Tris­(μ(4)-azepane-1-carbodi­thio­ato)bis­(μ(3)-azepane-1-carbodi­thio­ato)-μ(9)-bromido-tetra-μ(2)-bromido-octa­copper(I)­copper(II)

The reaction of Cu(Hm-dtc)(2) (H(2)m-dtc is azepane-1-carbodi­thioic acid), CuBr(2) and methyl iso­thio­cyanate yielded the title mixed-valence nona­nuclear Cu(I)/Cu(II) compound, [Cu(9)Br(5)(C(7)H(12)NS(2))(5)] or [Cu(I) (8)Cu(II)Br(5)(Hm-dtc)(5)], encapsulating a bromide anion in the center of the...

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Autores principales: Okubo, Takashi, Anma, Haruho, Maekawa, Masahiko, Kuroda-Sowa, Takayoshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647813/
https://www.ncbi.nlm.nih.gov/pubmed/23723779
http://dx.doi.org/10.1107/S1600536813009938
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author Okubo, Takashi
Anma, Haruho
Maekawa, Masahiko
Kuroda-Sowa, Takayoshi
author_facet Okubo, Takashi
Anma, Haruho
Maekawa, Masahiko
Kuroda-Sowa, Takayoshi
author_sort Okubo, Takashi
collection PubMed
description The reaction of Cu(Hm-dtc)(2) (H(2)m-dtc is azepane-1-carbodi­thioic acid), CuBr(2) and methyl iso­thio­cyanate yielded the title mixed-valence nona­nuclear Cu(I)/Cu(II) compound, [Cu(9)Br(5)(C(7)H(12)NS(2))(5)] or [Cu(I) (8)Cu(II)Br(5)(Hm-dtc)(5)], encapsulating a bromide anion in the center of the Cu(9)Br(4)S(10) cluster cage. The cage consists of a mononuclear Cu(II) unit [Cu(Hm-dtc)(2)], three μ(4)-bridging Hm-dtc(−) ligands, eight Cu(I) ions with distorted tetra­hedral or trigonal pyramidal coordination geometries and four μ(2)-bridging bromide anions. The incorporated central bromide anion inter­acts with nine Cu ions with shorter Cu—Br separations than the sum of the van der Waals radii for Cu and Br.
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spelling pubmed-36478132013-05-30 Tris­(μ(4)-azepane-1-carbodi­thio­ato)bis­(μ(3)-azepane-1-carbodi­thio­ato)-μ(9)-bromido-tetra-μ(2)-bromido-octa­copper(I)­copper(II) Okubo, Takashi Anma, Haruho Maekawa, Masahiko Kuroda-Sowa, Takayoshi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The reaction of Cu(Hm-dtc)(2) (H(2)m-dtc is azepane-1-carbodi­thioic acid), CuBr(2) and methyl iso­thio­cyanate yielded the title mixed-valence nona­nuclear Cu(I)/Cu(II) compound, [Cu(9)Br(5)(C(7)H(12)NS(2))(5)] or [Cu(I) (8)Cu(II)Br(5)(Hm-dtc)(5)], encapsulating a bromide anion in the center of the Cu(9)Br(4)S(10) cluster cage. The cage consists of a mononuclear Cu(II) unit [Cu(Hm-dtc)(2)], three μ(4)-bridging Hm-dtc(−) ligands, eight Cu(I) ions with distorted tetra­hedral or trigonal pyramidal coordination geometries and four μ(2)-bridging bromide anions. The incorporated central bromide anion inter­acts with nine Cu ions with shorter Cu—Br separations than the sum of the van der Waals radii for Cu and Br. International Union of Crystallography 2013-04-20 /pmc/articles/PMC3647813/ /pubmed/23723779 http://dx.doi.org/10.1107/S1600536813009938 Text en © Okubo et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Okubo, Takashi
Anma, Haruho
Maekawa, Masahiko
Kuroda-Sowa, Takayoshi
Tris­(μ(4)-azepane-1-carbodi­thio­ato)bis­(μ(3)-azepane-1-carbodi­thio­ato)-μ(9)-bromido-tetra-μ(2)-bromido-octa­copper(I)­copper(II)
title Tris­(μ(4)-azepane-1-carbodi­thio­ato)bis­(μ(3)-azepane-1-carbodi­thio­ato)-μ(9)-bromido-tetra-μ(2)-bromido-octa­copper(I)­copper(II)
title_full Tris­(μ(4)-azepane-1-carbodi­thio­ato)bis­(μ(3)-azepane-1-carbodi­thio­ato)-μ(9)-bromido-tetra-μ(2)-bromido-octa­copper(I)­copper(II)
title_fullStr Tris­(μ(4)-azepane-1-carbodi­thio­ato)bis­(μ(3)-azepane-1-carbodi­thio­ato)-μ(9)-bromido-tetra-μ(2)-bromido-octa­copper(I)­copper(II)
title_full_unstemmed Tris­(μ(4)-azepane-1-carbodi­thio­ato)bis­(μ(3)-azepane-1-carbodi­thio­ato)-μ(9)-bromido-tetra-μ(2)-bromido-octa­copper(I)­copper(II)
title_short Tris­(μ(4)-azepane-1-carbodi­thio­ato)bis­(μ(3)-azepane-1-carbodi­thio­ato)-μ(9)-bromido-tetra-μ(2)-bromido-octa­copper(I)­copper(II)
title_sort tris­(μ(4)-azepane-1-carbodi­thio­ato)bis­(μ(3)-azepane-1-carbodi­thio­ato)-μ(9)-bromido-tetra-μ(2)-bromido-octa­copper(i)­copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647813/
https://www.ncbi.nlm.nih.gov/pubmed/23723779
http://dx.doi.org/10.1107/S1600536813009938
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