2,3-Dimeth­oxy-10-oxostrychnidinium hydrogen oxalate dihydrate

In the cation of the title salt, C(23)H(27)N(2)O(4) (+)·C(2)HO(4) (−)·2H(2)O, both fused pyrrolidine rings exhibit twisted conformations, while the piperidine rings adopt screw-boat and boat conformations. In the crystal, the three components are linked via O—H⋯O and N—H⋯O inter­actions, forming a t...

Descripción completa

Detalles Bibliográficos
Autores principales: Krishnan, P., Gayathri, K., Sivakumar, N., Chakkaravarthi, G., Anbalagan, G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647855/
https://www.ncbi.nlm.nih.gov/pubmed/23723821
http://dx.doi.org/10.1107/S1600536813008623
Descripción
Sumario:In the cation of the title salt, C(23)H(27)N(2)O(4) (+)·C(2)HO(4) (−)·2H(2)O, both fused pyrrolidine rings exhibit twisted conformations, while the piperidine rings adopt screw-boat and boat conformations. In the crystal, the three components are linked via O—H⋯O and N—H⋯O inter­actions, forming a tape along the b axis. The tapes are further linked by weak C—H⋯O hydrogen bonds. forming a three-dimensional network.

Ejemplares similares