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2-[(5′-Chloro-1,1′:3′,1′′-terphenyl-4′-yl)imino]­acenaphthylen-1(2H)-one

The title compound, C(30)H(18)ClNO, is a product of the condensation reaction of acenaphthyl­ene-1,2-dione and 5′-chloro-1,1′:3′,1′′-terphenyl-4′-amine. The acenaphthyl­ene fragment and two terminal phenyl rings are rotated relative to the central benzene ring by 72.2 (3), 43.2 (3) and 41.2 (3)°, re...

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Detalles Bibliográficos
Autores principales: Du, Zhengyin, Che, Fushou, Yan, Yufei, Liu, Wei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647826/
https://www.ncbi.nlm.nih.gov/pubmed/23723792
http://dx.doi.org/10.1107/S1600536813008015
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author Du, Zhengyin
Che, Fushou
Yan, Yufei
Liu, Wei
author_facet Du, Zhengyin
Che, Fushou
Yan, Yufei
Liu, Wei
author_sort Du, Zhengyin
collection PubMed
description The title compound, C(30)H(18)ClNO, is a product of the condensation reaction of acenaphthyl­ene-1,2-dione and 5′-chloro-1,1′:3′,1′′-terphenyl-4′-amine. The acenaphthyl­ene fragment and two terminal phenyl rings are rotated relative to the central benzene ring by 72.2 (3), 43.2 (3) and 41.2 (3)°, respectively. This mol­ecular conformation is supported by weak C—H⋯π inter­actions. In the crystal, mol­ecules form centrosymmetric dimers by the stacking inter­actions between two neighboring acenaphthyl­ene fragments, with an inter­planar distance of 3.365 (3) Å. The dimers are bound to each other by weak C—H⋯N and C—H⋯π inter­actions, forming a three-dimensional framework.
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spelling pubmed-36478262013-05-30 2-[(5′-Chloro-1,1′:3′,1′′-terphenyl-4′-yl)imino]­acenaphthylen-1(2H)-one Du, Zhengyin Che, Fushou Yan, Yufei Liu, Wei Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(30)H(18)ClNO, is a product of the condensation reaction of acenaphthyl­ene-1,2-dione and 5′-chloro-1,1′:3′,1′′-terphenyl-4′-amine. The acenaphthyl­ene fragment and two terminal phenyl rings are rotated relative to the central benzene ring by 72.2 (3), 43.2 (3) and 41.2 (3)°, respectively. This mol­ecular conformation is supported by weak C—H⋯π inter­actions. In the crystal, mol­ecules form centrosymmetric dimers by the stacking inter­actions between two neighboring acenaphthyl­ene fragments, with an inter­planar distance of 3.365 (3) Å. The dimers are bound to each other by weak C—H⋯N and C—H⋯π inter­actions, forming a three-dimensional framework. International Union of Crystallography 2013-04-05 /pmc/articles/PMC3647826/ /pubmed/23723792 http://dx.doi.org/10.1107/S1600536813008015 Text en © Du et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Du, Zhengyin
Che, Fushou
Yan, Yufei
Liu, Wei
2-[(5′-Chloro-1,1′:3′,1′′-terphenyl-4′-yl)imino]­acenaphthylen-1(2H)-one
title 2-[(5′-Chloro-1,1′:3′,1′′-terphenyl-4′-yl)imino]­acenaphthylen-1(2H)-one
title_full 2-[(5′-Chloro-1,1′:3′,1′′-terphenyl-4′-yl)imino]­acenaphthylen-1(2H)-one
title_fullStr 2-[(5′-Chloro-1,1′:3′,1′′-terphenyl-4′-yl)imino]­acenaphthylen-1(2H)-one
title_full_unstemmed 2-[(5′-Chloro-1,1′:3′,1′′-terphenyl-4′-yl)imino]­acenaphthylen-1(2H)-one
title_short 2-[(5′-Chloro-1,1′:3′,1′′-terphenyl-4′-yl)imino]­acenaphthylen-1(2H)-one
title_sort 2-[(5′-chloro-1,1′:3′,1′′-terphenyl-4′-yl)imino]­acenaphthylen-1(2h)-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647826/
https://www.ncbi.nlm.nih.gov/pubmed/23723792
http://dx.doi.org/10.1107/S1600536813008015
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