rac-5-(1-Methyl­eth­yl)-2-sulfanylidene­imidazolidin-4-one

In the title compound, C(6)H(10)N(2)OS, the 2-sulfanylideneimidazolidin-4-one fragment is essentially planar (r.m.s. deviation = 0.0033 Å). In the crystal, one amino group is involved in N—H⋯O hydrogen bonding, which links pairs of mol­ecules into inversion dimers, while the other amino group genera...

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Detalles Bibliográficos
Autores principales: Castro, Rosane de P., Macedo, Fernando C., Brito, Tiago O., de Fátima, Angelo, Sabino, José R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647842/
https://www.ncbi.nlm.nih.gov/pubmed/23723808
http://dx.doi.org/10.1107/S1600536813008337
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author Castro, Rosane de P.
Macedo, Fernando C.
Brito, Tiago O.
de Fátima, Angelo
Sabino, José R.
author_facet Castro, Rosane de P.
Macedo, Fernando C.
Brito, Tiago O.
de Fátima, Angelo
Sabino, José R.
author_sort Castro, Rosane de P.
collection PubMed
description In the title compound, C(6)H(10)N(2)OS, the 2-sulfanylideneimidazolidin-4-one fragment is essentially planar (r.m.s. deviation = 0.0033 Å). In the crystal, one amino group is involved in N—H⋯O hydrogen bonding, which links pairs of mol­ecules into inversion dimers, while the other amino group generates weak N—H⋯S hydrogen bonds, which link these dimers into chains in [10-1]. The chains are further aggregated into layers parallel to the ac plane through weak C—H⋯O inter­actions.
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spelling pubmed-36478422013-05-30 rac-5-(1-Methyl­eth­yl)-2-sulfanylidene­imidazolidin-4-one Castro, Rosane de P. Macedo, Fernando C. Brito, Tiago O. de Fátima, Angelo Sabino, José R. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(6)H(10)N(2)OS, the 2-sulfanylideneimidazolidin-4-one fragment is essentially planar (r.m.s. deviation = 0.0033 Å). In the crystal, one amino group is involved in N—H⋯O hydrogen bonding, which links pairs of mol­ecules into inversion dimers, while the other amino group generates weak N—H⋯S hydrogen bonds, which link these dimers into chains in [10-1]. The chains are further aggregated into layers parallel to the ac plane through weak C—H⋯O inter­actions. International Union of Crystallography 2013-04-05 /pmc/articles/PMC3647842/ /pubmed/23723808 http://dx.doi.org/10.1107/S1600536813008337 Text en © Castro et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Castro, Rosane de P.
Macedo, Fernando C.
Brito, Tiago O.
de Fátima, Angelo
Sabino, José R.
rac-5-(1-Methyl­eth­yl)-2-sulfanylidene­imidazolidin-4-one
title rac-5-(1-Methyl­eth­yl)-2-sulfanylidene­imidazolidin-4-one
title_full rac-5-(1-Methyl­eth­yl)-2-sulfanylidene­imidazolidin-4-one
title_fullStr rac-5-(1-Methyl­eth­yl)-2-sulfanylidene­imidazolidin-4-one
title_full_unstemmed rac-5-(1-Methyl­eth­yl)-2-sulfanylidene­imidazolidin-4-one
title_short rac-5-(1-Methyl­eth­yl)-2-sulfanylidene­imidazolidin-4-one
title_sort rac-5-(1-methyl­eth­yl)-2-sulfanylidene­imidazolidin-4-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647842/
https://www.ncbi.nlm.nih.gov/pubmed/23723808
http://dx.doi.org/10.1107/S1600536813008337
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