(E)-6-(4-Chloro­phen­yl)-4-[(2-cyano-3-phenyl­all­yl)sulfan­yl]-2,2-difluoro-3-phenyl-1,3,2-oxaza­borinin-3-ium-2-uide

In the title compound, C(25)H(18)BClF(2)N(2)OS, the characteristic B—N and B—O bond lengths are 1.571 (3) and 1.458 (3) Å, respectively. The phenyl rings form dihedral angles of 83.1 (1) and 64.6 (1)° with the chloro­phenyl ring. In the crystal, weak C—H⋯N, C—H⋯F, C—H⋯π and π–π inter­actions [centro...

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Detalles Bibliográficos
Autores principales: Li, Ming, Wang, Shu-Wen, Wen, Li-Rong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647846/
https://www.ncbi.nlm.nih.gov/pubmed/23723812
http://dx.doi.org/10.1107/S1600536813007800
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author Li, Ming
Wang, Shu-Wen
Wen, Li-Rong
author_facet Li, Ming
Wang, Shu-Wen
Wen, Li-Rong
author_sort Li, Ming
collection PubMed
description In the title compound, C(25)H(18)BClF(2)N(2)OS, the characteristic B—N and B—O bond lengths are 1.571 (3) and 1.458 (3) Å, respectively. The phenyl rings form dihedral angles of 83.1 (1) and 64.6 (1)° with the chloro­phenyl ring. In the crystal, weak C—H⋯N, C—H⋯F, C—H⋯π and π–π inter­actions [centroid–centroid distances 3.877 (6) Å between the chloro­phenyl rings of neighbouring mol­ecules] held mol­ecules together, forming ladders along the b axis.
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spelling pubmed-36478462013-05-30 (E)-6-(4-Chloro­phen­yl)-4-[(2-cyano-3-phenyl­all­yl)sulfan­yl]-2,2-difluoro-3-phenyl-1,3,2-oxaza­borinin-3-ium-2-uide Li, Ming Wang, Shu-Wen Wen, Li-Rong Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(25)H(18)BClF(2)N(2)OS, the characteristic B—N and B—O bond lengths are 1.571 (3) and 1.458 (3) Å, respectively. The phenyl rings form dihedral angles of 83.1 (1) and 64.6 (1)° with the chloro­phenyl ring. In the crystal, weak C—H⋯N, C—H⋯F, C—H⋯π and π–π inter­actions [centroid–centroid distances 3.877 (6) Å between the chloro­phenyl rings of neighbouring mol­ecules] held mol­ecules together, forming ladders along the b axis. International Union of Crystallography 2013-04-05 /pmc/articles/PMC3647846/ /pubmed/23723812 http://dx.doi.org/10.1107/S1600536813007800 Text en © Li et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Ming
Wang, Shu-Wen
Wen, Li-Rong
(E)-6-(4-Chloro­phen­yl)-4-[(2-cyano-3-phenyl­all­yl)sulfan­yl]-2,2-difluoro-3-phenyl-1,3,2-oxaza­borinin-3-ium-2-uide
title (E)-6-(4-Chloro­phen­yl)-4-[(2-cyano-3-phenyl­all­yl)sulfan­yl]-2,2-difluoro-3-phenyl-1,3,2-oxaza­borinin-3-ium-2-uide
title_full (E)-6-(4-Chloro­phen­yl)-4-[(2-cyano-3-phenyl­all­yl)sulfan­yl]-2,2-difluoro-3-phenyl-1,3,2-oxaza­borinin-3-ium-2-uide
title_fullStr (E)-6-(4-Chloro­phen­yl)-4-[(2-cyano-3-phenyl­all­yl)sulfan­yl]-2,2-difluoro-3-phenyl-1,3,2-oxaza­borinin-3-ium-2-uide
title_full_unstemmed (E)-6-(4-Chloro­phen­yl)-4-[(2-cyano-3-phenyl­all­yl)sulfan­yl]-2,2-difluoro-3-phenyl-1,3,2-oxaza­borinin-3-ium-2-uide
title_short (E)-6-(4-Chloro­phen­yl)-4-[(2-cyano-3-phenyl­all­yl)sulfan­yl]-2,2-difluoro-3-phenyl-1,3,2-oxaza­borinin-3-ium-2-uide
title_sort (e)-6-(4-chloro­phen­yl)-4-[(2-cyano-3-phenyl­all­yl)sulfan­yl]-2,2-difluoro-3-phenyl-1,3,2-oxaza­borinin-3-ium-2-uide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647846/
https://www.ncbi.nlm.nih.gov/pubmed/23723812
http://dx.doi.org/10.1107/S1600536813007800
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