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Diethyl(μ(3)-2-methyl-4-oxo-4H-pyran-3-olato-κ(4) O (3),O (4):O (3):O (3))tris(μ(2)-2-methyl-4-oxo-4H-pyran-3-olato-κ(3) O (3),O (4):O (3))trizinc toluene disolvate
The title compound, [Zn(3)(C(2)H(5))(2)(C(6)H(5)O(3))(4)]·2C(7)H(8), crystallizes with one complex molecule solvated by two molecules of toluene in the asymmetric unit. The Zn(II) ions are coordinated by two terminal ethyl (Et) groups and four maltolate ligands, which act as μ(3)- and μ(2)-bridges...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647817/ https://www.ncbi.nlm.nih.gov/pubmed/23723783 http://dx.doi.org/10.1107/S1600536813010064 |
| _version_ | 1782268782530527232 |
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| author | Petrus, Rafał Petrus, Joanna Paszek, Karolina Sobota, Piotr |
| author_facet | Petrus, Rafał Petrus, Joanna Paszek, Karolina Sobota, Piotr |
| author_sort | Petrus, Rafał |
| collection | PubMed |
| description | The title compound, [Zn(3)(C(2)H(5))(2)(C(6)H(5)O(3))(4)]·2C(7)H(8), crystallizes with one complex molecule solvated by two molecules of toluene in the asymmetric unit. The Zn(II) ions are coordinated by two terminal ethyl (Et) groups and four maltolate ligands, which act as μ(3)- and μ(2)-bridges. The metal atoms are arranged in an incomplete cubane Zn(3)O(4) core structure, derived from one EtZnO(3) tetrahedron, one EtZnO(4) bipyramid and one ZnO(6) octahedron, sharing common corners. The structure is stabilized by weak C—H⋯O and C—H⋯π interactions. |
| format | Online Article Text |
| id | pubmed-3647817 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2013 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-36478172013-05-30 Diethyl(μ(3)-2-methyl-4-oxo-4H-pyran-3-olato-κ(4) O (3),O (4):O (3):O (3))tris(μ(2)-2-methyl-4-oxo-4H-pyran-3-olato-κ(3) O (3),O (4):O (3))trizinc toluene disolvate Petrus, Rafał Petrus, Joanna Paszek, Karolina Sobota, Piotr Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Zn(3)(C(2)H(5))(2)(C(6)H(5)O(3))(4)]·2C(7)H(8), crystallizes with one complex molecule solvated by two molecules of toluene in the asymmetric unit. The Zn(II) ions are coordinated by two terminal ethyl (Et) groups and four maltolate ligands, which act as μ(3)- and μ(2)-bridges. The metal atoms are arranged in an incomplete cubane Zn(3)O(4) core structure, derived from one EtZnO(3) tetrahedron, one EtZnO(4) bipyramid and one ZnO(6) octahedron, sharing common corners. The structure is stabilized by weak C—H⋯O and C—H⋯π interactions. International Union of Crystallography 2013-04-20 /pmc/articles/PMC3647817/ /pubmed/23723783 http://dx.doi.org/10.1107/S1600536813010064 Text en © Petrus et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Petrus, Rafał Petrus, Joanna Paszek, Karolina Sobota, Piotr Diethyl(μ(3)-2-methyl-4-oxo-4H-pyran-3-olato-κ(4) O (3),O (4):O (3):O (3))tris(μ(2)-2-methyl-4-oxo-4H-pyran-3-olato-κ(3) O (3),O (4):O (3))trizinc toluene disolvate |
| title | Diethyl(μ(3)-2-methyl-4-oxo-4H-pyran-3-olato-κ(4)
O
(3),O
(4):O
(3):O
(3))tris(μ(2)-2-methyl-4-oxo-4H-pyran-3-olato-κ(3)
O
(3),O
(4):O
(3))trizinc toluene disolvate |
| title_full | Diethyl(μ(3)-2-methyl-4-oxo-4H-pyran-3-olato-κ(4)
O
(3),O
(4):O
(3):O
(3))tris(μ(2)-2-methyl-4-oxo-4H-pyran-3-olato-κ(3)
O
(3),O
(4):O
(3))trizinc toluene disolvate |
| title_fullStr | Diethyl(μ(3)-2-methyl-4-oxo-4H-pyran-3-olato-κ(4)
O
(3),O
(4):O
(3):O
(3))tris(μ(2)-2-methyl-4-oxo-4H-pyran-3-olato-κ(3)
O
(3),O
(4):O
(3))trizinc toluene disolvate |
| title_full_unstemmed | Diethyl(μ(3)-2-methyl-4-oxo-4H-pyran-3-olato-κ(4)
O
(3),O
(4):O
(3):O
(3))tris(μ(2)-2-methyl-4-oxo-4H-pyran-3-olato-κ(3)
O
(3),O
(4):O
(3))trizinc toluene disolvate |
| title_short | Diethyl(μ(3)-2-methyl-4-oxo-4H-pyran-3-olato-κ(4)
O
(3),O
(4):O
(3):O
(3))tris(μ(2)-2-methyl-4-oxo-4H-pyran-3-olato-κ(3)
O
(3),O
(4):O
(3))trizinc toluene disolvate |
| title_sort | diethyl(μ(3)-2-methyl-4-oxo-4h-pyran-3-olato-κ(4)
o
(3),o
(4):o
(3):o
(3))tris(μ(2)-2-methyl-4-oxo-4h-pyran-3-olato-κ(3)
o
(3),o
(4):o
(3))trizinc toluene disolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647817/ https://www.ncbi.nlm.nih.gov/pubmed/23723783 http://dx.doi.org/10.1107/S1600536813010064 |
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