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Poly[[aqua{μ(4)-2-[(carboxymethyl)sulfanyl]nicotinato-κ(4) O:O′:O′′:O′′′}copper(II)] trihydrate]
In the polymeric title complex, {[Cu(C(8)H(5)NO(4)S)(H(2)O)]·3H(2)O}(n), the Cu(II) cation is coordinated by one water molecule and four carboxylate O atoms from four 2-[(carboxymethyl)sulfanyl]nicotinate anions in a distorted square-pyramidal geometry. The 2-[(carboxymethyl)sulfanyl]nicot...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647809/ https://www.ncbi.nlm.nih.gov/pubmed/23723775 http://dx.doi.org/10.1107/S1600536813009604 |
Sumario: | In the polymeric title complex, {[Cu(C(8)H(5)NO(4)S)(H(2)O)]·3H(2)O}(n), the Cu(II) cation is coordinated by one water molecule and four carboxylate O atoms from four 2-[(carboxymethyl)sulfanyl]nicotinate anions in a distorted square-pyramidal geometry. The 2-[(carboxymethyl)sulfanyl]nicotinate anion bridges four Cu(II) cations, forming a two-dimensional polymeric complex parallel to the bc plane. In the crystal, O—H⋯O, O—H⋯N and O—H⋯S hydrogen bonds link the complex molecules and lattice water molecules into a three-dimensional supramolecular architecture. |
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