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1,3-Diiodoazulene-2-carbonitrile
In the title compound, C(11)H(5)I(2)N, the two iodine-atom substitutents with their large atomic sizes lead to short intramolecular I⋯H distances (3.01 Å). In the crystal, the trisubstituted azulene system forms π-stacks [centroid–centroid distance = 3.6343 (11) Å] along the a-axis direction, show...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647852/ https://www.ncbi.nlm.nih.gov/pubmed/23723818 http://dx.doi.org/10.1107/S1600536813008301 |
Sumario: | In the title compound, C(11)H(5)I(2)N, the two iodine-atom substitutents with their large atomic sizes lead to short intramolecular I⋯H distances (3.01 Å). In the crystal, the trisubstituted azulene system forms π-stacks [centroid–centroid distance = 3.6343 (11) Å] along the a-axis direction, showing the characteristic azulene interaction mode between the electron-rich five-membered ring and the electron-deficient seven-membered ring. I⋯I [3.9129 (2) Å] non-covalent contacts are observed along with weak C—H⋯N and C—H⋯π. bonds. |
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