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Tris(μ(4)-azepane-1-carbodithioato)bis(μ(3)-azepane-1-carbodithioato)-μ(9)-bromido-tetra-μ(2)-bromido-octacopper(I)copper(II)
The reaction of Cu(Hm-dtc)(2) (H(2)m-dtc is azepane-1-carbodithioic acid), CuBr(2) and methyl isothiocyanate yielded the title mixed-valence nonanuclear Cu(I)/Cu(II) compound, [Cu(9)Br(5)(C(7)H(12)NS(2))(5)] or [Cu(I) (8)Cu(II)Br(5)(Hm-dtc)(5)], encapsulating a bromide anion in the center of the...
Autores principales: | Okubo, Takashi, Anma, Haruho, Maekawa, Masahiko, Kuroda-Sowa, Takayoshi |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647813/ https://www.ncbi.nlm.nih.gov/pubmed/23723779 http://dx.doi.org/10.1107/S1600536813009938 |
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