Bis(pyridin-2-ylmeth­yl)ammonium nitrate

In the title compound, C(12)H(14)N(3) (+)·NO(3) (−), the mononitrate of protonated bis­(pyridin-2-ylmeth­yl)amine, the least-squares planes defined by the non-H atoms of the two aromatic moieties inter­sect at an angle of 7.91 (6)°. In the crystal, N—H⋯N, N—H⋯O and C—H⋯N hydrogen bonds, as well as C...

Descripción completa

Detalles Bibliográficos
Autores principales: Abrahams, Abubak’r, van Brecht, Bernardus, Betz, Richard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647857/
https://www.ncbi.nlm.nih.gov/pubmed/23723823
http://dx.doi.org/10.1107/S1600536813008593
_version_ 1782268791697178624
author Abrahams, Abubak’r
van Brecht, Bernardus
Betz, Richard
author_facet Abrahams, Abubak’r
van Brecht, Bernardus
Betz, Richard
author_sort Abrahams, Abubak’r
collection PubMed
description In the title compound, C(12)H(14)N(3) (+)·NO(3) (−), the mononitrate of protonated bis­(pyridin-2-ylmeth­yl)amine, the least-squares planes defined by the non-H atoms of the two aromatic moieties inter­sect at an angle of 7.91 (6)°. In the crystal, N—H⋯N, N—H⋯O and C—H⋯N hydrogen bonds, as well as C—H⋯O contacts, connect the entities into a three-dimensional network. The shortest centroid–centroid distance between two aromatic systems is 3.7255 (8) Å and is apparent between the two different aromatic moieties.
format Online
Article
Text
id pubmed-3647857
institution National Center for Biotechnology Information
language English
publishDate 2013
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-36478572013-05-30 Bis(pyridin-2-ylmeth­yl)ammonium nitrate Abrahams, Abubak’r van Brecht, Bernardus Betz, Richard Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(12)H(14)N(3) (+)·NO(3) (−), the mononitrate of protonated bis­(pyridin-2-ylmeth­yl)amine, the least-squares planes defined by the non-H atoms of the two aromatic moieties inter­sect at an angle of 7.91 (6)°. In the crystal, N—H⋯N, N—H⋯O and C—H⋯N hydrogen bonds, as well as C—H⋯O contacts, connect the entities into a three-dimensional network. The shortest centroid–centroid distance between two aromatic systems is 3.7255 (8) Å and is apparent between the two different aromatic moieties. International Union of Crystallography 2013-04-05 /pmc/articles/PMC3647857/ /pubmed/23723823 http://dx.doi.org/10.1107/S1600536813008593 Text en © Abrahams et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Abrahams, Abubak’r
van Brecht, Bernardus
Betz, Richard
Bis(pyridin-2-ylmeth­yl)ammonium nitrate
title Bis(pyridin-2-ylmeth­yl)ammonium nitrate
title_full Bis(pyridin-2-ylmeth­yl)ammonium nitrate
title_fullStr Bis(pyridin-2-ylmeth­yl)ammonium nitrate
title_full_unstemmed Bis(pyridin-2-ylmeth­yl)ammonium nitrate
title_short Bis(pyridin-2-ylmeth­yl)ammonium nitrate
title_sort bis(pyridin-2-ylmeth­yl)ammonium nitrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647857/
https://www.ncbi.nlm.nih.gov/pubmed/23723823
http://dx.doi.org/10.1107/S1600536813008593
work_keys_str_mv AT abrahamsabubakr bispyridin2ylmethylammoniumnitrate
AT vanbrechtbernardus bispyridin2ylmethylammoniumnitrate
AT betzrichard bispyridin2ylmethylammoniumnitrate

Ejemplares similares