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N,N-Diphenyl-4-(1H-pyrrolo[1,2-f][1,10]phenanthrolin-2-yl)aniline ethanol monosolvate
The title compound, C(32)H(21)N(4)·C(2)H(5)OH, crystallized as an ethanol monosolvate. In the molecule of this phenanthroline derivative, the pyridine rings are almost coplanar, making a dihedral angle of 1.54 (13)°. The triphenylamine group, introduced as an electron donor, shows a propeller-typ...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647870/ https://www.ncbi.nlm.nih.gov/pubmed/23723836 http://dx.doi.org/10.1107/S1600536813008477 |
Sumario: | The title compound, C(32)H(21)N(4)·C(2)H(5)OH, crystallized as an ethanol monosolvate. In the molecule of this phenanthroline derivative, the pyridine rings are almost coplanar, making a dihedral angle of 1.54 (13)°. The triphenylamine group, introduced as an electron donor, shows a propeller-type structure, and the dihedral angles between the benzene rings are 68.71 11), 63.92 (16) and 70.81 (15)°. In the crystal, the phenanthroline molecules are linked via the solvent molecule by N—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds, leading to the formation of zigzag chains propagating along [010]. These chains are linked via C—H⋯N hydrogen bonds, forming undulating two-dimensional networks extending in the a- and b-axis directions. |
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