1,3,5-Tris(bromo­meth­yl)-2,4,6-trimeth­oxy­benzene

There are three independent mol­ecules in the asymmetric unit of the title compound, C(12)H(15)Br(3)O(3), two of which have approximate trigonal symmetry, the third being conformationally different as it adopts near mirror symmetry. The crystal structure features C—H⋯Br inter­actions, a weak C—H⋯O h...

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Detalles Bibliográficos
Autores principales: Koch, Niklas, Seichter, Wilhelm, Mazik, Monika
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647873/
https://www.ncbi.nlm.nih.gov/pubmed/23723839
http://dx.doi.org/10.1107/S1600536813008441
Descripción
Sumario:There are three independent mol­ecules in the asymmetric unit of the title compound, C(12)H(15)Br(3)O(3), two of which have approximate trigonal symmetry, the third being conformationally different as it adopts near mirror symmetry. The crystal structure features C—H⋯Br inter­actions, a weak C—H⋯O hydrogen bond, π–π inter­actions [minimum ring centroid separation = 3.4927 (18) Å] and a short Br⋯Br contact [3.5894 (5) Å], resulting in a three-dimensional supramolecular network.

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