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2-[(5′-Chloro-1,1′:3′,1′′-terphenyl-4′-yl)imino]acenaphthylen-1(2H)-one
The title compound, C(30)H(18)ClNO, is a product of the condensation reaction of acenaphthylene-1,2-dione and 5′-chloro-1,1′:3′,1′′-terphenyl-4′-amine. The acenaphthylene fragment and two terminal phenyl rings are rotated relative to the central benzene ring by 72.2 (3), 43.2 (3) and 41.2 (3)°, re...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647826/ https://www.ncbi.nlm.nih.gov/pubmed/23723792 http://dx.doi.org/10.1107/S1600536813008015 |
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author | Du, Zhengyin Che, Fushou Yan, Yufei Liu, Wei |
author_facet | Du, Zhengyin Che, Fushou Yan, Yufei Liu, Wei |
author_sort | Du, Zhengyin |
collection | PubMed |
description | The title compound, C(30)H(18)ClNO, is a product of the condensation reaction of acenaphthylene-1,2-dione and 5′-chloro-1,1′:3′,1′′-terphenyl-4′-amine. The acenaphthylene fragment and two terminal phenyl rings are rotated relative to the central benzene ring by 72.2 (3), 43.2 (3) and 41.2 (3)°, respectively. This molecular conformation is supported by weak C—H⋯π interactions. In the crystal, molecules form centrosymmetric dimers by the stacking interactions between two neighboring acenaphthylene fragments, with an interplanar distance of 3.365 (3) Å. The dimers are bound to each other by weak C—H⋯N and C—H⋯π interactions, forming a three-dimensional framework. |
format | Online Article Text |
id | pubmed-3647826 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36478262013-05-30 2-[(5′-Chloro-1,1′:3′,1′′-terphenyl-4′-yl)imino]acenaphthylen-1(2H)-one Du, Zhengyin Che, Fushou Yan, Yufei Liu, Wei Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(30)H(18)ClNO, is a product of the condensation reaction of acenaphthylene-1,2-dione and 5′-chloro-1,1′:3′,1′′-terphenyl-4′-amine. The acenaphthylene fragment and two terminal phenyl rings are rotated relative to the central benzene ring by 72.2 (3), 43.2 (3) and 41.2 (3)°, respectively. This molecular conformation is supported by weak C—H⋯π interactions. In the crystal, molecules form centrosymmetric dimers by the stacking interactions between two neighboring acenaphthylene fragments, with an interplanar distance of 3.365 (3) Å. The dimers are bound to each other by weak C—H⋯N and C—H⋯π interactions, forming a three-dimensional framework. International Union of Crystallography 2013-04-05 /pmc/articles/PMC3647826/ /pubmed/23723792 http://dx.doi.org/10.1107/S1600536813008015 Text en © Du et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Du, Zhengyin Che, Fushou Yan, Yufei Liu, Wei 2-[(5′-Chloro-1,1′:3′,1′′-terphenyl-4′-yl)imino]acenaphthylen-1(2H)-one |
title | 2-[(5′-Chloro-1,1′:3′,1′′-terphenyl-4′-yl)imino]acenaphthylen-1(2H)-one |
title_full | 2-[(5′-Chloro-1,1′:3′,1′′-terphenyl-4′-yl)imino]acenaphthylen-1(2H)-one |
title_fullStr | 2-[(5′-Chloro-1,1′:3′,1′′-terphenyl-4′-yl)imino]acenaphthylen-1(2H)-one |
title_full_unstemmed | 2-[(5′-Chloro-1,1′:3′,1′′-terphenyl-4′-yl)imino]acenaphthylen-1(2H)-one |
title_short | 2-[(5′-Chloro-1,1′:3′,1′′-terphenyl-4′-yl)imino]acenaphthylen-1(2H)-one |
title_sort | 2-[(5′-chloro-1,1′:3′,1′′-terphenyl-4′-yl)imino]acenaphthylen-1(2h)-one |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647826/ https://www.ncbi.nlm.nih.gov/pubmed/23723792 http://dx.doi.org/10.1107/S1600536813008015 |
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