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Diethyl(μ(3)-2-methyl-4-oxo-4H-pyran-3-olato-κ(4) O (3),O (4):O (3):O (3))tris(μ(2)-2-methyl-4-oxo-4H-pyran-3-olato-κ(3) O (3),O (4):O (3))trizinc toluene disolvate
The title compound, [Zn(3)(C(2)H(5))(2)(C(6)H(5)O(3))(4)]·2C(7)H(8), crystallizes with one complex molecule solvated by two molecules of toluene in the asymmetric unit. The Zn(II) ions are coordinated by two terminal ethyl (Et) groups and four maltolate ligands, which act as μ(3)- and μ(2)-bridges...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647817/ https://www.ncbi.nlm.nih.gov/pubmed/23723783 http://dx.doi.org/10.1107/S1600536813010064 |
Sumario: | The title compound, [Zn(3)(C(2)H(5))(2)(C(6)H(5)O(3))(4)]·2C(7)H(8), crystallizes with one complex molecule solvated by two molecules of toluene in the asymmetric unit. The Zn(II) ions are coordinated by two terminal ethyl (Et) groups and four maltolate ligands, which act as μ(3)- and μ(2)-bridges. The metal atoms are arranged in an incomplete cubane Zn(3)O(4) core structure, derived from one EtZnO(3) tetrahedron, one EtZnO(4) bipyramid and one ZnO(6) octahedron, sharing common corners. The structure is stabilized by weak C—H⋯O and C—H⋯π interactions. |
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