(3R,4S,5R)-Methyl 3,5-bis­[(tert-butyl­dimethyl­sil­yl)­oxy]-4-meth­oxy­cyclo­hex-1-ene­carboxyl­ate

The title compound, C(21)H(42)O(5)Si(2), was synthesized from (3R,4S,5R)-methyl 3,5-bis­[(tert-butyl­dimethyl­sil­yl)­oxy]-4-hy­droxy­cyclo­hex-1-ene­carboxyl­ate by an esterification reaction. The cyclo­hexene ring adopts a half-chair conformation. In the crystal, mol­ecules are linked via C—H⋯O hy...

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Detalles Bibliográficos
Autores principales: Liu, Ri, Shi, Yu, Xu, Chun-Xiu, Li, Yi-Liang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647833/
https://www.ncbi.nlm.nih.gov/pubmed/23723799
http://dx.doi.org/10.1107/S1600536813007551
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author Liu, Ri
Shi, Yu
Xu, Chun-Xiu
Li, Yi-Liang
author_facet Liu, Ri
Shi, Yu
Xu, Chun-Xiu
Li, Yi-Liang
author_sort Liu, Ri
collection PubMed
description The title compound, C(21)H(42)O(5)Si(2), was synthesized from (3R,4S,5R)-methyl 3,5-bis­[(tert-butyl­dimethyl­sil­yl)­oxy]-4-hy­droxy­cyclo­hex-1-ene­carboxyl­ate by an esterification reaction. The cyclo­hexene ring adopts a half-chair conformation. In the crystal, mol­ecules are linked via C—H⋯O hydrogen bonds, forming helical chains propagating along [010].
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spelling pubmed-36478332013-05-30 (3R,4S,5R)-Methyl 3,5-bis­[(tert-butyl­dimethyl­sil­yl)­oxy]-4-meth­oxy­cyclo­hex-1-ene­carboxyl­ate Liu, Ri Shi, Yu Xu, Chun-Xiu Li, Yi-Liang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(21)H(42)O(5)Si(2), was synthesized from (3R,4S,5R)-methyl 3,5-bis­[(tert-butyl­dimethyl­sil­yl)­oxy]-4-hy­droxy­cyclo­hex-1-ene­carboxyl­ate by an esterification reaction. The cyclo­hexene ring adopts a half-chair conformation. In the crystal, mol­ecules are linked via C—H⋯O hydrogen bonds, forming helical chains propagating along [010]. International Union of Crystallography 2013-04-05 /pmc/articles/PMC3647833/ /pubmed/23723799 http://dx.doi.org/10.1107/S1600536813007551 Text en © Liu et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Liu, Ri
Shi, Yu
Xu, Chun-Xiu
Li, Yi-Liang
(3R,4S,5R)-Methyl 3,5-bis­[(tert-butyl­dimethyl­sil­yl)­oxy]-4-meth­oxy­cyclo­hex-1-ene­carboxyl­ate
title (3R,4S,5R)-Methyl 3,5-bis­[(tert-butyl­dimethyl­sil­yl)­oxy]-4-meth­oxy­cyclo­hex-1-ene­carboxyl­ate
title_full (3R,4S,5R)-Methyl 3,5-bis­[(tert-butyl­dimethyl­sil­yl)­oxy]-4-meth­oxy­cyclo­hex-1-ene­carboxyl­ate
title_fullStr (3R,4S,5R)-Methyl 3,5-bis­[(tert-butyl­dimethyl­sil­yl)­oxy]-4-meth­oxy­cyclo­hex-1-ene­carboxyl­ate
title_full_unstemmed (3R,4S,5R)-Methyl 3,5-bis­[(tert-butyl­dimethyl­sil­yl)­oxy]-4-meth­oxy­cyclo­hex-1-ene­carboxyl­ate
title_short (3R,4S,5R)-Methyl 3,5-bis­[(tert-butyl­dimethyl­sil­yl)­oxy]-4-meth­oxy­cyclo­hex-1-ene­carboxyl­ate
title_sort (3r,4s,5r)-methyl 3,5-bis­[(tert-butyl­dimethyl­sil­yl)­oxy]-4-meth­oxy­cyclo­hex-1-ene­carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647833/
https://www.ncbi.nlm.nih.gov/pubmed/23723799
http://dx.doi.org/10.1107/S1600536813007551
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