(3R,4S,5R)-Methyl 3,5-bis­[(tert-butyl­dimethyl­sil­yl)­oxy]-4-meth­oxy­cyclo­hex-1-ene­carboxyl­ate

The title compound, C(21)H(42)O(5)Si(2), was synthesized from (3R,4S,5R)-methyl 3,5-bis­[(tert-butyl­dimethyl­sil­yl)­oxy]-4-hy­droxy­cyclo­hex-1-ene­carboxyl­ate by an esterification reaction. The cyclo­hexene ring adopts a half-chair conformation. In the crystal, mol­ecules are linked via C—H⋯O hy...

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Detalles Bibliográficos
Autores principales: Liu, Ri, Shi, Yu, Xu, Chun-Xiu, Li, Yi-Liang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647833/
https://www.ncbi.nlm.nih.gov/pubmed/23723799
http://dx.doi.org/10.1107/S1600536813007551
Descripción
Sumario:The title compound, C(21)H(42)O(5)Si(2), was synthesized from (3R,4S,5R)-methyl 3,5-bis­[(tert-butyl­dimethyl­sil­yl)­oxy]-4-hy­droxy­cyclo­hex-1-ene­carboxyl­ate by an esterification reaction. The cyclo­hexene ring adopts a half-chair conformation. In the crystal, mol­ecules are linked via C—H⋯O hydrogen bonds, forming helical chains propagating along [010].

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