Poly[[aqua­{μ(4)-2-[(carb­oxy­meth­yl)sulfan­yl]nicotinato-κ(4) O:O′:O′′:O′′′}copper(II)] trihydrate]

In the polymeric title complex, {[Cu(C(8)H(5)NO(4)S)(H(2)O)]·3H(2)O}(n), the Cu(II) cation is coordinated by one water mol­ecule and four carboxyl­ate O atoms from four 2-[(carb­oxy­meth­yl)sulfan­yl]nicotinate anions in a distorted square-pyramidal geometry. The 2-[(carb­oxy­meth­yl)sulfan­yl]nicot...

Descripción completa

Detalles Bibliográficos
Autor principal: Li, Wei-Qi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647809/
https://www.ncbi.nlm.nih.gov/pubmed/23723775
http://dx.doi.org/10.1107/S1600536813009604
_version_ 1782268780722782208
author Li, Wei-Qi
author_facet Li, Wei-Qi
author_sort Li, Wei-Qi
collection PubMed
description In the polymeric title complex, {[Cu(C(8)H(5)NO(4)S)(H(2)O)]·3H(2)O}(n), the Cu(II) cation is coordinated by one water mol­ecule and four carboxyl­ate O atoms from four 2-[(carb­oxy­meth­yl)sulfan­yl]nicotinate anions in a distorted square-pyramidal geometry. The 2-[(carb­oxy­meth­yl)sulfan­yl]nicotinate anion bridges four Cu(II) cations, forming a two-dimensional polymeric complex parallel to the bc plane. In the crystal, O—H⋯O, O—H⋯N and O—H⋯S hydrogen bonds link the complex mol­ecules and lattice water mol­ecules into a three-dimensional supra­molecular architecture.
format Online
Article
Text
id pubmed-3647809
institution National Center for Biotechnology Information
language English
publishDate 2013
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-36478092013-05-30 Poly[[aqua­{μ(4)-2-[(carb­oxy­meth­yl)sulfan­yl]nicotinato-κ(4) O:O′:O′′:O′′′}copper(II)] trihydrate] Li, Wei-Qi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the polymeric title complex, {[Cu(C(8)H(5)NO(4)S)(H(2)O)]·3H(2)O}(n), the Cu(II) cation is coordinated by one water mol­ecule and four carboxyl­ate O atoms from four 2-[(carb­oxy­meth­yl)sulfan­yl]nicotinate anions in a distorted square-pyramidal geometry. The 2-[(carb­oxy­meth­yl)sulfan­yl]nicotinate anion bridges four Cu(II) cations, forming a two-dimensional polymeric complex parallel to the bc plane. In the crystal, O—H⋯O, O—H⋯N and O—H⋯S hydrogen bonds link the complex mol­ecules and lattice water mol­ecules into a three-dimensional supra­molecular architecture. International Union of Crystallography 2013-04-13 /pmc/articles/PMC3647809/ /pubmed/23723775 http://dx.doi.org/10.1107/S1600536813009604 Text en © Wei-Qi Li 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Wei-Qi
Poly[[aqua­{μ(4)-2-[(carb­oxy­meth­yl)sulfan­yl]nicotinato-κ(4) O:O′:O′′:O′′′}copper(II)] trihydrate]
title Poly[[aqua­{μ(4)-2-[(carb­oxy­meth­yl)sulfan­yl]nicotinato-κ(4) O:O′:O′′:O′′′}copper(II)] trihydrate]
title_full Poly[[aqua­{μ(4)-2-[(carb­oxy­meth­yl)sulfan­yl]nicotinato-κ(4) O:O′:O′′:O′′′}copper(II)] trihydrate]
title_fullStr Poly[[aqua­{μ(4)-2-[(carb­oxy­meth­yl)sulfan­yl]nicotinato-κ(4) O:O′:O′′:O′′′}copper(II)] trihydrate]
title_full_unstemmed Poly[[aqua­{μ(4)-2-[(carb­oxy­meth­yl)sulfan­yl]nicotinato-κ(4) O:O′:O′′:O′′′}copper(II)] trihydrate]
title_short Poly[[aqua­{μ(4)-2-[(carb­oxy­meth­yl)sulfan­yl]nicotinato-κ(4) O:O′:O′′:O′′′}copper(II)] trihydrate]
title_sort poly[[aqua­{μ(4)-2-[(carb­oxy­meth­yl)sulfan­yl]nicotinato-κ(4) o:o′:o′′:o′′′}copper(ii)] trihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647809/
https://www.ncbi.nlm.nih.gov/pubmed/23723775
http://dx.doi.org/10.1107/S1600536813009604
work_keys_str_mv AT liweiqi polyaquam42carboxymethylsulfanylnicotinatok4oooocopperiitrihydrate

Ejemplares similares