(E)-6-(4-Chloro­phen­yl)-4-[(2-cyano-3-phenyl­all­yl)sulfan­yl]-2,2-difluoro-3-phenyl-1,3,2-oxaza­borinin-3-ium-2-uide

In the title compound, C(25)H(18)BClF(2)N(2)OS, the characteristic B—N and B—O bond lengths are 1.571 (3) and 1.458 (3) Å, respectively. The phenyl rings form dihedral angles of 83.1 (1) and 64.6 (1)° with the chloro­phenyl ring. In the crystal, weak C—H⋯N, C—H⋯F, C—H⋯π and π–π inter­actions [centro...

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Detalles Bibliográficos
Autores principales: Li, Ming, Wang, Shu-Wen, Wen, Li-Rong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647846/
https://www.ncbi.nlm.nih.gov/pubmed/23723812
http://dx.doi.org/10.1107/S1600536813007800
Descripción
Sumario:In the title compound, C(25)H(18)BClF(2)N(2)OS, the characteristic B—N and B—O bond lengths are 1.571 (3) and 1.458 (3) Å, respectively. The phenyl rings form dihedral angles of 83.1 (1) and 64.6 (1)° with the chloro­phenyl ring. In the crystal, weak C—H⋯N, C—H⋯F, C—H⋯π and π–π inter­actions [centroid–centroid distances 3.877 (6) Å between the chloro­phenyl rings of neighbouring mol­ecules] held mol­ecules together, forming ladders along the b axis.

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