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N,N-Di­phenyl-4-(1H-pyrrolo[1,2-f][1,10]phenanthro­lin-2-yl)­aniline ethanol monosolvate

The title compound, C(32)H(21)N(4)·C(2)H(5)OH, crystallized as an ethanol monosolvate. In the mol­ecule of this phenanthroline derivative, the pyridine rings are almost coplanar, making a dihedral angle of 1.54 (13)°. The tri­phenyl­amine group, introduced as an electron donor, shows a propeller-typ...

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Detalles Bibliográficos
Autores principales: Luo, Jun-Shan, Zhang, Yan-Yan, Liu, Zhao-Di, Tian, Yu-Peng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647870/
https://www.ncbi.nlm.nih.gov/pubmed/23723836
http://dx.doi.org/10.1107/S1600536813008477
Descripción
Sumario:The title compound, C(32)H(21)N(4)·C(2)H(5)OH, crystallized as an ethanol monosolvate. In the mol­ecule of this phenanthroline derivative, the pyridine rings are almost coplanar, making a dihedral angle of 1.54 (13)°. The tri­phenyl­amine group, introduced as an electron donor, shows a propeller-type structure, and the dihedral angles between the benzene rings are 68.71 11), 63.92 (16) and 70.81 (15)°. In the crystal, the phenanthroline mol­ecules are linked via the solvent mol­ecule by N—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds, leading to the formation of zigzag chains propagating along [010]. These chains are linked via C—H⋯N hydrogen bonds, forming undulating two-dimensional networks extending in the a- and b-axis directions.