Poly[[di­aqua­(μ(4)-benzene-1,2,4,5-tetra­carboxyl­ato)tetrakis­(1H-imidazole-κN (3))dicopper(II)] N,N-di­methyl­formamide monosolvate]

The asymmetric unit of the polymeric title compound, {[Cu(2)(C(10)H(2)O(8))(C(3)H(4)N(2))(4)(H(2)O)(2)]·C(3)H(7)NO}(n), contains two independent Cu(II) ions, each coordinated by one water mol­ecule, two imidazole N atoms and two carboxyl­ate O atoms from benzene-1,2,4,5-tetra­carboxyl­ate anions in...

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Autores principales: Zhou, Xiao-Fei, Xiao, Hong-Ping, Zhao, Ya-Juan, Li, Xin-Hua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647812/
https://www.ncbi.nlm.nih.gov/pubmed/23723778
http://dx.doi.org/10.1107/S1600536813010246
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author Zhou, Xiao-Fei
Xiao, Hong-Ping
Zhao, Ya-Juan
Li, Xin-Hua
author_facet Zhou, Xiao-Fei
Xiao, Hong-Ping
Zhao, Ya-Juan
Li, Xin-Hua
author_sort Zhou, Xiao-Fei
collection PubMed
description The asymmetric unit of the polymeric title compound, {[Cu(2)(C(10)H(2)O(8))(C(3)H(4)N(2))(4)(H(2)O)(2)]·C(3)H(7)NO}(n), contains two independent Cu(II) ions, each coordinated by one water mol­ecule, two imidazole N atoms and two carboxyl­ate O atoms from benzene-1,2,4,5-tetra­carboxyl­ate anions in a distorted square-pyramidal geometry. The benzene-1,2,4,5-tetra­carboxyl­ate anion bridges four Cu(II) ions, forming a polymeric sheet parallel to (010). In the crystal, extensive N—H⋯O and O—H⋯O hydrogen bonds link the polymeric sheets and di­methyl­formamide solvent mol­ecules into a three-dimensional supra­molecular structure.
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spelling pubmed-36478122013-05-30 Poly[[di­aqua­(μ(4)-benzene-1,2,4,5-tetra­carboxyl­ato)tetrakis­(1H-imidazole-κN (3))dicopper(II)] N,N-di­methyl­formamide monosolvate] Zhou, Xiao-Fei Xiao, Hong-Ping Zhao, Ya-Juan Li, Xin-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the polymeric title compound, {[Cu(2)(C(10)H(2)O(8))(C(3)H(4)N(2))(4)(H(2)O)(2)]·C(3)H(7)NO}(n), contains two independent Cu(II) ions, each coordinated by one water mol­ecule, two imidazole N atoms and two carboxyl­ate O atoms from benzene-1,2,4,5-tetra­carboxyl­ate anions in a distorted square-pyramidal geometry. The benzene-1,2,4,5-tetra­carboxyl­ate anion bridges four Cu(II) ions, forming a polymeric sheet parallel to (010). In the crystal, extensive N—H⋯O and O—H⋯O hydrogen bonds link the polymeric sheets and di­methyl­formamide solvent mol­ecules into a three-dimensional supra­molecular structure. International Union of Crystallography 2013-04-20 /pmc/articles/PMC3647812/ /pubmed/23723778 http://dx.doi.org/10.1107/S1600536813010246 Text en © Zhou et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhou, Xiao-Fei
Xiao, Hong-Ping
Zhao, Ya-Juan
Li, Xin-Hua
Poly[[di­aqua­(μ(4)-benzene-1,2,4,5-tetra­carboxyl­ato)tetrakis­(1H-imidazole-κN (3))dicopper(II)] N,N-di­methyl­formamide monosolvate]
title Poly[[di­aqua­(μ(4)-benzene-1,2,4,5-tetra­carboxyl­ato)tetrakis­(1H-imidazole-κN (3))dicopper(II)] N,N-di­methyl­formamide monosolvate]
title_full Poly[[di­aqua­(μ(4)-benzene-1,2,4,5-tetra­carboxyl­ato)tetrakis­(1H-imidazole-κN (3))dicopper(II)] N,N-di­methyl­formamide monosolvate]
title_fullStr Poly[[di­aqua­(μ(4)-benzene-1,2,4,5-tetra­carboxyl­ato)tetrakis­(1H-imidazole-κN (3))dicopper(II)] N,N-di­methyl­formamide monosolvate]
title_full_unstemmed Poly[[di­aqua­(μ(4)-benzene-1,2,4,5-tetra­carboxyl­ato)tetrakis­(1H-imidazole-κN (3))dicopper(II)] N,N-di­methyl­formamide monosolvate]
title_short Poly[[di­aqua­(μ(4)-benzene-1,2,4,5-tetra­carboxyl­ato)tetrakis­(1H-imidazole-κN (3))dicopper(II)] N,N-di­methyl­formamide monosolvate]
title_sort poly[[di­aqua­(μ(4)-benzene-1,2,4,5-tetra­carboxyl­ato)tetrakis­(1h-imidazole-κn (3))dicopper(ii)] n,n-di­methyl­formamide monosolvate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647812/
https://www.ncbi.nlm.nih.gov/pubmed/23723778
http://dx.doi.org/10.1107/S1600536813010246
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