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N,N-Di­phenyl-4-(1H-pyrrolo[1,2-f][1,10]phenanthro­lin-2-yl)­aniline ethanol monosolvate

The title compound, C(32)H(21)N(4)·C(2)H(5)OH, crystallized as an ethanol monosolvate. In the mol­ecule of this phenanthroline derivative, the pyridine rings are almost coplanar, making a dihedral angle of 1.54 (13)°. The tri­phenyl­amine group, introduced as an electron donor, shows a propeller-typ...

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Autores principales: Luo, Jun-Shan, Zhang, Yan-Yan, Liu, Zhao-Di, Tian, Yu-Peng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647870/
https://www.ncbi.nlm.nih.gov/pubmed/23723836
http://dx.doi.org/10.1107/S1600536813008477
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author Luo, Jun-Shan
Zhang, Yan-Yan
Liu, Zhao-Di
Tian, Yu-Peng
author_facet Luo, Jun-Shan
Zhang, Yan-Yan
Liu, Zhao-Di
Tian, Yu-Peng
author_sort Luo, Jun-Shan
collection PubMed
description The title compound, C(32)H(21)N(4)·C(2)H(5)OH, crystallized as an ethanol monosolvate. In the mol­ecule of this phenanthroline derivative, the pyridine rings are almost coplanar, making a dihedral angle of 1.54 (13)°. The tri­phenyl­amine group, introduced as an electron donor, shows a propeller-type structure, and the dihedral angles between the benzene rings are 68.71 11), 63.92 (16) and 70.81 (15)°. In the crystal, the phenanthroline mol­ecules are linked via the solvent mol­ecule by N—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds, leading to the formation of zigzag chains propagating along [010]. These chains are linked via C—H⋯N hydrogen bonds, forming undulating two-dimensional networks extending in the a- and b-axis directions.
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spelling pubmed-36478702013-05-30 N,N-Di­phenyl-4-(1H-pyrrolo[1,2-f][1,10]phenanthro­lin-2-yl)­aniline ethanol monosolvate Luo, Jun-Shan Zhang, Yan-Yan Liu, Zhao-Di Tian, Yu-Peng Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(32)H(21)N(4)·C(2)H(5)OH, crystallized as an ethanol monosolvate. In the mol­ecule of this phenanthroline derivative, the pyridine rings are almost coplanar, making a dihedral angle of 1.54 (13)°. The tri­phenyl­amine group, introduced as an electron donor, shows a propeller-type structure, and the dihedral angles between the benzene rings are 68.71 11), 63.92 (16) and 70.81 (15)°. In the crystal, the phenanthroline mol­ecules are linked via the solvent mol­ecule by N—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds, leading to the formation of zigzag chains propagating along [010]. These chains are linked via C—H⋯N hydrogen bonds, forming undulating two-dimensional networks extending in the a- and b-axis directions. International Union of Crystallography 2013-04-10 /pmc/articles/PMC3647870/ /pubmed/23723836 http://dx.doi.org/10.1107/S1600536813008477 Text en © Luo et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Luo, Jun-Shan
Zhang, Yan-Yan
Liu, Zhao-Di
Tian, Yu-Peng
N,N-Di­phenyl-4-(1H-pyrrolo[1,2-f][1,10]phenanthro­lin-2-yl)­aniline ethanol monosolvate
title N,N-Di­phenyl-4-(1H-pyrrolo[1,2-f][1,10]phenanthro­lin-2-yl)­aniline ethanol monosolvate
title_full N,N-Di­phenyl-4-(1H-pyrrolo[1,2-f][1,10]phenanthro­lin-2-yl)­aniline ethanol monosolvate
title_fullStr N,N-Di­phenyl-4-(1H-pyrrolo[1,2-f][1,10]phenanthro­lin-2-yl)­aniline ethanol monosolvate
title_full_unstemmed N,N-Di­phenyl-4-(1H-pyrrolo[1,2-f][1,10]phenanthro­lin-2-yl)­aniline ethanol monosolvate
title_short N,N-Di­phenyl-4-(1H-pyrrolo[1,2-f][1,10]phenanthro­lin-2-yl)­aniline ethanol monosolvate
title_sort n,n-di­phenyl-4-(1h-pyrrolo[1,2-f][1,10]phenanthro­lin-2-yl)­aniline ethanol monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647870/
https://www.ncbi.nlm.nih.gov/pubmed/23723836
http://dx.doi.org/10.1107/S1600536813008477
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