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Di-μ-cyanido-tetra­cyanido(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­aza­cyclo­tetra­decane)[N-(quinolin-8-yl)quinoline-2-carboxamidato]diiron(III)nickel(II) 2.07-hydrate

The asymmetric unit of the title complex, [Fe(2)Ni(C(19)H(12)N(3)O)(2)(CN)(6)(C(16)H(36)N(4))]·2.07H(2)O, contains one [Fe(qcq)(CN)(3)](−) anion, half a [Ni(teta)](2+) cation and two partially occupied inter­stitial water mol­ecules [qcq(−) is the N-(quinolin-8-yl)quinoline-2-carboxamidate anion and...

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Detalles Bibliográficos
Autores principales: Yang, Yuqi, Zhou, Hongbo, Shen, Xiaoping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647811/
https://www.ncbi.nlm.nih.gov/pubmed/23723777
http://dx.doi.org/10.1107/S1600536813010234
Descripción
Sumario:The asymmetric unit of the title complex, [Fe(2)Ni(C(19)H(12)N(3)O)(2)(CN)(6)(C(16)H(36)N(4))]·2.07H(2)O, contains one [Fe(qcq)(CN)(3)](−) anion, half a [Ni(teta)](2+) cation and two partially occupied inter­stitial water mol­ecules [qcq(−) is the N-(quinolin-8-yl)quinoline-2-carboxamidate anion and teta is 5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­aza­cyclo­tetra­deca­ne]. In the complex mol­ecule, two [Fe(qcq)(CN)(3)](−) anions additionally coordinate the central [Ni(teta)](2+) cation through cyanide groups in a trans mode, resulting in a trinuclear structure with the Ni(2+) cation lying on an inversion centre. The two inter­stitial water mol­ecules are partially occupied, with occupancy factors of 0.528 (10) and 0.506 (9). O—H⋯O and O—H⋯N hydrogen bonding involving the two lattice water molecules and the carbonyl function and a teta N atom in an adjacent cluster leads to the formation of layers extending parallel to (010).