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1,3-Diiodo­azulene-2-carbonitrile

In the title compound, C(11)H(5)I(2)N, the two iodine-atom substitutents with their large atomic sizes lead to short intra­molecular I⋯H distances (3.01 Å). In the crystal, the tris­ubstituted azulene system forms π-stacks [centroid–centroid distance = 3.6343 (11) Å] along the a-axis direction, show...

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Detalles Bibliográficos
Autores principales: Förster, Sebastian, Seichter, Wilhelm, Weber, Edwin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647852/
https://www.ncbi.nlm.nih.gov/pubmed/23723818
http://dx.doi.org/10.1107/S1600536813008301
Descripción
Sumario:In the title compound, C(11)H(5)I(2)N, the two iodine-atom substitutents with their large atomic sizes lead to short intra­molecular I⋯H distances (3.01 Å). In the crystal, the tris­ubstituted azulene system forms π-stacks [centroid–centroid distance = 3.6343 (11) Å] along the a-axis direction, showing the characteristic azulene inter­action mode between the electron-rich five-membered ring and the electron-deficient seven-membered ring. I⋯I [3.9129 (2) Å] non-covalent contacts are observed along with weak C—H⋯N and C—H⋯π. bonds.