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Bis(μ-4-formylbenzoato-κ(2) O:O′)bis[(4-formylbenzoato-κ(2) O,O′)bis(isonicotinamide-κN (1))copper(II)]
The asymmetric unit of the centrosymmetric dinuclear title compound, [Cu(2)(C(8)H(5)O(3))(4)(C(6)H(6)N(2)O)(4)], contains one half of the complex molecule. The Cu(II) atoms are bridged by the carboxylate groups of two 4-formylbenzoate (FOB) anions. Besides the two bridging FOB anions, one additio...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647822/ https://www.ncbi.nlm.nih.gov/pubmed/23723788 http://dx.doi.org/10.1107/S1600536813010908 |
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author | Sertçelik, Mustafa Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer |
author_facet | Sertçelik, Mustafa Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer |
author_sort | Sertçelik, Mustafa |
collection | PubMed |
description | The asymmetric unit of the centrosymmetric dinuclear title compound, [Cu(2)(C(8)H(5)O(3))(4)(C(6)H(6)N(2)O)(4)], contains one half of the complex molecule. The Cu(II) atoms are bridged by the carboxylate groups of two 4-formylbenzoate (FOB) anions. Besides the two bridging FOB anions, one additional chelating FOB anion and two isonicotinamide (INA) ligands complete the distorted CuN(2)O(4) octahedral coordination of each Cu(2+) cation. Within the asymmetric unit, the benzene and pyridine rings are oriented at dihedral angles of 25.1 (3) and 12.6 (3)°, respectively. In the crystal, N—H⋯O and C—H⋯O hydrogen bonds link the molecules into a three-dimensional network. π–π contacts between the pyridine rings [shortest centroid–centroid distance = 3.821 (3) Å] may further stabilize the crystal structure. One of the formyl groups of the two FOB anions is disordered over two sets of sites with an occupancy ratio of 0.65:0.35. |
format | Online Article Text |
id | pubmed-3647822 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36478222013-05-30 Bis(μ-4-formylbenzoato-κ(2) O:O′)bis[(4-formylbenzoato-κ(2) O,O′)bis(isonicotinamide-κN (1))copper(II)] Sertçelik, Mustafa Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the centrosymmetric dinuclear title compound, [Cu(2)(C(8)H(5)O(3))(4)(C(6)H(6)N(2)O)(4)], contains one half of the complex molecule. The Cu(II) atoms are bridged by the carboxylate groups of two 4-formylbenzoate (FOB) anions. Besides the two bridging FOB anions, one additional chelating FOB anion and two isonicotinamide (INA) ligands complete the distorted CuN(2)O(4) octahedral coordination of each Cu(2+) cation. Within the asymmetric unit, the benzene and pyridine rings are oriented at dihedral angles of 25.1 (3) and 12.6 (3)°, respectively. In the crystal, N—H⋯O and C—H⋯O hydrogen bonds link the molecules into a three-dimensional network. π–π contacts between the pyridine rings [shortest centroid–centroid distance = 3.821 (3) Å] may further stabilize the crystal structure. One of the formyl groups of the two FOB anions is disordered over two sets of sites with an occupancy ratio of 0.65:0.35. International Union of Crystallography 2013-04-27 /pmc/articles/PMC3647822/ /pubmed/23723788 http://dx.doi.org/10.1107/S1600536813010908 Text en © Sertçelik et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Sertçelik, Mustafa Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer Bis(μ-4-formylbenzoato-κ(2) O:O′)bis[(4-formylbenzoato-κ(2) O,O′)bis(isonicotinamide-κN (1))copper(II)] |
title | Bis(μ-4-formylbenzoato-κ(2)
O:O′)bis[(4-formylbenzoato-κ(2)
O,O′)bis(isonicotinamide-κN
(1))copper(II)] |
title_full | Bis(μ-4-formylbenzoato-κ(2)
O:O′)bis[(4-formylbenzoato-κ(2)
O,O′)bis(isonicotinamide-κN
(1))copper(II)] |
title_fullStr | Bis(μ-4-formylbenzoato-κ(2)
O:O′)bis[(4-formylbenzoato-κ(2)
O,O′)bis(isonicotinamide-κN
(1))copper(II)] |
title_full_unstemmed | Bis(μ-4-formylbenzoato-κ(2)
O:O′)bis[(4-formylbenzoato-κ(2)
O,O′)bis(isonicotinamide-κN
(1))copper(II)] |
title_short | Bis(μ-4-formylbenzoato-κ(2)
O:O′)bis[(4-formylbenzoato-κ(2)
O,O′)bis(isonicotinamide-κN
(1))copper(II)] |
title_sort | bis(μ-4-formylbenzoato-κ(2)
o:o′)bis[(4-formylbenzoato-κ(2)
o,o′)bis(isonicotinamide-κn
(1))copper(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647822/ https://www.ncbi.nlm.nih.gov/pubmed/23723788 http://dx.doi.org/10.1107/S1600536813010908 |
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