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Bis(μ-4-formyl­benzoato-κ(2) O:O′)bis­[(4-formyl­benzoato-κ(2) O,O′)bis­(iso­nicotin­amide-κN (1))copper(II)]

The asymmetric unit of the centrosymmetric dinuclear title compound, [Cu(2)(C(8)H(5)O(3))(4)(C(6)H(6)N(2)O)(4)], contains one half of the complex mol­ecule. The Cu(II) atoms are bridged by the carboxyl­ate groups of two 4-formyl­benzoate (FOB) anions. Besides the two bridging FOB anions, one additio...

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Autores principales: Sertçelik, Mustafa, Çaylak Delibaş, Nagihan, Necefoğlu, Hacali, Hökelek, Tuncer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647822/
https://www.ncbi.nlm.nih.gov/pubmed/23723788
http://dx.doi.org/10.1107/S1600536813010908
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author Sertçelik, Mustafa
Çaylak Delibaş, Nagihan
Necefoğlu, Hacali
Hökelek, Tuncer
author_facet Sertçelik, Mustafa
Çaylak Delibaş, Nagihan
Necefoğlu, Hacali
Hökelek, Tuncer
author_sort Sertçelik, Mustafa
collection PubMed
description The asymmetric unit of the centrosymmetric dinuclear title compound, [Cu(2)(C(8)H(5)O(3))(4)(C(6)H(6)N(2)O)(4)], contains one half of the complex mol­ecule. The Cu(II) atoms are bridged by the carboxyl­ate groups of two 4-formyl­benzoate (FOB) anions. Besides the two bridging FOB anions, one additional chelating FOB anion and two isonicotinamide (INA) ligands complete the distorted CuN(2)O(4) octa­hedral coordination of each Cu(2+) cation. Within the asymmetric unit, the benzene and pyridine rings are oriented at dihedral angles of 25.1 (3) and 12.6 (3)°, respectively. In the crystal, N—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network. π–π contacts between the pyridine rings [shortest centroid–centroid distance = 3.821 (3) Å] may further stabilize the crystal structure. One of the formyl groups of the two FOB anions is disordered over two sets of sites with an occupancy ratio of 0.65:0.35.
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spelling pubmed-36478222013-05-30 Bis(μ-4-formyl­benzoato-κ(2) O:O′)bis­[(4-formyl­benzoato-κ(2) O,O′)bis­(iso­nicotin­amide-κN (1))copper(II)] Sertçelik, Mustafa Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the centrosymmetric dinuclear title compound, [Cu(2)(C(8)H(5)O(3))(4)(C(6)H(6)N(2)O)(4)], contains one half of the complex mol­ecule. The Cu(II) atoms are bridged by the carboxyl­ate groups of two 4-formyl­benzoate (FOB) anions. Besides the two bridging FOB anions, one additional chelating FOB anion and two isonicotinamide (INA) ligands complete the distorted CuN(2)O(4) octa­hedral coordination of each Cu(2+) cation. Within the asymmetric unit, the benzene and pyridine rings are oriented at dihedral angles of 25.1 (3) and 12.6 (3)°, respectively. In the crystal, N—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network. π–π contacts between the pyridine rings [shortest centroid–centroid distance = 3.821 (3) Å] may further stabilize the crystal structure. One of the formyl groups of the two FOB anions is disordered over two sets of sites with an occupancy ratio of 0.65:0.35. International Union of Crystallography 2013-04-27 /pmc/articles/PMC3647822/ /pubmed/23723788 http://dx.doi.org/10.1107/S1600536813010908 Text en © Sertçelik et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sertçelik, Mustafa
Çaylak Delibaş, Nagihan
Necefoğlu, Hacali
Hökelek, Tuncer
Bis(μ-4-formyl­benzoato-κ(2) O:O′)bis­[(4-formyl­benzoato-κ(2) O,O′)bis­(iso­nicotin­amide-κN (1))copper(II)]
title Bis(μ-4-formyl­benzoato-κ(2) O:O′)bis­[(4-formyl­benzoato-κ(2) O,O′)bis­(iso­nicotin­amide-κN (1))copper(II)]
title_full Bis(μ-4-formyl­benzoato-κ(2) O:O′)bis­[(4-formyl­benzoato-κ(2) O,O′)bis­(iso­nicotin­amide-κN (1))copper(II)]
title_fullStr Bis(μ-4-formyl­benzoato-κ(2) O:O′)bis­[(4-formyl­benzoato-κ(2) O,O′)bis­(iso­nicotin­amide-κN (1))copper(II)]
title_full_unstemmed Bis(μ-4-formyl­benzoato-κ(2) O:O′)bis­[(4-formyl­benzoato-κ(2) O,O′)bis­(iso­nicotin­amide-κN (1))copper(II)]
title_short Bis(μ-4-formyl­benzoato-κ(2) O:O′)bis­[(4-formyl­benzoato-κ(2) O,O′)bis­(iso­nicotin­amide-κN (1))copper(II)]
title_sort bis(μ-4-formyl­benzoato-κ(2) o:o′)bis­[(4-formyl­benzoato-κ(2) o,o′)bis­(iso­nicotin­amide-κn (1))copper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647822/
https://www.ncbi.nlm.nih.gov/pubmed/23723788
http://dx.doi.org/10.1107/S1600536813010908
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