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Bis(cinnamato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)
The title mononuclear Cu(II) complex, [Cu(C(9)H(7)O(2))(2)(C(12)H(8)N(2))], is comprised of a Cu(II) cation, two cinnamate (L (−)) ligands and a 1,10-phenanthroline (phen) ligand. The Cu(II) atom and phen ligand lie on a twofold rotation axis. The Cu(II) atom is coordinated by two O atoms from two c...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647814/ https://www.ncbi.nlm.nih.gov/pubmed/23723780 http://dx.doi.org/10.1107/S1600536813010350 |
Sumario: | The title mononuclear Cu(II) complex, [Cu(C(9)H(7)O(2))(2)(C(12)H(8)N(2))], is comprised of a Cu(II) cation, two cinnamate (L (−)) ligands and a 1,10-phenanthroline (phen) ligand. The Cu(II) atom and phen ligand lie on a twofold rotation axis. The Cu(II) atom is coordinated by two O atoms from two carboxylate groups of two (L (−)) ligands and two N atoms from one phen ligand, exhibiting a distorted square-planar geometry. In the crystal, molecules are assembled into supramolecular chains parallel to the c axis through weak C—H⋯O hydrogen bonds involving the phen and cinnamate ligands. |
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