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(4-Eth­oxy­benzo­yl)[8-(4-eth­oxy­benzo­yl)-2,7-di­meth­oxy­naphthalen-1-yl]methanone

The title mol­ecule, C(30)H(28)O(6), possesses crystallographically imposed twofold symmetry, with two central C atoms in the naphthalene unit lying on the rotation axis along [001]. The 4-eth­oxy­benzoyl groups at the peri positions of the naphthalene ring system are disordered over two sets of sit...

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Autores principales: Sasagawa, Kosuke, Sakamoto, Rei, Hijikata, Daichi, Yonezawa, Noriyuki, Okamoto, Akiko
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647849/
https://www.ncbi.nlm.nih.gov/pubmed/23723815
http://dx.doi.org/10.1107/S1600536813008581
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author Sasagawa, Kosuke
Sakamoto, Rei
Hijikata, Daichi
Yonezawa, Noriyuki
Okamoto, Akiko
author_facet Sasagawa, Kosuke
Sakamoto, Rei
Hijikata, Daichi
Yonezawa, Noriyuki
Okamoto, Akiko
author_sort Sasagawa, Kosuke
collection PubMed
description The title mol­ecule, C(30)H(28)O(6), possesses crystallographically imposed twofold symmetry, with two central C atoms in the naphthalene unit lying on the rotation axis along [001]. The 4-eth­oxy­benzoyl groups at the peri positions of the naphthalene ring system are disordered over two sets of sites with occupancies of 0.769 (4) and 0.231 (4). They are directed in opposite directions from the naphthalene plane (anti orientation). For the major component, the dihedral angle between the aroyl benzene ring and the naphthalene ring system is 75.62 (13)° [minor component 75.5 (4)°], and that between the aroyl benzene rings is 32.58 (15)°. In the crystal, mol­ecules are linked via C—H⋯O and C—H⋯π inter­actions, forming a three-dimensional network.
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spelling pubmed-36478492013-05-30 (4-Eth­oxy­benzo­yl)[8-(4-eth­oxy­benzo­yl)-2,7-di­meth­oxy­naphthalen-1-yl]methanone Sasagawa, Kosuke Sakamoto, Rei Hijikata, Daichi Yonezawa, Noriyuki Okamoto, Akiko Acta Crystallogr Sect E Struct Rep Online Organic Papers The title mol­ecule, C(30)H(28)O(6), possesses crystallographically imposed twofold symmetry, with two central C atoms in the naphthalene unit lying on the rotation axis along [001]. The 4-eth­oxy­benzoyl groups at the peri positions of the naphthalene ring system are disordered over two sets of sites with occupancies of 0.769 (4) and 0.231 (4). They are directed in opposite directions from the naphthalene plane (anti orientation). For the major component, the dihedral angle between the aroyl benzene ring and the naphthalene ring system is 75.62 (13)° [minor component 75.5 (4)°], and that between the aroyl benzene rings is 32.58 (15)°. In the crystal, mol­ecules are linked via C—H⋯O and C—H⋯π inter­actions, forming a three-dimensional network. International Union of Crystallography 2013-04-05 /pmc/articles/PMC3647849/ /pubmed/23723815 http://dx.doi.org/10.1107/S1600536813008581 Text en © Sasagawa et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sasagawa, Kosuke
Sakamoto, Rei
Hijikata, Daichi
Yonezawa, Noriyuki
Okamoto, Akiko
(4-Eth­oxy­benzo­yl)[8-(4-eth­oxy­benzo­yl)-2,7-di­meth­oxy­naphthalen-1-yl]methanone
title (4-Eth­oxy­benzo­yl)[8-(4-eth­oxy­benzo­yl)-2,7-di­meth­oxy­naphthalen-1-yl]methanone
title_full (4-Eth­oxy­benzo­yl)[8-(4-eth­oxy­benzo­yl)-2,7-di­meth­oxy­naphthalen-1-yl]methanone
title_fullStr (4-Eth­oxy­benzo­yl)[8-(4-eth­oxy­benzo­yl)-2,7-di­meth­oxy­naphthalen-1-yl]methanone
title_full_unstemmed (4-Eth­oxy­benzo­yl)[8-(4-eth­oxy­benzo­yl)-2,7-di­meth­oxy­naphthalen-1-yl]methanone
title_short (4-Eth­oxy­benzo­yl)[8-(4-eth­oxy­benzo­yl)-2,7-di­meth­oxy­naphthalen-1-yl]methanone
title_sort (4-eth­oxy­benzo­yl)[8-(4-eth­oxy­benzo­yl)-2,7-di­meth­oxy­naphthalen-1-yl]methanone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647849/
https://www.ncbi.nlm.nih.gov/pubmed/23723815
http://dx.doi.org/10.1107/S1600536813008581
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