2,3-Dimeth­oxy-10-oxostrychnidinium hydrogen oxalate dihydrate

In the cation of the title salt, C(23)H(27)N(2)O(4) (+)·C(2)HO(4) (−)·2H(2)O, both fused pyrrolidine rings exhibit twisted conformations, while the piperidine rings adopt screw-boat and boat conformations. In the crystal, the three components are linked via O—H⋯O and N—H⋯O inter­actions, forming a t...

Descripción completa

Detalles Bibliográficos
Autores principales: Krishnan, P., Gayathri, K., Sivakumar, N., Chakkaravarthi, G., Anbalagan, G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647855/
https://www.ncbi.nlm.nih.gov/pubmed/23723821
http://dx.doi.org/10.1107/S1600536813008623
_version_ 1782268791239999488
author Krishnan, P.
Gayathri, K.
Sivakumar, N.
Chakkaravarthi, G.
Anbalagan, G.
author_facet Krishnan, P.
Gayathri, K.
Sivakumar, N.
Chakkaravarthi, G.
Anbalagan, G.
author_sort Krishnan, P.
collection PubMed
description In the cation of the title salt, C(23)H(27)N(2)O(4) (+)·C(2)HO(4) (−)·2H(2)O, both fused pyrrolidine rings exhibit twisted conformations, while the piperidine rings adopt screw-boat and boat conformations. In the crystal, the three components are linked via O—H⋯O and N—H⋯O inter­actions, forming a tape along the b axis. The tapes are further linked by weak C—H⋯O hydrogen bonds. forming a three-dimensional network.
format Online
Article
Text
id pubmed-3647855
institution National Center for Biotechnology Information
language English
publishDate 2013
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-36478552013-05-30 2,3-Dimeth­oxy-10-oxostrychnidinium hydrogen oxalate dihydrate Krishnan, P. Gayathri, K. Sivakumar, N. Chakkaravarthi, G. Anbalagan, G. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the cation of the title salt, C(23)H(27)N(2)O(4) (+)·C(2)HO(4) (−)·2H(2)O, both fused pyrrolidine rings exhibit twisted conformations, while the piperidine rings adopt screw-boat and boat conformations. In the crystal, the three components are linked via O—H⋯O and N—H⋯O inter­actions, forming a tape along the b axis. The tapes are further linked by weak C—H⋯O hydrogen bonds. forming a three-dimensional network. International Union of Crystallography 2013-04-05 /pmc/articles/PMC3647855/ /pubmed/23723821 http://dx.doi.org/10.1107/S1600536813008623 Text en © Krishnan et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Krishnan, P.
Gayathri, K.
Sivakumar, N.
Chakkaravarthi, G.
Anbalagan, G.
2,3-Dimeth­oxy-10-oxostrychnidinium hydrogen oxalate dihydrate
title 2,3-Dimeth­oxy-10-oxostrychnidinium hydrogen oxalate dihydrate
title_full 2,3-Dimeth­oxy-10-oxostrychnidinium hydrogen oxalate dihydrate
title_fullStr 2,3-Dimeth­oxy-10-oxostrychnidinium hydrogen oxalate dihydrate
title_full_unstemmed 2,3-Dimeth­oxy-10-oxostrychnidinium hydrogen oxalate dihydrate
title_short 2,3-Dimeth­oxy-10-oxostrychnidinium hydrogen oxalate dihydrate
title_sort 2,3-dimeth­oxy-10-oxostrychnidinium hydrogen oxalate dihydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647855/
https://www.ncbi.nlm.nih.gov/pubmed/23723821
http://dx.doi.org/10.1107/S1600536813008623
work_keys_str_mv AT krishnanp 23dimethoxy10oxostrychnidiniumhydrogenoxalatedihydrate
AT gayathrik 23dimethoxy10oxostrychnidiniumhydrogenoxalatedihydrate
AT sivakumarn 23dimethoxy10oxostrychnidiniumhydrogenoxalatedihydrate
AT chakkaravarthig 23dimethoxy10oxostrychnidiniumhydrogenoxalatedihydrate
AT anbalagang 23dimethoxy10oxostrychnidiniumhydrogenoxalatedihydrate

Ejemplares similares