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Bis(μ-4-formylbenzoato-κ(2) O:O′)bis[(4-formylbenzoato-κ(2) O,O′)bis(isonicotinamide-κN (1))copper(II)]
The asymmetric unit of the centrosymmetric dinuclear title compound, [Cu(2)(C(8)H(5)O(3))(4)(C(6)H(6)N(2)O)(4)], contains one half of the complex molecule. The Cu(II) atoms are bridged by the carboxylate groups of two 4-formylbenzoate (FOB) anions. Besides the two bridging FOB anions, one additio...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647822/ https://www.ncbi.nlm.nih.gov/pubmed/23723788 http://dx.doi.org/10.1107/S1600536813010908 |
Sumario: | The asymmetric unit of the centrosymmetric dinuclear title compound, [Cu(2)(C(8)H(5)O(3))(4)(C(6)H(6)N(2)O)(4)], contains one half of the complex molecule. The Cu(II) atoms are bridged by the carboxylate groups of two 4-formylbenzoate (FOB) anions. Besides the two bridging FOB anions, one additional chelating FOB anion and two isonicotinamide (INA) ligands complete the distorted CuN(2)O(4) octahedral coordination of each Cu(2+) cation. Within the asymmetric unit, the benzene and pyridine rings are oriented at dihedral angles of 25.1 (3) and 12.6 (3)°, respectively. In the crystal, N—H⋯O and C—H⋯O hydrogen bonds link the molecules into a three-dimensional network. π–π contacts between the pyridine rings [shortest centroid–centroid distance = 3.821 (3) Å] may further stabilize the crystal structure. One of the formyl groups of the two FOB anions is disordered over two sets of sites with an occupancy ratio of 0.65:0.35. |
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