saithong, Saowanit Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title one-dimensional coordination polymer, [Ag(2)(NCS)(2)(C(3)H(5)N(3)S)(2)](n), the Ag(I) atom adopts a distorted tetra­hedral AgNS(3) geometry. Adjacent Ag(I) atoms in the [001] chain are alternately linked by pairs of bridging 4-methyl-1H-1,2,4-triazole-3(4H)-thione (Hmptrz) ligands (via their S atoms) and double thio­cyanate bridges linking through both S and N atoms (μ-1,3-SCN). An intra­chain N—H⋯N hydrogen bond occurs between the NH group of the triazole ring and the N atom of the thio­cyanate bridging ligand. A (101) sheet structure arises from inter­chain S⋯N short contacts [3.239 (3) Å] involving the thio­cyanate S atom and the triazole-ring N atom and possible very weak π–π stacking [centroid–centroid separation = 4.0762 (18) Å] between the triazole rings. International Union of Crystallography 2013-04-13 /pmc/articles/PMC3647807/ /pubmed/23723773 http://dx.doi.org/10.1107/S160053681300946X Text en © Kodcharat et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kodcharat, Kultida
Pakawatchai, Chaveng
Saithong, Saowanit
catena-Poly[silver(I)-bis­[μ-4-methyl-1H-1,2,4-triazole-3(4H)-thione-κ(2) S:S]-silver(I)-di-μ-thio­cyanato-κ(2) S:N;κ(2) N:S]
title catena-Poly[silver(I)-bis­[μ-4-methyl-1H-1,2,4-triazole-3(4H)-thione-κ(2) S:S]-silver(I)-di-μ-thio­cyanato-κ(2) S:N;κ(2) N:S]
title_full catena-Poly[silver(I)-bis­[μ-4-methyl-1H-1,2,4-triazole-3(4H)-thione-κ(2) S:S]-silver(I)-di-μ-thio­cyanato-κ(2) S:N;κ(2) N:S]
title_fullStr catena-Poly[silver(I)-bis­[μ-4-methyl-1H-1,2,4-triazole-3(4H)-thione-κ(2) S:S]-silver(I)-di-μ-thio­cyanato-κ(2) S:N;κ(2) N:S]
title_full_unstemmed catena-Poly[silver(I)-bis­[μ-4-methyl-1H-1,2,4-triazole-3(4H)-thione-κ(2) S:S]-silver(I)-di-μ-thio­cyanato-κ(2) S:N;κ(2) N:S]
title_short catena-Poly[silver(I)-bis­[μ-4-methyl-1H-1,2,4-triazole-3(4H)-thione-κ(2) S:S]-silver(I)-di-μ-thio­cyanato-κ(2) S:N;κ(2) N:S]
title_sort catena-poly[silver(i)-bis­[μ-4-methyl-1h-1,2,4-triazole-3(4h)-thione-κ(2) s:s]-silver(i)-di-μ-thio­cyanato-κ(2) s:n;κ(2) n:s]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647807/
https://www.ncbi.nlm.nih.gov/pubmed/23723773
http://dx.doi.org/10.1107/S160053681300946X
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