catena-Poly[[bis­(2-meth­oxy­aniline-κN)cadmium]-di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N]

The structure of the title compound, [Cd(NCS)(2)(C(7)H(9)NO)(2)](n), consists of cadmium–thio­cyanate layers parallel to the ab plane. Pairs of Cd(II) ions are bridged by two end-to-end inversely bridging μ-NCS-N:S thio­cyanate groups, forming a two-dimensional network with the remaining two trans p...

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Detalles Bibliográficos
Autores principales: Chemli, Rakia, Kamoun, Slaheddine, Roisnel, Thierry
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647823/
https://www.ncbi.nlm.nih.gov/pubmed/23723789
http://dx.doi.org/10.1107/S1600536813010738
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author Chemli, Rakia
Kamoun, Slaheddine
Roisnel, Thierry
author_facet Chemli, Rakia
Kamoun, Slaheddine
Roisnel, Thierry
author_sort Chemli, Rakia
collection PubMed
description The structure of the title compound, [Cd(NCS)(2)(C(7)H(9)NO)(2)](n), consists of cadmium–thio­cyanate layers parallel to the ab plane. Pairs of Cd(II) ions are bridged by two end-to-end inversely bridging μ-NCS-N:S thio­cyanate groups, forming a two-dimensional network with the remaining two trans positions of the octa­hedrally coordinated Cd(II) ions occupied by the N atoms of two neutral 2-meth­oxy­aniline ligands. The crystal structure is stabilized by intra­layer N—H⋯S hydrogen bonds.
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spelling pubmed-36478232013-05-30 catena-Poly[[bis­(2-meth­oxy­aniline-κN)cadmium]-di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N] Chemli, Rakia Kamoun, Slaheddine Roisnel, Thierry Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, [Cd(NCS)(2)(C(7)H(9)NO)(2)](n), consists of cadmium–thio­cyanate layers parallel to the ab plane. Pairs of Cd(II) ions are bridged by two end-to-end inversely bridging μ-NCS-N:S thio­cyanate groups, forming a two-dimensional network with the remaining two trans positions of the octa­hedrally coordinated Cd(II) ions occupied by the N atoms of two neutral 2-meth­oxy­aniline ligands. The crystal structure is stabilized by intra­layer N—H⋯S hydrogen bonds. International Union of Crystallography 2013-04-27 /pmc/articles/PMC3647823/ /pubmed/23723789 http://dx.doi.org/10.1107/S1600536813010738 Text en © Chemli et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chemli, Rakia
Kamoun, Slaheddine
Roisnel, Thierry
catena-Poly[[bis­(2-meth­oxy­aniline-κN)cadmium]-di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N]
title catena-Poly[[bis­(2-meth­oxy­aniline-κN)cadmium]-di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N]
title_full catena-Poly[[bis­(2-meth­oxy­aniline-κN)cadmium]-di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N]
title_fullStr catena-Poly[[bis­(2-meth­oxy­aniline-κN)cadmium]-di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N]
title_full_unstemmed catena-Poly[[bis­(2-meth­oxy­aniline-κN)cadmium]-di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N]
title_short catena-Poly[[bis­(2-meth­oxy­aniline-κN)cadmium]-di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N]
title_sort catena-poly[[bis­(2-meth­oxy­aniline-κn)cadmium]-di-μ-thio­cyanato-κ(2) n:s;κ(2) s:n]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647823/
https://www.ncbi.nlm.nih.gov/pubmed/23723789
http://dx.doi.org/10.1107/S1600536813010738
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AT roisnelthierry catenapolybis2methoxyanilinekncadmiumdimthiocyanatok2nsk2sn

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