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Di-μ-cyanido-tetracyanido(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)[N-(quinolin-8-yl)quinoline-2-carboxamidato]diiron(III)nickel(II) 2.07-hydrate
The asymmetric unit of the title complex, [Fe(2)Ni(C(19)H(12)N(3)O)(2)(CN)(6)(C(16)H(36)N(4))]·2.07H(2)O, contains one [Fe(qcq)(CN)(3)](−) anion, half a [Ni(teta)](2+) cation and two partially occupied interstitial water molecules [qcq(−) is the N-(quinolin-8-yl)quinoline-2-carboxamidate anion and...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647811/ https://www.ncbi.nlm.nih.gov/pubmed/23723777 http://dx.doi.org/10.1107/S1600536813010234 |
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author | Yang, Yuqi Zhou, Hongbo Shen, Xiaoping |
author_facet | Yang, Yuqi Zhou, Hongbo Shen, Xiaoping |
author_sort | Yang, Yuqi |
collection | PubMed |
description | The asymmetric unit of the title complex, [Fe(2)Ni(C(19)H(12)N(3)O)(2)(CN)(6)(C(16)H(36)N(4))]·2.07H(2)O, contains one [Fe(qcq)(CN)(3)](−) anion, half a [Ni(teta)](2+) cation and two partially occupied interstitial water molecules [qcq(−) is the N-(quinolin-8-yl)quinoline-2-carboxamidate anion and teta is 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane]. In the complex molecule, two [Fe(qcq)(CN)(3)](−) anions additionally coordinate the central [Ni(teta)](2+) cation through cyanide groups in a trans mode, resulting in a trinuclear structure with the Ni(2+) cation lying on an inversion centre. The two interstitial water molecules are partially occupied, with occupancy factors of 0.528 (10) and 0.506 (9). O—H⋯O and O—H⋯N hydrogen bonding involving the two lattice water molecules and the carbonyl function and a teta N atom in an adjacent cluster leads to the formation of layers extending parallel to (010). |
format | Online Article Text |
id | pubmed-3647811 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36478112013-05-30 Di-μ-cyanido-tetracyanido(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)[N-(quinolin-8-yl)quinoline-2-carboxamidato]diiron(III)nickel(II) 2.07-hydrate Yang, Yuqi Zhou, Hongbo Shen, Xiaoping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex, [Fe(2)Ni(C(19)H(12)N(3)O)(2)(CN)(6)(C(16)H(36)N(4))]·2.07H(2)O, contains one [Fe(qcq)(CN)(3)](−) anion, half a [Ni(teta)](2+) cation and two partially occupied interstitial water molecules [qcq(−) is the N-(quinolin-8-yl)quinoline-2-carboxamidate anion and teta is 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane]. In the complex molecule, two [Fe(qcq)(CN)(3)](−) anions additionally coordinate the central [Ni(teta)](2+) cation through cyanide groups in a trans mode, resulting in a trinuclear structure with the Ni(2+) cation lying on an inversion centre. The two interstitial water molecules are partially occupied, with occupancy factors of 0.528 (10) and 0.506 (9). O—H⋯O and O—H⋯N hydrogen bonding involving the two lattice water molecules and the carbonyl function and a teta N atom in an adjacent cluster leads to the formation of layers extending parallel to (010). International Union of Crystallography 2013-04-20 /pmc/articles/PMC3647811/ /pubmed/23723777 http://dx.doi.org/10.1107/S1600536813010234 Text en © Yang et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Yang, Yuqi Zhou, Hongbo Shen, Xiaoping Di-μ-cyanido-tetracyanido(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)[N-(quinolin-8-yl)quinoline-2-carboxamidato]diiron(III)nickel(II) 2.07-hydrate |
title | Di-μ-cyanido-tetracyanido(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)[N-(quinolin-8-yl)quinoline-2-carboxamidato]diiron(III)nickel(II) 2.07-hydrate |
title_full | Di-μ-cyanido-tetracyanido(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)[N-(quinolin-8-yl)quinoline-2-carboxamidato]diiron(III)nickel(II) 2.07-hydrate |
title_fullStr | Di-μ-cyanido-tetracyanido(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)[N-(quinolin-8-yl)quinoline-2-carboxamidato]diiron(III)nickel(II) 2.07-hydrate |
title_full_unstemmed | Di-μ-cyanido-tetracyanido(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)[N-(quinolin-8-yl)quinoline-2-carboxamidato]diiron(III)nickel(II) 2.07-hydrate |
title_short | Di-μ-cyanido-tetracyanido(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)[N-(quinolin-8-yl)quinoline-2-carboxamidato]diiron(III)nickel(II) 2.07-hydrate |
title_sort | di-μ-cyanido-tetracyanido(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)[n-(quinolin-8-yl)quinoline-2-carboxamidato]diiron(iii)nickel(ii) 2.07-hydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647811/ https://www.ncbi.nlm.nih.gov/pubmed/23723777 http://dx.doi.org/10.1107/S1600536813010234 |
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