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Bis[4-chloro-2-(quinolin-8-yliminomethyl)phenolato-κ(3) N,N′,O]cobalt(III) trichloridomethanolcobaltate(II)
The reaction of 4-chloro-2-(quinolin-8-yliminomethyl)phenol (HClQP) with cobalt(II) dichloride hexahydrate in methanol/chloroform under solvothermal conditions yielded the title compound, [Co(C(16)H(10)ClN(2)O)(2)][CoCl(3)(CH(3)OH)]. The Co(III) atom is six-coordinated in a slightly distorted o...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647815/ https://www.ncbi.nlm.nih.gov/pubmed/23723781 http://dx.doi.org/10.1107/S1600536813010118 |
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author | Luo, Xu-Jian Zhang, Chuan-Hui Zhou, Jie Liu, Yan-Cheng |
author_facet | Luo, Xu-Jian Zhang, Chuan-Hui Zhou, Jie Liu, Yan-Cheng |
author_sort | Luo, Xu-Jian |
collection | PubMed |
description | The reaction of 4-chloro-2-(quinolin-8-yliminomethyl)phenol (HClQP) with cobalt(II) dichloride hexahydrate in methanol/chloroform under solvothermal conditions yielded the title compound, [Co(C(16)H(10)ClN(2)O)(2)][CoCl(3)(CH(3)OH)]. The Co(III) atom is six-coordinated in a slightly distorted octahedral geometry by four N atoms and two O atoms of two tridentate HClQP ligands, which are nearly perpendicular to each other, making a dihedral angle of 86.95°. The Co(II) atom is four-coordinated by three Cl atoms and one O atom from a methanol ligand in a distorted tetrahedral geometry. The crystal packing is consolidated by intermolecular O—H⋯Cl, C—H⋯Cl and C—H⋯O hydrogen bonds, forming a three-dimensional supramolecular structure, in which [Co(II)Cl(3)(CH(3)OH)] anions are connected via O—H⋯Cl and C—H⋯Cl hydrogen bonds into centrosymmetric dimers. Neighboring cobalt(III) complexes form dimers through C—H⋯O hydrogen bonds, as well as π–π stacking [centroid–centroid distances = 3.30 (2) Å] between the planar quinoline systems of one HClQP ligand and the phenolate ring of another. |
format | Online Article Text |
id | pubmed-3647815 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36478152013-05-30 Bis[4-chloro-2-(quinolin-8-yliminomethyl)phenolato-κ(3) N,N′,O]cobalt(III) trichloridomethanolcobaltate(II) Luo, Xu-Jian Zhang, Chuan-Hui Zhou, Jie Liu, Yan-Cheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The reaction of 4-chloro-2-(quinolin-8-yliminomethyl)phenol (HClQP) with cobalt(II) dichloride hexahydrate in methanol/chloroform under solvothermal conditions yielded the title compound, [Co(C(16)H(10)ClN(2)O)(2)][CoCl(3)(CH(3)OH)]. The Co(III) atom is six-coordinated in a slightly distorted octahedral geometry by four N atoms and two O atoms of two tridentate HClQP ligands, which are nearly perpendicular to each other, making a dihedral angle of 86.95°. The Co(II) atom is four-coordinated by three Cl atoms and one O atom from a methanol ligand in a distorted tetrahedral geometry. The crystal packing is consolidated by intermolecular O—H⋯Cl, C—H⋯Cl and C—H⋯O hydrogen bonds, forming a three-dimensional supramolecular structure, in which [Co(II)Cl(3)(CH(3)OH)] anions are connected via O—H⋯Cl and C—H⋯Cl hydrogen bonds into centrosymmetric dimers. Neighboring cobalt(III) complexes form dimers through C—H⋯O hydrogen bonds, as well as π–π stacking [centroid–centroid distances = 3.30 (2) Å] between the planar quinoline systems of one HClQP ligand and the phenolate ring of another. International Union of Crystallography 2013-04-20 /pmc/articles/PMC3647815/ /pubmed/23723781 http://dx.doi.org/10.1107/S1600536813010118 Text en © Luo et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Luo, Xu-Jian Zhang, Chuan-Hui Zhou, Jie Liu, Yan-Cheng Bis[4-chloro-2-(quinolin-8-yliminomethyl)phenolato-κ(3) N,N′,O]cobalt(III) trichloridomethanolcobaltate(II) |
title | Bis[4-chloro-2-(quinolin-8-yliminomethyl)phenolato-κ(3)
N,N′,O]cobalt(III) trichloridomethanolcobaltate(II) |
title_full | Bis[4-chloro-2-(quinolin-8-yliminomethyl)phenolato-κ(3)
N,N′,O]cobalt(III) trichloridomethanolcobaltate(II) |
title_fullStr | Bis[4-chloro-2-(quinolin-8-yliminomethyl)phenolato-κ(3)
N,N′,O]cobalt(III) trichloridomethanolcobaltate(II) |
title_full_unstemmed | Bis[4-chloro-2-(quinolin-8-yliminomethyl)phenolato-κ(3)
N,N′,O]cobalt(III) trichloridomethanolcobaltate(II) |
title_short | Bis[4-chloro-2-(quinolin-8-yliminomethyl)phenolato-κ(3)
N,N′,O]cobalt(III) trichloridomethanolcobaltate(II) |
title_sort | bis[4-chloro-2-(quinolin-8-yliminomethyl)phenolato-κ(3)
n,n′,o]cobalt(iii) trichloridomethanolcobaltate(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647815/ https://www.ncbi.nlm.nih.gov/pubmed/23723781 http://dx.doi.org/10.1107/S1600536813010118 |
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