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Bis[2,4-dibromo-6-(N-{4-[(E)-1-(benzyloxyimino)ethyl]phenyl}carboximidoyl)phenolato]copper(II)
In the title complex, [Cu(C(22)H(17)Br(2)N(2)O(2))(2)], the Cu(II) ion is four-coordinated in a trans-CuN(2)O(2) square-planar geometry by two phenolate O and two imino N atoms from two deprotonated N,O-bidentate ligands. In the crystal, the packing of the molecules is controlled by C—H⋯π and π–π i...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647808/ https://www.ncbi.nlm.nih.gov/pubmed/23723774 http://dx.doi.org/10.1107/S1600536813009847 |
| _version_ | 1782268780493144064 |
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| author | Li, Xiao-Bing Li, Xiao-Jun Meng, Wei-Sheng Zhang, Yu-Jie Li, Gang |
| author_facet | Li, Xiao-Bing Li, Xiao-Jun Meng, Wei-Sheng Zhang, Yu-Jie Li, Gang |
| author_sort | Li, Xiao-Bing |
| collection | PubMed |
| description | In the title complex, [Cu(C(22)H(17)Br(2)N(2)O(2))(2)], the Cu(II) ion is four-coordinated in a trans-CuN(2)O(2) square-planar geometry by two phenolate O and two imino N atoms from two deprotonated N,O-bidentate ligands. In the crystal, the packing of the molecules is controlled by C—H⋯π and π–π interactions [centroid–centroid distances = 3.568 (3), 3.678 (2), 3.717 (3) and 3.799 (2) Å] and weak Br⋯Br halogen bonds [3.508 (4) Å], linking the molecules into an infinite three-dimensional supramolecular network. |
| format | Online Article Text |
| id | pubmed-3647808 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2013 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-36478082013-05-30 Bis[2,4-dibromo-6-(N-{4-[(E)-1-(benzyloxyimino)ethyl]phenyl}carboximidoyl)phenolato]copper(II) Li, Xiao-Bing Li, Xiao-Jun Meng, Wei-Sheng Zhang, Yu-Jie Li, Gang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(22)H(17)Br(2)N(2)O(2))(2)], the Cu(II) ion is four-coordinated in a trans-CuN(2)O(2) square-planar geometry by two phenolate O and two imino N atoms from two deprotonated N,O-bidentate ligands. In the crystal, the packing of the molecules is controlled by C—H⋯π and π–π interactions [centroid–centroid distances = 3.568 (3), 3.678 (2), 3.717 (3) and 3.799 (2) Å] and weak Br⋯Br halogen bonds [3.508 (4) Å], linking the molecules into an infinite three-dimensional supramolecular network. International Union of Crystallography 2013-04-13 /pmc/articles/PMC3647808/ /pubmed/23723774 http://dx.doi.org/10.1107/S1600536813009847 Text en © Li et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Li, Xiao-Bing Li, Xiao-Jun Meng, Wei-Sheng Zhang, Yu-Jie Li, Gang Bis[2,4-dibromo-6-(N-{4-[(E)-1-(benzyloxyimino)ethyl]phenyl}carboximidoyl)phenolato]copper(II) |
| title | Bis[2,4-dibromo-6-(N-{4-[(E)-1-(benzyloxyimino)ethyl]phenyl}carboximidoyl)phenolato]copper(II) |
| title_full | Bis[2,4-dibromo-6-(N-{4-[(E)-1-(benzyloxyimino)ethyl]phenyl}carboximidoyl)phenolato]copper(II) |
| title_fullStr | Bis[2,4-dibromo-6-(N-{4-[(E)-1-(benzyloxyimino)ethyl]phenyl}carboximidoyl)phenolato]copper(II) |
| title_full_unstemmed | Bis[2,4-dibromo-6-(N-{4-[(E)-1-(benzyloxyimino)ethyl]phenyl}carboximidoyl)phenolato]copper(II) |
| title_short | Bis[2,4-dibromo-6-(N-{4-[(E)-1-(benzyloxyimino)ethyl]phenyl}carboximidoyl)phenolato]copper(II) |
| title_sort | bis[2,4-dibromo-6-(n-{4-[(e)-1-(benzyloxyimino)ethyl]phenyl}carboximidoyl)phenolato]copper(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647808/ https://www.ncbi.nlm.nih.gov/pubmed/23723774 http://dx.doi.org/10.1107/S1600536813009847 |
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